| Summary: | The suitability of CaCl<sub>2</sub> as a mineralizing agent in the synthesis of a low-temperature C<sub>2</sub>S-cement clinker from wastes of autoclaved aerated concrete was investigated. As chlorellestadite is a potential host mineral for the immobilization of chlorine, the formation conditions for the highest joint content of chlorellestadite and C<sub>2</sub>S were studied in samples with different sulfate contents. Oven experiments were conducted at temperatures between 700 and 1200 °C. The samples were analyzed by X-ray diffraction in combination with chemical and thermal analysis and Raman spectroscopy. Calculation of the yield of C<sub>2</sub>S and ellestadite for all samples proves the optimum temperature range for the C<sub>2</sub>S-ellestadite clinker from 950 to 1000 °C. At lower temperatures, the formation of a carbonate-rich halogenide melt promotes the crystallization of a significant amount of spurrite at the expense of C<sub>2</sub>S. Ellestadite formation mainly depends on the sulfate content and to a lesser extent on the synthesis temperature. However, at higher temperatures, with ternesite another sulfate coexists in sulfate-rich samples at the expense of ellestadite. In addition, distinct evidence for non-stoichiometry and carbonate substitution in the structure of low-temperature ellestadite was found. Low sulfate content leads to the crystallization of Ca<sub>10</sub>[Si<sub>2</sub>O<sub>7</sub>]<sub>3</sub>Cl<sub>2</sub> at higher temperatures. In all samples treated at temperatures above 1000 °C chlorine loss starts. Its extent decreases with increasing sulfate content.
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