Improvement of a method for the correction of wall slip effects within the rheological measurements of filled rubber compounds

Abstract Rubber compounds have an increased tendency to flow anomalies depending on the compound ingredients and the processing parameters. Due to wall slip effects, rheological material measurements and the material parameters derived from them are affected by errors, since the fundamental analytic...

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Main Authors: Dennis Kleinschmidt, Volker Schöppner
Format: Article
Language:English
Published: Wiley 2023-04-01
Series:SPE Polymers
Subjects:
Online Access:https://doi.org/10.1002/pls2.10087
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author Dennis Kleinschmidt
Volker Schöppner
author_facet Dennis Kleinschmidt
Volker Schöppner
author_sort Dennis Kleinschmidt
collection DOAJ
description Abstract Rubber compounds have an increased tendency to flow anomalies depending on the compound ingredients and the processing parameters. Due to wall slip effects, rheological material measurements and the material parameters derived from them are affected by errors, since the fundamental analytical and numerical calculation approaches assume wall adhesion. In the literature, various approaches for the description of wall slip effects exist, which partially lead to negative slip velocities as well as slip volume flows that exceed the total volume flow in the capillary. The purpose of this article is the improvement of an analytical model for the determination of slip velocities for both laboratory and near‐process rheological investigations. A comparison shows the limitations of the established wall slip correction methods and the possibilities of the improved correction method.
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spelling doaj.art-4b17bbd4a5f543d99e155ede7587781d2023-04-17T12:20:29ZengWileySPE Polymers2690-38572023-04-0142637910.1002/pls2.10087Improvement of a method for the correction of wall slip effects within the rheological measurements of filled rubber compoundsDennis Kleinschmidt0Volker Schöppner1Polymer Engineering Paderborn Paderborn University Paderborn GermanyPolymer Engineering Paderborn Paderborn University Paderborn GermanyAbstract Rubber compounds have an increased tendency to flow anomalies depending on the compound ingredients and the processing parameters. Due to wall slip effects, rheological material measurements and the material parameters derived from them are affected by errors, since the fundamental analytical and numerical calculation approaches assume wall adhesion. In the literature, various approaches for the description of wall slip effects exist, which partially lead to negative slip velocities as well as slip volume flows that exceed the total volume flow in the capillary. The purpose of this article is the improvement of an analytical model for the determination of slip velocities for both laboratory and near‐process rheological investigations. A comparison shows the limitations of the established wall slip correction methods and the possibilities of the improved correction method.https://doi.org/10.1002/pls2.10087extrusionrheologyrubberviscosity
spellingShingle Dennis Kleinschmidt
Volker Schöppner
Improvement of a method for the correction of wall slip effects within the rheological measurements of filled rubber compounds
SPE Polymers
extrusion
rheology
rubber
viscosity
title Improvement of a method for the correction of wall slip effects within the rheological measurements of filled rubber compounds
title_full Improvement of a method for the correction of wall slip effects within the rheological measurements of filled rubber compounds
title_fullStr Improvement of a method for the correction of wall slip effects within the rheological measurements of filled rubber compounds
title_full_unstemmed Improvement of a method for the correction of wall slip effects within the rheological measurements of filled rubber compounds
title_short Improvement of a method for the correction of wall slip effects within the rheological measurements of filled rubber compounds
title_sort improvement of a method for the correction of wall slip effects within the rheological measurements of filled rubber compounds
topic extrusion
rheology
rubber
viscosity
url https://doi.org/10.1002/pls2.10087
work_keys_str_mv AT denniskleinschmidt improvementofamethodforthecorrectionofwallslipeffectswithintherheologicalmeasurementsoffilledrubbercompounds
AT volkerschoppner improvementofamethodforthecorrectionofwallslipeffectswithintherheologicalmeasurementsoffilledrubbercompounds