Elongational Viscosities of Polymethylmethacrylate / Nano-Clay Composites

The elongational flow of polymethylmethacrylate / nano-clay composites was studied during stressing and creep experiments using a Münstedt tensile rheometer (MTR). The dispersion of the nano-clay was controlled by means of transmission electron microscopy (TEM) and the layer distance was measured wi...

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Main Authors: Katsikis Nikolaos, Königer Tobias, Münstedt Helmut
Format: Article
Language:English
Published: De Gruyter 2007-10-01
Series:Applied Rheology
Subjects:
Online Access:https://doi.org/10.1515/arh-2007-0017
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author Katsikis Nikolaos
Königer Tobias
Münstedt Helmut
author_facet Katsikis Nikolaos
Königer Tobias
Münstedt Helmut
author_sort Katsikis Nikolaos
collection DOAJ
description The elongational flow of polymethylmethacrylate / nano-clay composites was studied during stressing and creep experiments using a Münstedt tensile rheometer (MTR). The dispersion of the nano-clay was controlled by means of transmission electron microscopy (TEM) and the layer distance was measured with X-ray diffraction (XRD). With growing volume fraction of the filler an increase of the viscosity is observed under constant strain rate and constant stress conditions. The results for the elongational viscosities for both modes are consistent with each other. Furthermore, a strain softening behavior can be measured, which is the more pronounced the higher the nano-clay content is. As the Trouton rule is not valid, deviations from the linear behaviour are related to an envolope curve for the elongational viscosities instead of the threefold zero shear viscosity.
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spelling doaj.art-4bcb7a8542f0490f8bec46bbe11097c72022-12-21T22:37:18ZengDe GruyterApplied Rheology1617-81062007-10-0117552751-152751-910.1515/arh-2007-0017Elongational Viscosities of Polymethylmethacrylate / Nano-Clay CompositesKatsikis Nikolaos0Königer Tobias1Münstedt Helmut2Institute of Polymer Materials, Department of Materials Science, University Erlangen-Nürnberg, Martensstrasse 7, 91058Erlangen, GermanyInstitute of Polymer Materials, Department of Materials Science, University Erlangen-Nürnberg, Martensstrasse 7, 91058Erlangen, GermanyInstitute of Polymer Materials, Department of Materials Science, University Erlangen-Nürnberg, Martensstrasse 7, 91058Erlangen, GermanyThe elongational flow of polymethylmethacrylate / nano-clay composites was studied during stressing and creep experiments using a Münstedt tensile rheometer (MTR). The dispersion of the nano-clay was controlled by means of transmission electron microscopy (TEM) and the layer distance was measured with X-ray diffraction (XRD). With growing volume fraction of the filler an increase of the viscosity is observed under constant strain rate and constant stress conditions. The results for the elongational viscosities for both modes are consistent with each other. Furthermore, a strain softening behavior can be measured, which is the more pronounced the higher the nano-clay content is. As the Trouton rule is not valid, deviations from the linear behaviour are related to an envolope curve for the elongational viscosities instead of the threefold zero shear viscosity.https://doi.org/10.1515/arh-2007-0017nano-claypolymethylmethacrylateuniaxial elongationelongational viscositystressing experimentcreep experiment
spellingShingle Katsikis Nikolaos
Königer Tobias
Münstedt Helmut
Elongational Viscosities of Polymethylmethacrylate / Nano-Clay Composites
Applied Rheology
nano-clay
polymethylmethacrylate
uniaxial elongation
elongational viscosity
stressing experiment
creep experiment
title Elongational Viscosities of Polymethylmethacrylate / Nano-Clay Composites
title_full Elongational Viscosities of Polymethylmethacrylate / Nano-Clay Composites
title_fullStr Elongational Viscosities of Polymethylmethacrylate / Nano-Clay Composites
title_full_unstemmed Elongational Viscosities of Polymethylmethacrylate / Nano-Clay Composites
title_short Elongational Viscosities of Polymethylmethacrylate / Nano-Clay Composites
title_sort elongational viscosities of polymethylmethacrylate nano clay composites
topic nano-clay
polymethylmethacrylate
uniaxial elongation
elongational viscosity
stressing experiment
creep experiment
url https://doi.org/10.1515/arh-2007-0017
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AT konigertobias elongationalviscositiesofpolymethylmethacrylatenanoclaycomposites
AT munstedthelmut elongationalviscositiesofpolymethylmethacrylatenanoclaycomposites