Electric modulus of manganese doped cobalt ferrite nanoparticles

The electric modulus of manganese doped cobalt ferrite nanoparticles with the composition Co1-xMnxFe2O4 0.125≤x≤0.5 are reported in this communication. Due to heterogeneity in their microstructure, the characteristic frequency, determined from the dispersion of the imaginary portion of the electric...

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Main Authors: M.Z. Ahsan, M.M. Kamal, S.S. Rakhi, S.N. Tanha, G.I. Hasan
Format: Article
Language:English
Published: Elsevier 2023-07-01
Series:Results in Physics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2211379723003868
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author M.Z. Ahsan
M.M. Kamal
S.S. Rakhi
S.N. Tanha
G.I. Hasan
author_facet M.Z. Ahsan
M.M. Kamal
S.S. Rakhi
S.N. Tanha
G.I. Hasan
author_sort M.Z. Ahsan
collection DOAJ
description The electric modulus of manganese doped cobalt ferrite nanoparticles with the composition Co1-xMnxFe2O4 0.125≤x≤0.5 are reported in this communication. Due to heterogeneity in their microstructure, the characteristic frequency, determined from the dispersion of the imaginary portion of the electric modulus, does not pursue the rising trend in Mn content. Based on the Mn content, the Nyquist plot of complex electric modulus identifies the type of charge carriers that dominate the conduction phase. This dominance of carrier type can easily be identified from the Nyquist plots. As such, n-type (Fe2+/Fe3+) plays a dominant role in the hopping process for the sample of Mn content 0.5 across the grain boundaries in the B site. Conversely, the p-type (Co2+/Co3+) carriers are found to play their role in the hopping process across the grain boundaries for the sample of Mn content 0.125, 0.25, and 0.375.
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spelling doaj.art-4adb37a156b844e9aa6cc38b090c2f7a2023-06-17T05:18:16ZengElsevierResults in Physics2211-37972023-07-0150106593Electric modulus of manganese doped cobalt ferrite nanoparticlesM.Z. Ahsan0M.M. Kamal1S.S. Rakhi2S.N. Tanha3G.I. Hasan4Department of Physics, Bangladesh University of Engineering and Technology, Dhaka, Bangladesh; Departments of Chemistry and Physics, Gono Bishwabidyalay, Savar, Dhaka, Bangladesh; Corresponding author at: Department of Physics, Bangladesh University of Engineering and Technology, Dhaka, Bangladesh.Departments of Chemistry and Physics, Gono Bishwabidyalay, Savar, Dhaka, BangladeshDepartments of Chemistry and Physics, Gono Bishwabidyalay, Savar, Dhaka, BangladeshDepartments of Chemistry and Physics, Gono Bishwabidyalay, Savar, Dhaka, BangladeshDepartments of Chemistry and Physics, Gono Bishwabidyalay, Savar, Dhaka, BangladeshThe electric modulus of manganese doped cobalt ferrite nanoparticles with the composition Co1-xMnxFe2O4 0.125≤x≤0.5 are reported in this communication. Due to heterogeneity in their microstructure, the characteristic frequency, determined from the dispersion of the imaginary portion of the electric modulus, does not pursue the rising trend in Mn content. Based on the Mn content, the Nyquist plot of complex electric modulus identifies the type of charge carriers that dominate the conduction phase. This dominance of carrier type can easily be identified from the Nyquist plots. As such, n-type (Fe2+/Fe3+) plays a dominant role in the hopping process for the sample of Mn content 0.5 across the grain boundaries in the B site. Conversely, the p-type (Co2+/Co3+) carriers are found to play their role in the hopping process across the grain boundaries for the sample of Mn content 0.125, 0.25, and 0.375.http://www.sciencedirect.com/science/article/pii/S2211379723003868Cobalt ferritePermittivityElectric Modulus
spellingShingle M.Z. Ahsan
M.M. Kamal
S.S. Rakhi
S.N. Tanha
G.I. Hasan
Electric modulus of manganese doped cobalt ferrite nanoparticles
Results in Physics
Cobalt ferrite
Permittivity
Electric Modulus
title Electric modulus of manganese doped cobalt ferrite nanoparticles
title_full Electric modulus of manganese doped cobalt ferrite nanoparticles
title_fullStr Electric modulus of manganese doped cobalt ferrite nanoparticles
title_full_unstemmed Electric modulus of manganese doped cobalt ferrite nanoparticles
title_short Electric modulus of manganese doped cobalt ferrite nanoparticles
title_sort electric modulus of manganese doped cobalt ferrite nanoparticles
topic Cobalt ferrite
Permittivity
Electric Modulus
url http://www.sciencedirect.com/science/article/pii/S2211379723003868
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