Engineering in Oxygen-incorporated monolayer MoS2 for Effi-cient Hydrogen Evolution
MoS2 is a promising alternative to Pt in hydrogen evolution reaction (HER) due to its low cost. To enhance the catalytic properties of the 2H MoS2 inert basal plane, we propose an approach of employing oxygen incorporated MoS2 as a catalyst for HER. Different density of oxygen substitution doped mon...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Kaunas University of Technology
2024-01-01
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| Series: | Medžiagotyra |
| Subjects: | |
| Online Access: | https://matsc.ktu.lt/index.php/MatSc/article/view/33985 |
| _version_ | 1797302401783300096 |
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| author | Jianling MENG Zheng WEI Shuhua YANG Xiao REN |
| author_facet | Jianling MENG Zheng WEI Shuhua YANG Xiao REN |
| author_sort | Jianling MENG |
| collection | DOAJ |
| description | MoS2 is a promising alternative to Pt in hydrogen evolution reaction (HER) due to its low cost. To enhance the catalytic properties of the 2H MoS2 inert basal plane, we propose an approach of employing oxygen incorporated MoS2 as a catalyst for HER. Different density of oxygen substitution doped monolayer MoS2 samples (MoS1.51O0.49, MoS1.55O0.45, MoS1.67O0.33) were achieved by chemical vapor deposition method and their catalytic performance were tested. Experimentally, we demonstrate that oxygen substitution can activate the inert basal plane and the catalytic performance is dependent on the oxygen substitution percentage. Also, combining with DFT calculations, we confirm that oxygen substitution act as catalytic sites. Our work provides a strategy for enhancing of monolayer MoS2 HER activities through in situ substitution doping. |
| first_indexed | 2024-03-07T23:37:21Z |
| format | Article |
| id | doaj.art-4bd8fc5693b64569a3dfcc0fbcc94009 |
| institution | Directory Open Access Journal |
| issn | 1392-1320 2029-7289 |
| language | English |
| last_indexed | 2024-03-07T23:37:21Z |
| publishDate | 2024-01-01 |
| publisher | Kaunas University of Technology |
| record_format | Article |
| series | Medžiagotyra |
| spelling | doaj.art-4bd8fc5693b64569a3dfcc0fbcc940092024-02-20T05:53:47ZengKaunas University of TechnologyMedžiagotyra1392-13202029-72892024-01-0130112813210.5755/j02.ms.3398539239Engineering in Oxygen-incorporated monolayer MoS2 for Effi-cient Hydrogen EvolutionJianling MENG0https://orcid.org/0000-0001-5413-1952Zheng WEI1https://orcid.org/0000-0002-4877-6719Shuhua YANG2https://orcid.org/0000-0002-2364-9676Xiao REN3https://orcid.org/0000-0003-2456-8138Beijing University of Chemical TechnologyDalian Jiaotong UniversityUniversity of JinanPeking UniversityMoS2 is a promising alternative to Pt in hydrogen evolution reaction (HER) due to its low cost. To enhance the catalytic properties of the 2H MoS2 inert basal plane, we propose an approach of employing oxygen incorporated MoS2 as a catalyst for HER. Different density of oxygen substitution doped monolayer MoS2 samples (MoS1.51O0.49, MoS1.55O0.45, MoS1.67O0.33) were achieved by chemical vapor deposition method and their catalytic performance were tested. Experimentally, we demonstrate that oxygen substitution can activate the inert basal plane and the catalytic performance is dependent on the oxygen substitution percentage. Also, combining with DFT calculations, we confirm that oxygen substitution act as catalytic sites. Our work provides a strategy for enhancing of monolayer MoS2 HER activities through in situ substitution doping.https://matsc.ktu.lt/index.php/MatSc/article/view/33985monolayer mos2oxygen substitution dopinghydrogen evolution reaction |
| spellingShingle | Jianling MENG Zheng WEI Shuhua YANG Xiao REN Engineering in Oxygen-incorporated monolayer MoS2 for Effi-cient Hydrogen Evolution Medžiagotyra monolayer mos2 oxygen substitution doping hydrogen evolution reaction |
| title | Engineering in Oxygen-incorporated monolayer MoS2 for Effi-cient Hydrogen Evolution |
| title_full | Engineering in Oxygen-incorporated monolayer MoS2 for Effi-cient Hydrogen Evolution |
| title_fullStr | Engineering in Oxygen-incorporated monolayer MoS2 for Effi-cient Hydrogen Evolution |
| title_full_unstemmed | Engineering in Oxygen-incorporated monolayer MoS2 for Effi-cient Hydrogen Evolution |
| title_short | Engineering in Oxygen-incorporated monolayer MoS2 for Effi-cient Hydrogen Evolution |
| title_sort | engineering in oxygen incorporated monolayer mos2 for effi cient hydrogen evolution |
| topic | monolayer mos2 oxygen substitution doping hydrogen evolution reaction |
| url | https://matsc.ktu.lt/index.php/MatSc/article/view/33985 |
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