Composite Carbon Foams as an Alternative to the Conventional Biomass-Derived Activated Carbon in Catalytic Application

The suitability of a new type of polyurethane-based composite carbon foam for several possible usages is evaluated and reported. A comparison of the properties of the as-prepared carbon foams was performed with widely available commercial biomass-derived activated carbon. Carbon foams were synthesiz...

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Bibliographic Details
Main Authors: Mahitha Udayakumar, Renáta Zsanett Boros, László Farkas, Andrea Simon, Tamás Koós, Máté Leskó, Anett Katalin Leskó, Klara Hernadi, Zoltán Németh
Format: Article
Language:English
Published: MDPI AG 2021-08-01
Series:Materials
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Online Access:https://www.mdpi.com/1996-1944/14/16/4540
Description
Summary:The suitability of a new type of polyurethane-based composite carbon foam for several possible usages is evaluated and reported. A comparison of the properties of the as-prepared carbon foams was performed with widely available commercial biomass-derived activated carbon. Carbon foams were synthesized from polyurethane foams with different graphite contents through one-step activation using CO<sub>2</sub>. In this work, a carbon catalyst was synthesized with a moderately active surface (S<sub>BET</sub> = 554 m<sup>2</sup>/g), a thermal conductivity of 0.09 W/mK, and a minimum metal ion content of 0.2 wt%, which can be recommended for phosgene production. The composite carbon foams exhibited better thermal stability, as there is a very little weight loss at temperatures below 500 °C, and weight loss is slower at temperatures above 500 °C (phosgene synthesis: 550–700 °C). Owing to the good surface and thermal properties and the negligible metallic impurities, composite carbon foam produced from polyurethane foams are the best alternative to the conventional coconut-based activated carbon catalyst used in phosgene gas production.
ISSN:1996-1944