Zero Liquid Discharge and Resource Treatment of Low-Salinity Mineralized Wastewater Based on Combing Selectrodialysis with Bipolar Membrane Electrodialysis

A large amount of mine water is generated during coal production, which not only damages the surface environment and ecology but also wastes groundwater resources in the mining area, exacerbating regional water scarcity. In this work, a novel zero liquid discharge technology combining selectrodialys...

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Main Authors: Xueting Zhao, Xinhao Cheng, Jinshan Sun, Jialin Liu, Zhaofeng Liu, Yali Wang, Jiefeng Pan
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Separations
Subjects:
Online Access:https://www.mdpi.com/2297-8739/10/4/269
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author Xueting Zhao
Xinhao Cheng
Jinshan Sun
Jialin Liu
Zhaofeng Liu
Yali Wang
Jiefeng Pan
author_facet Xueting Zhao
Xinhao Cheng
Jinshan Sun
Jialin Liu
Zhaofeng Liu
Yali Wang
Jiefeng Pan
author_sort Xueting Zhao
collection DOAJ
description A large amount of mine water is generated during coal production, which not only damages the surface environment and ecology but also wastes groundwater resources in the mining area, exacerbating regional water scarcity. In this work, a novel zero liquid discharge technology combining selectrodialysis (SED) and bipolar membrane electrodialysis (BMED) was developed for the resourceful treatment of low-salinity mineralized wastewater. The SED stack had demonstrated to be workable for the elimination of multivalent ions. The BMED stack converts brine into acid and base. After SED, a high pure crude salt (~98%) was attained. Furthermore, under the conditions of a current density of 20 mA/cm<sup>2</sup>, a flow velocity of 20 L/h, and an initial acid/base concentration of 0.10 mol/L, the maximum concentrations of acid and base were found to be 0.75 mol/L and 0.765 mol/L, respectively, for a feed conductivity of 55 mS/cm. The cost of the entire electrodialysis stage was evaluated to be USD 1.38/kg of NaOH. Therefore, this combined UF-RO-SED-BMED process may be an effective strategy for the sustainable treatment of low-salinity mineralized wastewater.
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spelling doaj.art-4bb7154f70794fdfb2bf0e81b5db88272023-11-17T21:20:52ZengMDPI AGSeparations2297-87392023-04-0110426910.3390/separations10040269Zero Liquid Discharge and Resource Treatment of Low-Salinity Mineralized Wastewater Based on Combing Selectrodialysis with Bipolar Membrane ElectrodialysisXueting Zhao0Xinhao Cheng1Jinshan Sun2Jialin Liu3Zhaofeng Liu4Yali Wang5Jiefeng Pan6College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaState Key Laboratory of Water Resource Protection and Utilization in Coal Mining, Beijing 100049, ChinaDepartment of Chemistry and Chemical Engineering, Yulin University, Yulin 719000, ChinaCollege of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, ChinaA large amount of mine water is generated during coal production, which not only damages the surface environment and ecology but also wastes groundwater resources in the mining area, exacerbating regional water scarcity. In this work, a novel zero liquid discharge technology combining selectrodialysis (SED) and bipolar membrane electrodialysis (BMED) was developed for the resourceful treatment of low-salinity mineralized wastewater. The SED stack had demonstrated to be workable for the elimination of multivalent ions. The BMED stack converts brine into acid and base. After SED, a high pure crude salt (~98%) was attained. Furthermore, under the conditions of a current density of 20 mA/cm<sup>2</sup>, a flow velocity of 20 L/h, and an initial acid/base concentration of 0.10 mol/L, the maximum concentrations of acid and base were found to be 0.75 mol/L and 0.765 mol/L, respectively, for a feed conductivity of 55 mS/cm. The cost of the entire electrodialysis stage was evaluated to be USD 1.38/kg of NaOH. Therefore, this combined UF-RO-SED-BMED process may be an effective strategy for the sustainable treatment of low-salinity mineralized wastewater.https://www.mdpi.com/2297-8739/10/4/269selectrodialysisbipolar membrane electrodialysismineralized wastewaterrecoveryinfluence factors
spellingShingle Xueting Zhao
Xinhao Cheng
Jinshan Sun
Jialin Liu
Zhaofeng Liu
Yali Wang
Jiefeng Pan
Zero Liquid Discharge and Resource Treatment of Low-Salinity Mineralized Wastewater Based on Combing Selectrodialysis with Bipolar Membrane Electrodialysis
Separations
selectrodialysis
bipolar membrane electrodialysis
mineralized wastewater
recovery
influence factors
title Zero Liquid Discharge and Resource Treatment of Low-Salinity Mineralized Wastewater Based on Combing Selectrodialysis with Bipolar Membrane Electrodialysis
title_full Zero Liquid Discharge and Resource Treatment of Low-Salinity Mineralized Wastewater Based on Combing Selectrodialysis with Bipolar Membrane Electrodialysis
title_fullStr Zero Liquid Discharge and Resource Treatment of Low-Salinity Mineralized Wastewater Based on Combing Selectrodialysis with Bipolar Membrane Electrodialysis
title_full_unstemmed Zero Liquid Discharge and Resource Treatment of Low-Salinity Mineralized Wastewater Based on Combing Selectrodialysis with Bipolar Membrane Electrodialysis
title_short Zero Liquid Discharge and Resource Treatment of Low-Salinity Mineralized Wastewater Based on Combing Selectrodialysis with Bipolar Membrane Electrodialysis
title_sort zero liquid discharge and resource treatment of low salinity mineralized wastewater based on combing selectrodialysis with bipolar membrane electrodialysis
topic selectrodialysis
bipolar membrane electrodialysis
mineralized wastewater
recovery
influence factors
url https://www.mdpi.com/2297-8739/10/4/269
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