Nanogranular Strontium Ferromolybdate/Strontium Molybdate Ceramics—A Magnetic Material Possessing a Natural Core-Shell Structure

In this work, we demonstrate the preparation of easy-to-fabricate nanogranular strontium ferromolybdate/strontium molybdate core-shell ceramics and examine their properties, including tunnel magnetoresistance, magnetic field sensitivity, and temperature coefficient of the tunnel magnetoresistance. T...

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Main Authors: Gunnar Suchaneck, Evgenii Artiukh, Nikolay Kalanda, Marta Yarmolich, Gerald Gerlach
Format: Article
Language:English
Published: MDPI AG 2024-01-01
Series:Electronic Materials
Subjects:
Online Access:https://www.mdpi.com/2673-3978/5/1/1
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author Gunnar Suchaneck
Evgenii Artiukh
Nikolay Kalanda
Marta Yarmolich
Gerald Gerlach
author_facet Gunnar Suchaneck
Evgenii Artiukh
Nikolay Kalanda
Marta Yarmolich
Gerald Gerlach
author_sort Gunnar Suchaneck
collection DOAJ
description In this work, we demonstrate the preparation of easy-to-fabricate nanogranular strontium ferromolybdate/strontium molybdate core-shell ceramics and examine their properties, including tunnel magnetoresistance, magnetic field sensitivity, and temperature coefficient of the tunnel magnetoresistance. The tunnel magnetoresistance of nanogranular strontium ferromolybdate/strontium molybdate core-shell ceramics was modeled, yielding values suitable for magnetoresistive sensor applications. Such structures possess a narrow peak of magnetic flux sensibility located at about 80 mT. For magnetic flux measurement, single-domain granules with superparamagnetic behavior should be applied. The predicted TMR magnetic flux sensitivities for granules with superparamagnetic behavior amount to about 7.7% T<sup>−1</sup> and 1.5% T<sup>−1</sup> for granule sizes of 3 nm and 5 nm, respectively. A drawback of the tunnel magnetoresistance of such nanogranular core-shell ceramics is the unacceptably large value of the temperature coefficient. Acceptable values, lower than 2% K<sup>−1</sup>, are obtained only at low temperatures (less than 100 K) or large magnetic flux densities (exceeding 6 T). Therefore, a Wheatstone bridge configuration should be adopted for magnetoresistive sensor design to compensate for the effect of temperature.
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spelling doaj.art-4b11324219d84c7e9d4e9208e12f65cd2024-03-27T13:34:42ZengMDPI AGElectronic Materials2673-39782024-01-015111610.3390/electronicmat5010001Nanogranular Strontium Ferromolybdate/Strontium Molybdate Ceramics—A Magnetic Material Possessing a Natural Core-Shell StructureGunnar Suchaneck0Evgenii Artiukh1Nikolay Kalanda2Marta Yarmolich3Gerald Gerlach4Solid-State Electronics Laboratory, TU Dresden, 01062 Dresden, GermanyCryogenic Research Division, SSPA “Scientific-Practical Materials Research Centre of NAS of Belarus”, 220072 Minsk, BelarusCryogenic Research Division, SSPA “Scientific-Practical Materials Research Centre of NAS of Belarus”, 220072 Minsk, BelarusCryogenic Research Division, SSPA “Scientific-Practical Materials Research Centre of NAS of Belarus”, 220072 Minsk, BelarusSolid-State Electronics Laboratory, TU Dresden, 01062 Dresden, GermanyIn this work, we demonstrate the preparation of easy-to-fabricate nanogranular strontium ferromolybdate/strontium molybdate core-shell ceramics and examine their properties, including tunnel magnetoresistance, magnetic field sensitivity, and temperature coefficient of the tunnel magnetoresistance. The tunnel magnetoresistance of nanogranular strontium ferromolybdate/strontium molybdate core-shell ceramics was modeled, yielding values suitable for magnetoresistive sensor applications. Such structures possess a narrow peak of magnetic flux sensibility located at about 80 mT. For magnetic flux measurement, single-domain granules with superparamagnetic behavior should be applied. The predicted TMR magnetic flux sensitivities for granules with superparamagnetic behavior amount to about 7.7% T<sup>−1</sup> and 1.5% T<sup>−1</sup> for granule sizes of 3 nm and 5 nm, respectively. A drawback of the tunnel magnetoresistance of such nanogranular core-shell ceramics is the unacceptably large value of the temperature coefficient. Acceptable values, lower than 2% K<sup>−1</sup>, are obtained only at low temperatures (less than 100 K) or large magnetic flux densities (exceeding 6 T). Therefore, a Wheatstone bridge configuration should be adopted for magnetoresistive sensor design to compensate for the effect of temperature.https://www.mdpi.com/2673-3978/5/1/1strontium ferromolybdatenanogranular structurecore-shell ceramicstunnel magnetoresistancemagnetic flux sensitivitytemperature coefficient
spellingShingle Gunnar Suchaneck
Evgenii Artiukh
Nikolay Kalanda
Marta Yarmolich
Gerald Gerlach
Nanogranular Strontium Ferromolybdate/Strontium Molybdate Ceramics—A Magnetic Material Possessing a Natural Core-Shell Structure
Electronic Materials
strontium ferromolybdate
nanogranular structure
core-shell ceramics
tunnel magnetoresistance
magnetic flux sensitivity
temperature coefficient
title Nanogranular Strontium Ferromolybdate/Strontium Molybdate Ceramics—A Magnetic Material Possessing a Natural Core-Shell Structure
title_full Nanogranular Strontium Ferromolybdate/Strontium Molybdate Ceramics—A Magnetic Material Possessing a Natural Core-Shell Structure
title_fullStr Nanogranular Strontium Ferromolybdate/Strontium Molybdate Ceramics—A Magnetic Material Possessing a Natural Core-Shell Structure
title_full_unstemmed Nanogranular Strontium Ferromolybdate/Strontium Molybdate Ceramics—A Magnetic Material Possessing a Natural Core-Shell Structure
title_short Nanogranular Strontium Ferromolybdate/Strontium Molybdate Ceramics—A Magnetic Material Possessing a Natural Core-Shell Structure
title_sort nanogranular strontium ferromolybdate strontium molybdate ceramics a magnetic material possessing a natural core shell structure
topic strontium ferromolybdate
nanogranular structure
core-shell ceramics
tunnel magnetoresistance
magnetic flux sensitivity
temperature coefficient
url https://www.mdpi.com/2673-3978/5/1/1
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AT nikolaykalanda nanogranularstrontiumferromolybdatestrontiummolybdateceramicsamagneticmaterialpossessinganaturalcoreshellstructure
AT martayarmolich nanogranularstrontiumferromolybdatestrontiummolybdateceramicsamagneticmaterialpossessinganaturalcoreshellstructure
AT geraldgerlach nanogranularstrontiumferromolybdatestrontiummolybdateceramicsamagneticmaterialpossessinganaturalcoreshellstructure