Mesoionic tetrazolium-5-aminides: Synthesis, molecular and crystal structures, UV–vis spectra, and DFT calculations

Mesoionic tetrazolium-5-aminides: Synthesis, molecular and crystal structures, UV–vis spectra, and DFT calculations

Tetrazolium-5-aminides have been prepared by the tert-butylation of 5-aminotetrazole and its N-methyl derivatives by the t-BuOH/HClO4 system followed by the treatment of the tetrazolium salts by alkali. The mesoionic compounds have been found to show a higher reactivity of the exocyclic N atom in co...

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Bibliographic Details
Main Authors: Vladislav A. Budevich, Sergei V. Voitekhovich, Alexander V. Zuraev, Vadim E. Matulis, Vitaly E. Matulis, Alexander S. Lyakhov, Ludmila S. Ivashkevich, Oleg A. Ivashkevich
Format: Article
Language:English
Published: Beilstein-Institut 2021-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
aminotetrazoles
dft
mesoionic compounds
uv–vis spectra
x-ray analysis
Online Access:https://doi.org/10.3762/bjoc.17.34

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