Structural studies and magnetism of Dy6Ni2.43Sn0.5 stannide

Intermetallic compound Dy6Ni2.43Sn0.5 was prepared by arc melting and annealing at 873 K. It was characterized by X-ray powder diffraction, differential thermal analysis, and electron probe microanalysis. The crystal structure of low temperature Dy6Ni2.43Sn0.5 phase belongs to the orthorhombic Ho6Co...

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Main Authors: L. Romaka, Kh. Miliyanchuk, V.V. Romaka, L. Havela, Y. Stadnyk
Format: Article
Language:English
Published: Vasyl Stefanyk Precarpathian National University 2023-06-01
Series:Фізика і хімія твердого тіла
Subjects:
Online Access:https://journals.pnu.edu.ua/index.php/pcss/article/view/6209
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author L. Romaka
Kh. Miliyanchuk
V.V. Romaka
L. Havela
Y. Stadnyk
author_facet L. Romaka
Kh. Miliyanchuk
V.V. Romaka
L. Havela
Y. Stadnyk
author_sort L. Romaka
collection DOAJ
description Intermetallic compound Dy6Ni2.43Sn0.5 was prepared by arc melting and annealing at 873 K. It was characterized by X-ray powder diffraction, differential thermal analysis, and electron probe microanalysis. The crystal structure of low temperature Dy6Ni2.43Sn0.5 phase belongs to the orthorhombic Ho6Co2Ga structure type (space group Immm, a = 0.93116(1) nm, b = 0.94993(1) nm, c = 0.98947(1) nm). Crystal structure refinements showed the deviation from the ideal 6:2:1 stoichiometry corresponding to the formula Dy6Ni2.43Sn0.5. It exhibits a sequence of magnetic phase transitions; antiferromagnetic ordering sets in at 60 K, while further order-order magnetic phase transitions take place at lower temperatures.
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spelling doaj.art-4a9e3749ca9f4d79b66aabfc294b39122023-09-19T08:42:35ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892023-06-0124228428910.15330/pcss.24.2.284-2896209Structural studies and magnetism of Dy6Ni2.43Sn0.5 stannideL. Romaka0Kh. Miliyanchuk1V.V. Romaka2L. Havela3Y. Stadnyk4Ivan Franko National University of Lviv, Lviv, UkraineIvan Franko National University of Lviv, Lviv, UkraineInstitute for Solid State Research, IFW-Dresden, Dresden, GermanyCharles University, Prague, Czech RepublicIvan Franko National University of Lviv, Lviv, UkraineIntermetallic compound Dy6Ni2.43Sn0.5 was prepared by arc melting and annealing at 873 K. It was characterized by X-ray powder diffraction, differential thermal analysis, and electron probe microanalysis. The crystal structure of low temperature Dy6Ni2.43Sn0.5 phase belongs to the orthorhombic Ho6Co2Ga structure type (space group Immm, a = 0.93116(1) nm, b = 0.94993(1) nm, c = 0.98947(1) nm). Crystal structure refinements showed the deviation from the ideal 6:2:1 stoichiometry corresponding to the formula Dy6Ni2.43Sn0.5. It exhibits a sequence of magnetic phase transitions; antiferromagnetic ordering sets in at 60 K, while further order-order magnetic phase transitions take place at lower temperatures.https://journals.pnu.edu.ua/index.php/pcss/article/view/6209intermetallicscrystal structuremagnetic propertiesheat capacity
spellingShingle L. Romaka
Kh. Miliyanchuk
V.V. Romaka
L. Havela
Y. Stadnyk
Structural studies and magnetism of Dy6Ni2.43Sn0.5 stannide
Фізика і хімія твердого тіла
intermetallics
crystal structure
magnetic properties
heat capacity
title Structural studies and magnetism of Dy6Ni2.43Sn0.5 stannide
title_full Structural studies and magnetism of Dy6Ni2.43Sn0.5 stannide
title_fullStr Structural studies and magnetism of Dy6Ni2.43Sn0.5 stannide
title_full_unstemmed Structural studies and magnetism of Dy6Ni2.43Sn0.5 stannide
title_short Structural studies and magnetism of Dy6Ni2.43Sn0.5 stannide
title_sort structural studies and magnetism of dy6ni2 43sn0 5 stannide
topic intermetallics
crystal structure
magnetic properties
heat capacity
url https://journals.pnu.edu.ua/index.php/pcss/article/view/6209
work_keys_str_mv AT lromaka structuralstudiesandmagnetismofdy6ni243sn05stannide
AT khmiliyanchuk structuralstudiesandmagnetismofdy6ni243sn05stannide
AT vvromaka structuralstudiesandmagnetismofdy6ni243sn05stannide
AT lhavela structuralstudiesandmagnetismofdy6ni243sn05stannide
AT ystadnyk structuralstudiesandmagnetismofdy6ni243sn05stannide