Effect of Temperature Gradient on Chloride Ion Diffusion in Nuclear Reactor Containment Building Concrete

Chloride diffusion through concrete is influenced by harsh environmental conditions such as high ambient temperature and relative humidity. This paper examined the influence of temperature gradient on chloride diffusion in concrete under high ambient temperature conditions. Chloride diffusion tests...

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Main Authors: Boohyun An, Pyungyeon Cho, Remilekun A. Shittu, Tae-Yeon Kim, Paul Rostron, Akram AlFantazi, Yongsun Yi
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/15/15/5581
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author Boohyun An
Pyungyeon Cho
Remilekun A. Shittu
Tae-Yeon Kim
Paul Rostron
Akram AlFantazi
Yongsun Yi
author_facet Boohyun An
Pyungyeon Cho
Remilekun A. Shittu
Tae-Yeon Kim
Paul Rostron
Akram AlFantazi
Yongsun Yi
author_sort Boohyun An
collection DOAJ
description Chloride diffusion through concrete is influenced by harsh environmental conditions such as high ambient temperature and relative humidity. This paper examined the influence of temperature gradient on chloride diffusion in concrete under high ambient temperature conditions. Chloride diffusion tests using cylindrical concrete samples were performed in constant temperature and temperature gradient conditions. In a temperature gradient condition, a much higher chloride concentration was measured than at constant temperatures, which could not be explained only by the mass diffusion driven by the concentration gradient. A new analytical model of chloride diffusion with the mass diffusion term including the temperature effect and the thermo-diffusion term including the temperature gradient effect was applied to the results, which showed that the thermo-diffusion contribution was significant. Using the analytical model with the mass diffusion (<i>D<sub>Cl</sub></i>) and thermo-diffusion (<i>D<sub>T</sub></i>) coefficients, the service life of reactor containment buildings (RCBs) in nuclear power plants (NPPs) in the Middle Eastern and North African (MENA) region was estimated. The results showed that the service life of the RCBs could be reduced by the temperature gradient, indicating the possible application of the proposed analytical model.
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spelling doaj.art-4b93804bcb204111ac679d27961530542023-12-03T12:35:58ZengMDPI AGEnergies1996-10732022-08-011515558110.3390/en15155581Effect of Temperature Gradient on Chloride Ion Diffusion in Nuclear Reactor Containment Building ConcreteBoohyun An0Pyungyeon Cho1Remilekun A. Shittu2Tae-Yeon Kim3Paul Rostron4Akram AlFantazi5Yongsun Yi6Emirates Nuclear Technology Center, Khalifa University of Science and Technology, Abu Dhabi 127788, United Arab EmiratesEmirates Nuclear Technology Center, Khalifa University of Science and Technology, Abu Dhabi 127788, United Arab EmiratesEmirates Nuclear Technology Center, Khalifa University of Science and Technology, Abu Dhabi 127788, United Arab EmiratesEmirates Nuclear Technology Center, Khalifa University of Science and Technology, Abu Dhabi 127788, United Arab EmiratesEmirates Nuclear Technology Center, Khalifa University of Science and Technology, Abu Dhabi 127788, United Arab EmiratesEmirates Nuclear Technology Center, Khalifa University of Science and Technology, Abu Dhabi 127788, United Arab EmiratesEmirates Nuclear Technology Center, Khalifa University of Science and Technology, Abu Dhabi 127788, United Arab EmiratesChloride diffusion through concrete is influenced by harsh environmental conditions such as high ambient temperature and relative humidity. This paper examined the influence of temperature gradient on chloride diffusion in concrete under high ambient temperature conditions. Chloride diffusion tests using cylindrical concrete samples were performed in constant temperature and temperature gradient conditions. In a temperature gradient condition, a much higher chloride concentration was measured than at constant temperatures, which could not be explained only by the mass diffusion driven by the concentration gradient. A new analytical model of chloride diffusion with the mass diffusion term including the temperature effect and the thermo-diffusion term including the temperature gradient effect was applied to the results, which showed that the thermo-diffusion contribution was significant. Using the analytical model with the mass diffusion (<i>D<sub>Cl</sub></i>) and thermo-diffusion (<i>D<sub>T</sub></i>) coefficients, the service life of reactor containment buildings (RCBs) in nuclear power plants (NPPs) in the Middle Eastern and North African (MENA) region was estimated. The results showed that the service life of the RCBs could be reduced by the temperature gradient, indicating the possible application of the proposed analytical model.https://www.mdpi.com/1996-1073/15/15/5581chloride iontemperature gradientthermo-diffusionmass diffusionreactor containment building
spellingShingle Boohyun An
Pyungyeon Cho
Remilekun A. Shittu
Tae-Yeon Kim
Paul Rostron
Akram AlFantazi
Yongsun Yi
Effect of Temperature Gradient on Chloride Ion Diffusion in Nuclear Reactor Containment Building Concrete
Energies
chloride ion
temperature gradient
thermo-diffusion
mass diffusion
reactor containment building
title Effect of Temperature Gradient on Chloride Ion Diffusion in Nuclear Reactor Containment Building Concrete
title_full Effect of Temperature Gradient on Chloride Ion Diffusion in Nuclear Reactor Containment Building Concrete
title_fullStr Effect of Temperature Gradient on Chloride Ion Diffusion in Nuclear Reactor Containment Building Concrete
title_full_unstemmed Effect of Temperature Gradient on Chloride Ion Diffusion in Nuclear Reactor Containment Building Concrete
title_short Effect of Temperature Gradient on Chloride Ion Diffusion in Nuclear Reactor Containment Building Concrete
title_sort effect of temperature gradient on chloride ion diffusion in nuclear reactor containment building concrete
topic chloride ion
temperature gradient
thermo-diffusion
mass diffusion
reactor containment building
url https://www.mdpi.com/1996-1073/15/15/5581
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