Catalyst-Dependent Chemoselectivity in the Dirhodium-Catalyzed Cyclization Reactions Between Enodiazoacetamide and Nitrosoarene: A Theoretical Study

Catalyst-Dependent Chemoselectivity in the Dirhodium-Catalyzed Cyclization Reactions Between Enodiazoacetamide and Nitrosoarene: A Theoretical Study

N-O heterocycle compounds play an important role in various fields. Doyle et al. (Cheng et al., 2017) have recently reported an efficient catalyst-controlled selective cyclization reactions of tert-butyldimethylsilyl (TBS)-protected enoldiazoacetamides with nitrosoarenes in which the multifunctional...

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Bibliographic Details
Main Authors: Yan Zhang, Yongsheng Yang, Ruyu Zhu, Xingyu Wang, Ying Xue
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-08-01
Series:Frontiers in Chemistry
Subjects:
DFT
mechanism
cyclization
dirhodium
chemoselectivity
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00586/full

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