A practical approach for the calculation of the activation energy of the sintering

Newly developed software for calculation of activation energy (Qs in the following) of sintering using the Wang and Raj model is presented. To demonstrate the practical potential of the software and to evaluate the behaviour of the Qs during the sintering process, alumina and cubic zirconia...

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Main Authors: Pouchly Vaclav, Hruby Jan, Maca Karel
Format: Article
Language:English
Published: International Institute for the Science of Sintering, Beograd 2016-01-01
Series:Science of Sintering
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0350-820X/2016/0350-820X1603317P.pdf
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author Pouchly Vaclav
Hruby Jan
Maca Karel
author_facet Pouchly Vaclav
Hruby Jan
Maca Karel
author_sort Pouchly Vaclav
collection DOAJ
description Newly developed software for calculation of activation energy (Qs in the following) of sintering using the Wang and Raj model is presented. To demonstrate the practical potential of the software and to evaluate the behaviour of the Qs during the sintering process, alumina and cubic zirconia ceramic compacts were prepared from nanometric powders. The results obtained with both materials are in agreement with previously published data calculated by different approaches. In the interval of interest (relative densities from 60 % to almost 100 % of theoretical density), both materials show similar behaviour. Three distinct regions can be seen: the initial constant values of Qs 868 kJ/mol and 762 kJ/mol for alumina and cubic zirconia, respectively; a region containing linear drop of Qs and the final region of constant Qs values 625 kJ/mol and 645 kJ/mol for alumina and cubic zirconia, respectively.
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spelling doaj.art-4b9330ef18b14854b9dd440c12b249d62022-12-21T23:25:16ZengInternational Institute for the Science of Sintering, BeogradScience of Sintering0350-820X1820-74132016-01-0148331732410.2298/SOS1603317P0350-820X1603317PA practical approach for the calculation of the activation energy of the sinteringPouchly Vaclav0Hruby Jan1Maca Karel2CEITEC BUT, Brno University of Technology, Brno, Czech RepublicCEITEC BUT, Brno University of Technology, Brno, Czech RepublicCEITEC BUT, Brno University of Technology, Brno, Czech RepublicNewly developed software for calculation of activation energy (Qs in the following) of sintering using the Wang and Raj model is presented. To demonstrate the practical potential of the software and to evaluate the behaviour of the Qs during the sintering process, alumina and cubic zirconia ceramic compacts were prepared from nanometric powders. The results obtained with both materials are in agreement with previously published data calculated by different approaches. In the interval of interest (relative densities from 60 % to almost 100 % of theoretical density), both materials show similar behaviour. Three distinct regions can be seen: the initial constant values of Qs 868 kJ/mol and 762 kJ/mol for alumina and cubic zirconia, respectively; a region containing linear drop of Qs and the final region of constant Qs values 625 kJ/mol and 645 kJ/mol for alumina and cubic zirconia, respectively.http://www.doiserbia.nb.rs/img/doi/0350-820X/2016/0350-820X1603317P.pdfSinteringActivation energyAluminaZirconia
spellingShingle Pouchly Vaclav
Hruby Jan
Maca Karel
A practical approach for the calculation of the activation energy of the sintering
Science of Sintering
Sintering
Activation energy
Alumina
Zirconia
title A practical approach for the calculation of the activation energy of the sintering
title_full A practical approach for the calculation of the activation energy of the sintering
title_fullStr A practical approach for the calculation of the activation energy of the sintering
title_full_unstemmed A practical approach for the calculation of the activation energy of the sintering
title_short A practical approach for the calculation of the activation energy of the sintering
title_sort practical approach for the calculation of the activation energy of the sintering
topic Sintering
Activation energy
Alumina
Zirconia
url http://www.doiserbia.nb.rs/img/doi/0350-820X/2016/0350-820X1603317P.pdf
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