Speciation of Six-Arsenic Species of Rice in Korea by HPLC/ICPMS
Determination of arsenic (As) speciation in rice is necessary because inorganic As species are more toxic than organic As. Arsenic levels of rice in Korea were determined by microwave extraction and High Performance Liquid Chromatography coupled with Inductively Coupled Plasma-Mass Spectrometry. The...
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| Format: | Article |
| Language: | English |
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EDP Sciences
2013-04-01
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| Series: | E3S Web of Conferences |
| Subjects: | |
| Online Access: | http://dx.doi.org/10.1051/e3sconf/20130139008 |
| _version_ | 1818875761953603584 |
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| author | Kim J.Y. Kim W.I. Yoo J.H. Lee J.H. Kunhikrishnan A. Kim D.H. |
| author_facet | Kim J.Y. Kim W.I. Yoo J.H. Lee J.H. Kunhikrishnan A. Kim D.H. |
| author_sort | Kim J.Y. |
| collection | DOAJ |
| description | Determination of arsenic (As) speciation in rice is necessary because inorganic As species are more toxic than organic As. Arsenic levels of rice in Korea were determined by microwave extraction and High Performance Liquid Chromatography coupled with Inductively Coupled Plasma-Mass Spectrometry. The extraction method showed a high recovery and low Limit of Detection (LOD) and Limit of Quantitation (LOQ). Most of the As species in rice were noticed to be inorganic [Arsenite (AsIII), Dimethylarsinic acid (DMA)]. The percentage of inorganic As/total As is 69.01 % (36.40-87.86 %). Arsenite and DMA were the major compounds in rice in Korea when compare to U.S. rice. The order and percentage of As species showed were AsIII (56-70 %)>DMA (23-38 %)>AsV (5 %)>MMA(1 %). |
| first_indexed | 2024-12-19T13:31:38Z |
| format | Article |
| id | doaj.art-4ae67c4b50d242f7ba3aa9e143cf19db |
| institution | Directory Open Access Journal |
| issn | 2267-1242 |
| language | English |
| last_indexed | 2024-12-19T13:31:38Z |
| publishDate | 2013-04-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | E3S Web of Conferences |
| spelling | doaj.art-4ae67c4b50d242f7ba3aa9e143cf19db2022-12-21T20:19:21ZengEDP SciencesE3S Web of Conferences2267-12422013-04-0113900810.1051/e3sconf/20130139008Speciation of Six-Arsenic Species of Rice in Korea by HPLC/ICPMSKim J.Y.Kim W.I.Yoo J.H.Lee J.H.Kunhikrishnan A.Kim D.H.Determination of arsenic (As) speciation in rice is necessary because inorganic As species are more toxic than organic As. Arsenic levels of rice in Korea were determined by microwave extraction and High Performance Liquid Chromatography coupled with Inductively Coupled Plasma-Mass Spectrometry. The extraction method showed a high recovery and low Limit of Detection (LOD) and Limit of Quantitation (LOQ). Most of the As species in rice were noticed to be inorganic [Arsenite (AsIII), Dimethylarsinic acid (DMA)]. The percentage of inorganic As/total As is 69.01 % (36.40-87.86 %). Arsenite and DMA were the major compounds in rice in Korea when compare to U.S. rice. The order and percentage of As species showed were AsIII (56-70 %)>DMA (23-38 %)>AsV (5 %)>MMA(1 %).http://dx.doi.org/10.1051/e3sconf/20130139008SpeciationArsenic speciesHPLC/ICPMSRice |
| spellingShingle | Kim J.Y. Kim W.I. Yoo J.H. Lee J.H. Kunhikrishnan A. Kim D.H. Speciation of Six-Arsenic Species of Rice in Korea by HPLC/ICPMS E3S Web of Conferences Speciation Arsenic species HPLC/ICPMS Rice |
| title | Speciation of Six-Arsenic Species of Rice in Korea by HPLC/ICPMS |
| title_full | Speciation of Six-Arsenic Species of Rice in Korea by HPLC/ICPMS |
| title_fullStr | Speciation of Six-Arsenic Species of Rice in Korea by HPLC/ICPMS |
| title_full_unstemmed | Speciation of Six-Arsenic Species of Rice in Korea by HPLC/ICPMS |
| title_short | Speciation of Six-Arsenic Species of Rice in Korea by HPLC/ICPMS |
| title_sort | speciation of six arsenic species of rice in korea by hplc icpms |
| topic | Speciation Arsenic species HPLC/ICPMS Rice |
| url | http://dx.doi.org/10.1051/e3sconf/20130139008 |
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