Electrode material promoted dehydrogenative homo-/cross-coupling of weakly activated naphthalenes
Herein, we reported an electrochemical dehydrogenative homo-/cross-coupling of weakly activated naphthalene in the exogenous transition metal- and oxidants-free manner. Benefiting from the microscopic interaction between the reactants and the carbon plate anode, the electropolymerization of aromatic...
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| Format: | Article |
| Language: | English |
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KeAi Communications Co. Ltd.
2023-02-01
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| Series: | Green Synthesis and Catalysis |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666554922000448 |
| _version_ | 1797868201692889088 |
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| author | Siyuan Liu Yi Lu Siying Sun Hong Wang Wei Gao Yuying Wang Xiaofei Jia Jianbin Chen |
| author_facet | Siyuan Liu Yi Lu Siying Sun Hong Wang Wei Gao Yuying Wang Xiaofei Jia Jianbin Chen |
| author_sort | Siyuan Liu |
| collection | DOAJ |
| description | Herein, we reported an electrochemical dehydrogenative homo-/cross-coupling of weakly activated naphthalene in the exogenous transition metal- and oxidants-free manner. Benefiting from the microscopic interaction between the reactants and the carbon plate anode, the electropolymerization of aromatic rings was suppressed. And a series of binaphthyl and naphthalene-aryl privileged scaffolds were obtained in 28%–90% yields by homo- or cross-coupling. This C(sp2)-H activation strategy featured atom and step economy as well as the ready scalability. |
| first_indexed | 2024-04-09T23:53:22Z |
| format | Article |
| id | doaj.art-4be2e592e34e44e1acb29de1f2bdd872 |
| institution | Directory Open Access Journal |
| issn | 2666-5549 |
| language | English |
| last_indexed | 2024-04-09T23:53:22Z |
| publishDate | 2023-02-01 |
| publisher | KeAi Communications Co. Ltd. |
| record_format | Article |
| series | Green Synthesis and Catalysis |
| spelling | doaj.art-4be2e592e34e44e1acb29de1f2bdd8722023-03-17T04:34:43ZengKeAi Communications Co. Ltd.Green Synthesis and Catalysis2666-55492023-02-01417175Electrode material promoted dehydrogenative homo-/cross-coupling of weakly activated naphthalenesSiyuan Liu0Yi Lu1Siying Sun2Hong Wang3Wei Gao4Yuying Wang5Xiaofei Jia6Jianbin Chen7Shandong Provincial Key Laboratory of Molecular Engineering, State Key Laboratory of Biobased Material and Green Papermaking, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China; Corresponding authors.Shandong Provincial Key Laboratory of Molecular Engineering, State Key Laboratory of Biobased Material and Green Papermaking, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, ChinaShandong Provincial Key Laboratory of Molecular Engineering, State Key Laboratory of Biobased Material and Green Papermaking, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, ChinaShandong Provincial Key Laboratory of Molecular Engineering, State Key Laboratory of Biobased Material and Green Papermaking, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, ChinaShandong Provincial Key Laboratory of Molecular Engineering, State Key Laboratory of Biobased Material and Green Papermaking, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, ChinaShandong Provincial Key Laboratory of Molecular Engineering, State Key Laboratory of Biobased Material and Green Papermaking, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, ChinaKey Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, ChinaShandong Provincial Key Laboratory of Molecular Engineering, State Key Laboratory of Biobased Material and Green Papermaking, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China; Corresponding authors.Herein, we reported an electrochemical dehydrogenative homo-/cross-coupling of weakly activated naphthalene in the exogenous transition metal- and oxidants-free manner. Benefiting from the microscopic interaction between the reactants and the carbon plate anode, the electropolymerization of aromatic rings was suppressed. And a series of binaphthyl and naphthalene-aryl privileged scaffolds were obtained in 28%–90% yields by homo- or cross-coupling. This C(sp2)-H activation strategy featured atom and step economy as well as the ready scalability.http://www.sciencedirect.com/science/article/pii/S2666554922000448ElectrosynthesisDehydrogenative couplingWeakly activated naphthaleneAnode material tuningHigh efficiency |
| spellingShingle | Siyuan Liu Yi Lu Siying Sun Hong Wang Wei Gao Yuying Wang Xiaofei Jia Jianbin Chen Electrode material promoted dehydrogenative homo-/cross-coupling of weakly activated naphthalenes Green Synthesis and Catalysis Electrosynthesis Dehydrogenative coupling Weakly activated naphthalene Anode material tuning High efficiency |
| title | Electrode material promoted dehydrogenative homo-/cross-coupling of weakly activated naphthalenes |
| title_full | Electrode material promoted dehydrogenative homo-/cross-coupling of weakly activated naphthalenes |
| title_fullStr | Electrode material promoted dehydrogenative homo-/cross-coupling of weakly activated naphthalenes |
| title_full_unstemmed | Electrode material promoted dehydrogenative homo-/cross-coupling of weakly activated naphthalenes |
| title_short | Electrode material promoted dehydrogenative homo-/cross-coupling of weakly activated naphthalenes |
| title_sort | electrode material promoted dehydrogenative homo cross coupling of weakly activated naphthalenes |
| topic | Electrosynthesis Dehydrogenative coupling Weakly activated naphthalene Anode material tuning High efficiency |
| url | http://www.sciencedirect.com/science/article/pii/S2666554922000448 |
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