Thermal properties of methyltrimethoxysilane aerogel thin films

Aerogels are light and porous solids whose properties, largely determined by their nanostructure, are useful in a wide range of applications, e.g., thermal insulation. In this work, as-deposited and thermally treated air-filled silica aerogel thin films synthesized using the sol-gel method were stud...

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Main Authors: Leandro N. Acquaroli, Pascal Newby, Clara Santato, Yves-Alain Peter
Format: Article
Language:English
Published: AIP Publishing LLC 2016-10-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.4965921
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author Leandro N. Acquaroli
Pascal Newby
Clara Santato
Yves-Alain Peter
author_facet Leandro N. Acquaroli
Pascal Newby
Clara Santato
Yves-Alain Peter
author_sort Leandro N. Acquaroli
collection DOAJ
description Aerogels are light and porous solids whose properties, largely determined by their nanostructure, are useful in a wide range of applications, e.g., thermal insulation. In this work, as-deposited and thermally treated air-filled silica aerogel thin films synthesized using the sol-gel method were studied for their thermal properties using the 3-omega technique, at ambient conditions. The thermal conductivity and diffusivity were found to increase as the porosity of the aerogel decreased. Thermally treated films show a clear reduction in thermal conductivity compared with that of as-deposited films, likely due to an increase of porosity. The smallest thermal conductivity and diffusivity found for our aerogels were 0.019 W m−1 K−1 and 9.8 × 10-9 m2 s−1. A model was used to identify the components (solid, gaseous and radiative) of the total thermal conductivity of the aerogel.
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spelling doaj.art-4a990ecae6e34c879d481a0bad55bb722022-12-21T19:01:59ZengAIP Publishing LLCAIP Advances2158-32262016-10-01610105007105007-710.1063/1.4965921023610ADVThermal properties of methyltrimethoxysilane aerogel thin filmsLeandro N. Acquaroli0Pascal Newby1Clara Santato2Yves-Alain Peter3Department of Engineering Physics, Polytechnique Montreal, P.O. Box 6079, Station Centre-Ville, Montreal, Québec H3C 3A7, CanadaDepartment of Mechanical Engineering, Université de Sherbrooke, 3000 Bv. Université, Sherbrooke, Québec J1K 0A5, CanadaDepartment of Engineering Physics, Polytechnique Montreal, P.O. Box 6079, Station Centre-Ville, Montreal, Québec H3C 3A7, CanadaDepartment of Engineering Physics, Polytechnique Montreal, P.O. Box 6079, Station Centre-Ville, Montreal, Québec H3C 3A7, CanadaAerogels are light and porous solids whose properties, largely determined by their nanostructure, are useful in a wide range of applications, e.g., thermal insulation. In this work, as-deposited and thermally treated air-filled silica aerogel thin films synthesized using the sol-gel method were studied for their thermal properties using the 3-omega technique, at ambient conditions. The thermal conductivity and diffusivity were found to increase as the porosity of the aerogel decreased. Thermally treated films show a clear reduction in thermal conductivity compared with that of as-deposited films, likely due to an increase of porosity. The smallest thermal conductivity and diffusivity found for our aerogels were 0.019 W m−1 K−1 and 9.8 × 10-9 m2 s−1. A model was used to identify the components (solid, gaseous and radiative) of the total thermal conductivity of the aerogel.http://dx.doi.org/10.1063/1.4965921
spellingShingle Leandro N. Acquaroli
Pascal Newby
Clara Santato
Yves-Alain Peter
Thermal properties of methyltrimethoxysilane aerogel thin films
AIP Advances
title Thermal properties of methyltrimethoxysilane aerogel thin films
title_full Thermal properties of methyltrimethoxysilane aerogel thin films
title_fullStr Thermal properties of methyltrimethoxysilane aerogel thin films
title_full_unstemmed Thermal properties of methyltrimethoxysilane aerogel thin films
title_short Thermal properties of methyltrimethoxysilane aerogel thin films
title_sort thermal properties of methyltrimethoxysilane aerogel thin films
url http://dx.doi.org/10.1063/1.4965921
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