Thermal and Electrical Characterization of Polyester Resins Suitable for Electric Motor Insulation

This paper undertakes the thermal and electrical characterization of three commercial unsaturated polyester imide resins (UPIR) to identify which among them could better perform the insulation function of electric motors (high-power induction motors fed by pulse-wide modulation (PWM) inverters). The...

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Main Authors: Elisa Calabrese, Marialuigia Raimondo, Michelina Catauro, Luigi Vertuccio, Patrizia Lamberti, Raffaele Raimo, Vincenzo Tucci, Liberata Guadagno
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/6/1374
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author Elisa Calabrese
Marialuigia Raimondo
Michelina Catauro
Luigi Vertuccio
Patrizia Lamberti
Raffaele Raimo
Vincenzo Tucci
Liberata Guadagno
author_facet Elisa Calabrese
Marialuigia Raimondo
Michelina Catauro
Luigi Vertuccio
Patrizia Lamberti
Raffaele Raimo
Vincenzo Tucci
Liberata Guadagno
author_sort Elisa Calabrese
collection DOAJ
description This paper undertakes the thermal and electrical characterization of three commercial unsaturated polyester imide resins (UPIR) to identify which among them could better perform the insulation function of electric motors (high-power induction motors fed by pulse-wide modulation (PWM) inverters). The process foreseen for the motor insulation using these resins is Vacuum Pressure Impregnation (VPI). The resin formulations were specially selected because they are one-component systems; hence, before the VPI process, they do not require mixing steps with external hardeners to activate the curing process. Furthermore, they are characterized by low viscosity and a thermal class higher than 180 °C and are Volatile Organic Compound (VOC)-free. Thermal investigations using Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC) techniques prove their excellent thermal resistance up to 320 °C. Moreover, impedance spectroscopy in the frequency range of 100 Hz–1 MHz was analyzed to compare the electromagnetic performance of the considered formulations. They manifest an electrical conductivity starting from 10<sup>−10</sup> S/m, a relative permittivity around 3, and a loss tangent value lower than 0.02, which appears almost stable in the analyzed frequency range. These values confirm their usefulness as impregnating resins in secondary insulation material applications.
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spelling doaj.art-4bc139cdd1af4d58836c103da1ff9b852023-11-17T13:24:39ZengMDPI AGPolymers2073-43602023-03-01156137410.3390/polym15061374Thermal and Electrical Characterization of Polyester Resins Suitable for Electric Motor InsulationElisa Calabrese0Marialuigia Raimondo1Michelina Catauro2Luigi Vertuccio3Patrizia Lamberti4Raffaele Raimo5Vincenzo Tucci6Liberata Guadagno7Department of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano, ItalyDepartment of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano, ItalyDepartment of Engineering, University of Campania “Luigi Vanvitelli”, Via Roma 29, 81031 Aversa, ItalyDepartment of Engineering, University of Campania “Luigi Vanvitelli”, Via Roma 29, 81031 Aversa, ItalyDepartment of Information and Electrical Engineering and Applied Mathematics, University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano, ItalyDepartment of Information and Electrical Engineering and Applied Mathematics, University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano, ItalyDepartment of Information and Electrical Engineering and Applied Mathematics, University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano, ItalyDepartment of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132, 84084 Fisciano, ItalyThis paper undertakes the thermal and electrical characterization of three commercial unsaturated polyester imide resins (UPIR) to identify which among them could better perform the insulation function of electric motors (high-power induction motors fed by pulse-wide modulation (PWM) inverters). The process foreseen for the motor insulation using these resins is Vacuum Pressure Impregnation (VPI). The resin formulations were specially selected because they are one-component systems; hence, before the VPI process, they do not require mixing steps with external hardeners to activate the curing process. Furthermore, they are characterized by low viscosity and a thermal class higher than 180 °C and are Volatile Organic Compound (VOC)-free. Thermal investigations using Thermogravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC) techniques prove their excellent thermal resistance up to 320 °C. Moreover, impedance spectroscopy in the frequency range of 100 Hz–1 MHz was analyzed to compare the electromagnetic performance of the considered formulations. They manifest an electrical conductivity starting from 10<sup>−10</sup> S/m, a relative permittivity around 3, and a loss tangent value lower than 0.02, which appears almost stable in the analyzed frequency range. These values confirm their usefulness as impregnating resins in secondary insulation material applications.https://www.mdpi.com/2073-4360/15/6/1374insulating materialspolyester resinsthermal analysesVacuum Pressure Impregnation (VPI)PWM-fed motors
spellingShingle Elisa Calabrese
Marialuigia Raimondo
Michelina Catauro
Luigi Vertuccio
Patrizia Lamberti
Raffaele Raimo
Vincenzo Tucci
Liberata Guadagno
Thermal and Electrical Characterization of Polyester Resins Suitable for Electric Motor Insulation
Polymers
insulating materials
polyester resins
thermal analyses
Vacuum Pressure Impregnation (VPI)
PWM-fed motors
title Thermal and Electrical Characterization of Polyester Resins Suitable for Electric Motor Insulation
title_full Thermal and Electrical Characterization of Polyester Resins Suitable for Electric Motor Insulation
title_fullStr Thermal and Electrical Characterization of Polyester Resins Suitable for Electric Motor Insulation
title_full_unstemmed Thermal and Electrical Characterization of Polyester Resins Suitable for Electric Motor Insulation
title_short Thermal and Electrical Characterization of Polyester Resins Suitable for Electric Motor Insulation
title_sort thermal and electrical characterization of polyester resins suitable for electric motor insulation
topic insulating materials
polyester resins
thermal analyses
Vacuum Pressure Impregnation (VPI)
PWM-fed motors
url https://www.mdpi.com/2073-4360/15/6/1374
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AT marialuigiaraimondo thermalandelectricalcharacterizationofpolyesterresinssuitableforelectricmotorinsulation
AT michelinacatauro thermalandelectricalcharacterizationofpolyesterresinssuitableforelectricmotorinsulation
AT luigivertuccio thermalandelectricalcharacterizationofpolyesterresinssuitableforelectricmotorinsulation
AT patrizialamberti thermalandelectricalcharacterizationofpolyesterresinssuitableforelectricmotorinsulation
AT raffaeleraimo thermalandelectricalcharacterizationofpolyesterresinssuitableforelectricmotorinsulation
AT vincenzotucci thermalandelectricalcharacterizationofpolyesterresinssuitableforelectricmotorinsulation
AT liberataguadagno thermalandelectricalcharacterizationofpolyesterresinssuitableforelectricmotorinsulation