Enhancing the Performance of Ceramic-Rich Polymer Composite Electrolytes Using Polymer Grafted LLZO
Solid-state batteries are the holy grail for the next generation of automotive batteries. The development of solid-state batteries requires efficient electrolytes to improve the performance of the cells in terms of ionic conductivity, electrochemical stability, interfacial compatibility, and so on....
| Main Authors: | , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2022-06-01
|
| Series: | Inorganics |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2304-6740/10/6/81 |
| _version_ | 1797486216674803712 |
|---|---|
| author | Pierre Ranque Jakub Zagórski Grazia Accardo Ander Orue Mendizabal Juan Miguel López del Amo Nicola Boaretto Maria Martinez-Ibañez Hugo Arrou-Vignod Frederic Aguesse Michel Armand Shanmukaraj Devaraj |
| author_facet | Pierre Ranque Jakub Zagórski Grazia Accardo Ander Orue Mendizabal Juan Miguel López del Amo Nicola Boaretto Maria Martinez-Ibañez Hugo Arrou-Vignod Frederic Aguesse Michel Armand Shanmukaraj Devaraj |
| author_sort | Pierre Ranque |
| collection | DOAJ |
| description | Solid-state batteries are the holy grail for the next generation of automotive batteries. The development of solid-state batteries requires efficient electrolytes to improve the performance of the cells in terms of ionic conductivity, electrochemical stability, interfacial compatibility, and so on. These requirements call for the combined properties of ceramic and polymer electrolytes, making ceramic-rich polymer electrolytes a promising solution to be developed. Aligned with this aim, we have shown a surface modification of Ga substituted Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> (LLZO), to be an essential strategy for the preparation of ceramic-rich electrolytes. Ceramic-rich polymer membranes with surface-modified LLZO show marked improvements in the performance, in terms of electrolyte physical and electrochemical properties, as well as coulombic efficiency, interfacial compatibility, and cyclability of solid-state cells. |
| first_indexed | 2024-03-09T23:30:05Z |
| format | Article |
| id | doaj.art-4b522d1b93484a59baf5094af797a19a |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-03-09T23:30:05Z |
| publishDate | 2022-06-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-4b522d1b93484a59baf5094af797a19a2023-11-23T17:10:34ZengMDPI AGInorganics2304-67402022-06-011068110.3390/inorganics10060081Enhancing the Performance of Ceramic-Rich Polymer Composite Electrolytes Using Polymer Grafted LLZOPierre Ranque0Jakub Zagórski1Grazia Accardo2Ander Orue Mendizabal3Juan Miguel López del Amo4Nicola Boaretto5Maria Martinez-Ibañez6Hugo Arrou-Vignod7Frederic Aguesse8Michel Armand9Shanmukaraj Devaraj10Centre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainCentre for Cooperative Research on Alternative Energies (CIC energiGUNE), Basque Research and Technology Alliance (BRTA), Alava Technology Park, 01510 Vitoria-Gasteiz, SpainSolid-state batteries are the holy grail for the next generation of automotive batteries. The development of solid-state batteries requires efficient electrolytes to improve the performance of the cells in terms of ionic conductivity, electrochemical stability, interfacial compatibility, and so on. These requirements call for the combined properties of ceramic and polymer electrolytes, making ceramic-rich polymer electrolytes a promising solution to be developed. Aligned with this aim, we have shown a surface modification of Ga substituted Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> (LLZO), to be an essential strategy for the preparation of ceramic-rich electrolytes. Ceramic-rich polymer membranes with surface-modified LLZO show marked improvements in the performance, in terms of electrolyte physical and electrochemical properties, as well as coulombic efficiency, interfacial compatibility, and cyclability of solid-state cells.https://www.mdpi.com/2304-6740/10/6/81polymer graftingcomposite electrolyteceramic-richsolid-state batteriesLLZOstrategy |
| spellingShingle | Pierre Ranque Jakub Zagórski Grazia Accardo Ander Orue Mendizabal Juan Miguel López del Amo Nicola Boaretto Maria Martinez-Ibañez Hugo Arrou-Vignod Frederic Aguesse Michel Armand Shanmukaraj Devaraj Enhancing the Performance of Ceramic-Rich Polymer Composite Electrolytes Using Polymer Grafted LLZO Inorganics polymer grafting composite electrolyte ceramic-rich solid-state batteries LLZO strategy |
| title | Enhancing the Performance of Ceramic-Rich Polymer Composite Electrolytes Using Polymer Grafted LLZO |
| title_full | Enhancing the Performance of Ceramic-Rich Polymer Composite Electrolytes Using Polymer Grafted LLZO |
| title_fullStr | Enhancing the Performance of Ceramic-Rich Polymer Composite Electrolytes Using Polymer Grafted LLZO |
| title_full_unstemmed | Enhancing the Performance of Ceramic-Rich Polymer Composite Electrolytes Using Polymer Grafted LLZO |
| title_short | Enhancing the Performance of Ceramic-Rich Polymer Composite Electrolytes Using Polymer Grafted LLZO |
| title_sort | enhancing the performance of ceramic rich polymer composite electrolytes using polymer grafted llzo |
| topic | polymer grafting composite electrolyte ceramic-rich solid-state batteries LLZO strategy |
| url | https://www.mdpi.com/2304-6740/10/6/81 |
| work_keys_str_mv | AT pierreranque enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo AT jakubzagorski enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo AT graziaaccardo enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo AT anderoruemendizabal enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo AT juanmiguellopezdelamo enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo AT nicolaboaretto enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo AT mariamartinezibanez enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo AT hugoarrouvignod enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo AT fredericaguesse enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo AT michelarmand enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo AT shanmukarajdevaraj enhancingtheperformanceofceramicrichpolymercompositeelectrolytesusingpolymergraftedllzo |