Gas Nitriding of the Near-Beta-Titanium Alloy

The present research investigates the nitriding kinetics of the near-beta-titanium alloy of Ti-Al-Nb-Fe-Zr-Mo-V system at 750, 800, and 850°C in gaseous nitrogen at 10 5 Pa for 2, 4, and 8 h. The parabolic coefficient kp of the layer’s growth rate and the nitriding activation energy E are set as the...

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Main Authors: A.G. Luk’yanenko, I.M. Pohrelyuk, V.M. Fedirko, A.G. Molyar, V.S. Trush, T.M. Kravchyshyn
Format: Article
Language:English
Published: Polish Academy of Sciences 2023-06-01
Series:Archives of Metallurgy and Materials
Subjects:
Online Access:https://journals.pan.pl/Content/127265/PDF/AMM-2023-2-03-Luk'yanenko.pdf
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author A.G. Luk’yanenko
I.M. Pohrelyuk
V.M. Fedirko
A.G. Molyar
V.S. Trush
T.M. Kravchyshyn
author_facet A.G. Luk’yanenko
I.M. Pohrelyuk
V.M. Fedirko
A.G. Molyar
V.S. Trush
T.M. Kravchyshyn
author_sort A.G. Luk’yanenko
collection DOAJ
description The present research investigates the nitriding kinetics of the near-beta-titanium alloy of Ti-Al-Nb-Fe-Zr-Mo-V system at 750, 800, and 850°C in gaseous nitrogen at 10 5 Pa for 2, 4, and 8 h. The parabolic coefficient kp of the layer’s growth rate and the nitriding activation energy E are set as the kinetic parameters of the nitrided layer’s growth. The activation energy for the formation of a nitride layer is ~108 kJ/mol. The authors discuss the morphology of the nitride layers as well as their roughness and surface hardness. The study determines the effective diffusion coefficient for the growth of diffusion layers in the temperature range of 750...850°C: Def = D0 × exp (– E/RT), where D0 = 0.0177 m 2/s; E = 215.7 kJ/mol. The friction coefficient of the disk from near-beta-titanium alloy with a bronze block is lowered by significantly more than 10 times after gas nitriding, and the temperature in the friction zone is reduced by 2.5 times.
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spelling doaj.art-4b9192da1edd4de0aafe9560c4f7267f2023-06-06T08:16:18ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092023-06-01vol. 68No 2431438https://doi.org/10.24425/amm.2023.142419Gas Nitriding of the Near-Beta-Titanium AlloyA.G. Luk’yanenko0https://orcid.org/0000-0001-6642-2300I.M. Pohrelyuk1https://orcid.org/0000-0002-3009-2829V.M. Fedirko2https://orcid.org/0000-0002-4337-1691A.G. Molyar3V.S. Trush4https://orcid.org/0000-0002-2264-3918T.M. Kravchyshyn5G.V. Karpenko Physico-Mechanics Institute of the NAS of Ukraine, Department of Material Science Bases of Surface Engineering, 5, Naukova Str., 79060 Lviv, UkraineG.V. Karpenko Physico-Mechanics Institute of the NAS of Ukraine, Department of Material Science Bases of Surface Engineering, 5, Naukova Str., 79060 Lviv, UkraineG.V. Karpenko Physico-Mechanics Institute of the NAS of Ukraine, Department of Material Science Bases of Surface Engineering, 5, Naukova Str., 79060 Lviv, UkraineG.V. Kurdyumov Institute for Metal Physics of the NAS of Ukraine, Department of Physics of Strength and Ductility of Inhomogeneous Alloys,36 Academician Vernadsky Boulevard, 03142 Kyiv, UkraineG.V. Karpenko Physico-Mechanics Institute of the NAS of Ukraine, Department of Material Science Bases of Surface Engineering, 5, Naukova Str., 79060 Lviv, UkraineG.V. Karpenko Physico-Mechanics Institute of the NAS of Ukraine, Department of Material Science Bases of Surface Engineering, 5, Naukova Str., 79060 Lviv, UkraineThe present research investigates the nitriding kinetics of the near-beta-titanium alloy of Ti-Al-Nb-Fe-Zr-Mo-V system at 750, 800, and 850°C in gaseous nitrogen at 10 5 Pa for 2, 4, and 8 h. The parabolic coefficient kp of the layer’s growth rate and the nitriding activation energy E are set as the kinetic parameters of the nitrided layer’s growth. The activation energy for the formation of a nitride layer is ~108 kJ/mol. The authors discuss the morphology of the nitride layers as well as their roughness and surface hardness. The study determines the effective diffusion coefficient for the growth of diffusion layers in the temperature range of 750...850°C: Def = D0 × exp (– E/RT), where D0 = 0.0177 m 2/s; E = 215.7 kJ/mol. The friction coefficient of the disk from near-beta-titanium alloy with a bronze block is lowered by significantly more than 10 times after gas nitriding, and the temperature in the friction zone is reduced by 2.5 times.https://journals.pan.pl/Content/127265/PDF/AMM-2023-2-03-Luk'yanenko.pdfnear-beta-titanium alloynitridingkineticsdiffusionmicrohardness
spellingShingle A.G. Luk’yanenko
I.M. Pohrelyuk
V.M. Fedirko
A.G. Molyar
V.S. Trush
T.M. Kravchyshyn
Gas Nitriding of the Near-Beta-Titanium Alloy
Archives of Metallurgy and Materials
near-beta-titanium alloy
nitriding
kinetics
diffusion
microhardness
title Gas Nitriding of the Near-Beta-Titanium Alloy
title_full Gas Nitriding of the Near-Beta-Titanium Alloy
title_fullStr Gas Nitriding of the Near-Beta-Titanium Alloy
title_full_unstemmed Gas Nitriding of the Near-Beta-Titanium Alloy
title_short Gas Nitriding of the Near-Beta-Titanium Alloy
title_sort gas nitriding of the near beta titanium alloy
topic near-beta-titanium alloy
nitriding
kinetics
diffusion
microhardness
url https://journals.pan.pl/Content/127265/PDF/AMM-2023-2-03-Luk'yanenko.pdf
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AT impohrelyuk gasnitridingofthenearbetatitaniumalloy
AT vmfedirko gasnitridingofthenearbetatitaniumalloy
AT agmolyar gasnitridingofthenearbetatitaniumalloy
AT vstrush gasnitridingofthenearbetatitaniumalloy
AT tmkravchyshyn gasnitridingofthenearbetatitaniumalloy