Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages
Coordination driven self-assembly of achiral components, i.e., hexa-alkylated truxene ligands (L) with bis-metallic complexes (M<sub>2</sub>), afforded three chiral face-rotating stereoisomer polyhedra (M<sub>6</sub>L<sub>2</sub>). By tuning the length of the alky...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-07-01
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| Series: | Inorganics |
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| Online Access: | https://www.mdpi.com/2304-6740/10/7/103 |
| _version_ | 1827618859987763200 |
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| author | Amina Benchohra Simon Séjourné Antoine Labrunie Liam Miller Enzo Charbonneau Vincent Carré Frédéric Aubriet Magali Allain Marc Sallé Sébastien Goeb |
| author_facet | Amina Benchohra Simon Séjourné Antoine Labrunie Liam Miller Enzo Charbonneau Vincent Carré Frédéric Aubriet Magali Allain Marc Sallé Sébastien Goeb |
| author_sort | Amina Benchohra |
| collection | DOAJ |
| description | Coordination driven self-assembly of achiral components, i.e., hexa-alkylated truxene ligands (L) with bis-metallic complexes (M<sub>2</sub>), afforded three chiral face-rotating stereoisomer polyhedra (M<sub>6</sub>L<sub>2</sub>). By tuning the length of the alkyl chains as well as the distance between both ligands facing each other in the self-assemblies (M<sub>6</sub>L<sub>2</sub>), one can control the diastereomeric distribution between the expected homo- and hetero-chiral structures. |
| first_indexed | 2024-03-09T10:17:12Z |
| format | Article |
| id | doaj.art-4afbfbe65124447293704b628b5cf557 |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-03-09T10:17:12Z |
| publishDate | 2022-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-4afbfbe65124447293704b628b5cf5572023-12-01T22:17:07ZengMDPI AGInorganics2304-67402022-07-0110710310.3390/inorganics10070103Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled CagesAmina Benchohra0Simon Séjourné1Antoine Labrunie2Liam Miller3Enzo Charbonneau4Vincent Carré5Frédéric Aubriet6Magali Allain7Marc Sallé8Sébastien Goeb9Laboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, SFR MATRIX, 2 Bd Lavoisier, 49045 Angers, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, SFR MATRIX, 2 Bd Lavoisier, 49045 Angers, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, SFR MATRIX, 2 Bd Lavoisier, 49045 Angers, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, SFR MATRIX, 2 Bd Lavoisier, 49045 Angers, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, SFR MATRIX, 2 Bd Lavoisier, 49045 Angers, FranceLCP-A2MC, FR 2843 Institut Jean Barriol de Chimie et Physique Moléculaires et Biomoléculaires, FR 3624 Réseau National de Spectrométrie de Masse FT-ICR à très haut champ, Université de Lorraine, ICPM, 1 Boulevard Arago, CEDEX 03, 57078 Metz, FranceLCP-A2MC, FR 2843 Institut Jean Barriol de Chimie et Physique Moléculaires et Biomoléculaires, FR 3624 Réseau National de Spectrométrie de Masse FT-ICR à très haut champ, Université de Lorraine, ICPM, 1 Boulevard Arago, CEDEX 03, 57078 Metz, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, SFR MATRIX, 2 Bd Lavoisier, 49045 Angers, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, SFR MATRIX, 2 Bd Lavoisier, 49045 Angers, FranceLaboratoire MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, SFR MATRIX, 2 Bd Lavoisier, 49045 Angers, FranceCoordination driven self-assembly of achiral components, i.e., hexa-alkylated truxene ligands (L) with bis-metallic complexes (M<sub>2</sub>), afforded three chiral face-rotating stereoisomer polyhedra (M<sub>6</sub>L<sub>2</sub>). By tuning the length of the alkyl chains as well as the distance between both ligands facing each other in the self-assemblies (M<sub>6</sub>L<sub>2</sub>), one can control the diastereomeric distribution between the expected homo- and hetero-chiral structures.https://www.mdpi.com/2304-6740/10/7/103supramolecular chemistryself-assemblyself-sortingmetalla-cagechiralitytruxene |
| spellingShingle | Amina Benchohra Simon Séjourné Antoine Labrunie Liam Miller Enzo Charbonneau Vincent Carré Frédéric Aubriet Magali Allain Marc Sallé Sébastien Goeb Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages Inorganics supramolecular chemistry self-assembly self-sorting metalla-cage chirality truxene |
| title | Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages |
| title_full | Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages |
| title_fullStr | Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages |
| title_full_unstemmed | Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages |
| title_short | Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages |
| title_sort | controlling chiral self sorting in truxene based self assembled cages |
| topic | supramolecular chemistry self-assembly self-sorting metalla-cage chirality truxene |
| url | https://www.mdpi.com/2304-6740/10/7/103 |
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