Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp 3)–heteroatom bonds
The development of new methodologies for the construction of C(sp 3)–heteroatom bonds under mild conditions is desirable. Here the authors report the formation of C(sp 3)–heteroatom bonds via ring opening of arylcyclopropanes enabled by photoredox catalysis.
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-10-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-33602-4 |
| _version_ | 1811226671604301824 |
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| author | Liang Ge Chi Zhang Chengkai Pan Ding-Xing Wang Dong-Ying Liu Zhi-Qiang Li Pingkang Shen Lifang Tian Chao Feng |
| author_facet | Liang Ge Chi Zhang Chengkai Pan Ding-Xing Wang Dong-Ying Liu Zhi-Qiang Li Pingkang Shen Lifang Tian Chao Feng |
| author_sort | Liang Ge |
| collection | DOAJ |
| description | The development of new methodologies for the construction of C(sp 3)–heteroatom bonds under mild conditions is desirable. Here the authors report the formation of C(sp 3)–heteroatom bonds via ring opening of arylcyclopropanes enabled by photoredox catalysis. |
| first_indexed | 2024-04-12T09:29:05Z |
| format | Article |
| id | doaj.art-4ae8889c7b904a2fa03051fa72477de2 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-12T09:29:05Z |
| publishDate | 2022-10-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-4ae8889c7b904a2fa03051fa72477de22022-12-22T03:38:24ZengNature PortfolioNature Communications2041-17232022-10-0113111310.1038/s41467-022-33602-4Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp 3)–heteroatom bondsLiang Ge0Chi Zhang1Chengkai Pan2Ding-Xing Wang3Dong-Ying Liu4Zhi-Qiang Li5Pingkang Shen6Lifang Tian7Chao Feng8Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech UniversityTechnical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech UniversityTechnical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech UniversityTechnical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech UniversityTechnical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech UniversityTechnical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech UniversityTechnical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech UniversityTechnical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech UniversityTechnical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS), School of Chemistry and Molecular Engineering, State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech UniversityThe development of new methodologies for the construction of C(sp 3)–heteroatom bonds under mild conditions is desirable. Here the authors report the formation of C(sp 3)–heteroatom bonds via ring opening of arylcyclopropanes enabled by photoredox catalysis.https://doi.org/10.1038/s41467-022-33602-4 |
| spellingShingle | Liang Ge Chi Zhang Chengkai Pan Ding-Xing Wang Dong-Ying Liu Zhi-Qiang Li Pingkang Shen Lifang Tian Chao Feng Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp 3)–heteroatom bonds Nature Communications |
| title | Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp 3)–heteroatom bonds |
| title_full | Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp 3)–heteroatom bonds |
| title_fullStr | Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp 3)–heteroatom bonds |
| title_full_unstemmed | Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp 3)–heteroatom bonds |
| title_short | Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp 3)–heteroatom bonds |
| title_sort | photoredox catalyzed c c bond cleavage of cyclopropanes for the formation of c sp 3 heteroatom bonds |
| url | https://doi.org/10.1038/s41467-022-33602-4 |
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