Optical, Geochemical and Mineralogical Characteristics of Light-Absorbing Impurities Deposited on Djankuat Glacier in the Caucasus Mountains

Supra-glacial material, including light-absorbing impurities (LAI) such as mineral dust of crustal and soil origin, black carbon, algae and cryoconite, reduce the reflectance of snow and glacier ice. The reduction depends on the amount of LAI and their physical and chemical properties, which vary sp...

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Main Authors: Stanislav Kutuzov, Maria Shahgedanova, Viktoria Krupskaya, Sergey Goryachkin
Format: Article
Language:English
Published: MDPI AG 2021-10-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/13/21/2993
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author Stanislav Kutuzov
Maria Shahgedanova
Viktoria Krupskaya
Sergey Goryachkin
author_facet Stanislav Kutuzov
Maria Shahgedanova
Viktoria Krupskaya
Sergey Goryachkin
author_sort Stanislav Kutuzov
collection DOAJ
description Supra-glacial material, including light-absorbing impurities (LAI) such as mineral dust of crustal and soil origin, black carbon, algae and cryoconite, reduce the reflectance of snow and glacier ice. The reduction depends on the amount of LAI and their physical and chemical properties, which vary spatially and temporally. Spectral reflectance data and snow and ice samples, containing LAI, were collected in the ablation zone of the Djankuat Glacier, Central Caucasus, Russia. The spectra of the samples containing mineral dust transported from deserts were characterized by negative visible near-infrared gradients and were different from the spectra of clean aged snow and exposed glacier ice and from the samples containing mineral dust produced locally. Geochemical and mineralogical analysis using X-ray diffraction and X-ray fluorescence spectrometry showed that samples containing desert dust were characterised by a high proportion of clay materials and such minerals as smectites, illite–smectites and palygorskite and by a smaller size of mineral particles. They were enriched in chromium, zinc and vanadium. The latter served as an indicator of dust transport over or origin from the oil-producing regions of the Middle East. There was a strong negative correlation between the amount of organic matter and mineral dust in the collected samples and the albedo of surfaces from which the samples were collected. The results suggested that organic matter reduced albedo more efficiently than mineral dust. The study highlighted the importance of supra-glacial material in changing the surface reflectivity of snow and glaciers in the Caucasus region.
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spelling doaj.art-4af7760ba7b548fb87d2e92e918d54a92023-11-22T21:53:42ZengMDPI AGWater2073-44412021-10-011321299310.3390/w13212993Optical, Geochemical and Mineralogical Characteristics of Light-Absorbing Impurities Deposited on Djankuat Glacier in the Caucasus MountainsStanislav Kutuzov0Maria Shahgedanova1Viktoria Krupskaya2Sergey Goryachkin3Institute of Geography, Russian Academy of Sciences, 119017 Moscow, RussiaDepartment of Geography and Environmental Science, University of Reading, Whiteknights RG6 6AB, UKInstitute of Geology of Ore Deposits, Petrology, Mineralogy and Geochemistry of the Russian Academy of Sciences, 119017 Moscow, RussiaInstitute of Geography, Russian Academy of Sciences, 119017 Moscow, RussiaSupra-glacial material, including light-absorbing impurities (LAI) such as mineral dust of crustal and soil origin, black carbon, algae and cryoconite, reduce the reflectance of snow and glacier ice. The reduction depends on the amount of LAI and their physical and chemical properties, which vary spatially and temporally. Spectral reflectance data and snow and ice samples, containing LAI, were collected in the ablation zone of the Djankuat Glacier, Central Caucasus, Russia. The spectra of the samples containing mineral dust transported from deserts were characterized by negative visible near-infrared gradients and were different from the spectra of clean aged snow and exposed glacier ice and from the samples containing mineral dust produced locally. Geochemical and mineralogical analysis using X-ray diffraction and X-ray fluorescence spectrometry showed that samples containing desert dust were characterised by a high proportion of clay materials and such minerals as smectites, illite–smectites and palygorskite and by a smaller size of mineral particles. They were enriched in chromium, zinc and vanadium. The latter served as an indicator of dust transport over or origin from the oil-producing regions of the Middle East. There was a strong negative correlation between the amount of organic matter and mineral dust in the collected samples and the albedo of surfaces from which the samples were collected. The results suggested that organic matter reduced albedo more efficiently than mineral dust. The study highlighted the importance of supra-glacial material in changing the surface reflectivity of snow and glaciers in the Caucasus region.https://www.mdpi.com/2073-4441/13/21/2993light-absorbing impuritiesmineral dustspectral reflectancealbedoglaciersCaucasus
spellingShingle Stanislav Kutuzov
Maria Shahgedanova
Viktoria Krupskaya
Sergey Goryachkin
Optical, Geochemical and Mineralogical Characteristics of Light-Absorbing Impurities Deposited on Djankuat Glacier in the Caucasus Mountains
Water
light-absorbing impurities
mineral dust
spectral reflectance
albedo
glaciers
Caucasus
title Optical, Geochemical and Mineralogical Characteristics of Light-Absorbing Impurities Deposited on Djankuat Glacier in the Caucasus Mountains
title_full Optical, Geochemical and Mineralogical Characteristics of Light-Absorbing Impurities Deposited on Djankuat Glacier in the Caucasus Mountains
title_fullStr Optical, Geochemical and Mineralogical Characteristics of Light-Absorbing Impurities Deposited on Djankuat Glacier in the Caucasus Mountains
title_full_unstemmed Optical, Geochemical and Mineralogical Characteristics of Light-Absorbing Impurities Deposited on Djankuat Glacier in the Caucasus Mountains
title_short Optical, Geochemical and Mineralogical Characteristics of Light-Absorbing Impurities Deposited on Djankuat Glacier in the Caucasus Mountains
title_sort optical geochemical and mineralogical characteristics of light absorbing impurities deposited on djankuat glacier in the caucasus mountains
topic light-absorbing impurities
mineral dust
spectral reflectance
albedo
glaciers
Caucasus
url https://www.mdpi.com/2073-4441/13/21/2993
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