Mechanistic Views on First-row Earth-Abundant Transition Metal Catalyzed Ullmann-type O-Arylation Reactions
Transition metal-catalyzed reactions have attracted much attention in synthetic organic chemistry due to their important role in the formation of C-heteroatom bonds. Ullmann coupling has risen in prominence in recent decades owing to its utilization in the synthesis of biaryl ethers found in a wid...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | deu |
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Swiss Chemical Society
2023-04-01
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| Series: | CHIMIA |
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| Online Access: | https://www.chimia.ch/chimia/article/view/6306 |
| _version_ | 1797826476108677120 |
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| author | Parvathi Santhoshkumar C. Rajalakshmi Lydia Elizabeth Mathews Rehin Sulay Vibin Ipe Thomas |
| author_facet | Parvathi Santhoshkumar C. Rajalakshmi Lydia Elizabeth Mathews Rehin Sulay Vibin Ipe Thomas |
| author_sort | Parvathi Santhoshkumar |
| collection | DOAJ |
| description |
Transition metal-catalyzed reactions have attracted much attention in synthetic organic chemistry due to their important role in the formation of C-heteroatom bonds. Ullmann coupling has risen in prominence in recent decades owing to its utilization in the synthesis of biaryl ethers found in a wide range of natural products together with biologically essential molecules, including antibiotics and major industrial polymers. In this article we provide the current understanding of the theoretical aspects of the underlying mechanism of the Ullmann-type O-arylation reaction.
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| first_indexed | 2024-04-09T12:33:22Z |
| format | Article |
| id | doaj.art-4bfd78205d214317b7bf095a86447b6a |
| institution | Directory Open Access Journal |
| issn | 0009-4293 2673-2424 |
| language | deu |
| last_indexed | 2024-04-09T12:33:22Z |
| publishDate | 2023-04-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj.art-4bfd78205d214317b7bf095a86447b6a2023-05-16T00:10:59ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242023-04-0177410.2533/chimia.2023.246Mechanistic Views on First-row Earth-Abundant Transition Metal Catalyzed Ullmann-type O-Arylation ReactionsParvathi Santhoshkumar0C. Rajalakshmi1Lydia Elizabeth Mathews2Rehin Sulay3Vibin Ipe Thomas4Department of Chemistry, CMS College Kottayam (Autonomous), Kerala,IndiaDepartment of Chemistry, CMS College Kottayam(Mahatma Gandhi University) Kerala, IndiaDepartment of Chemistry, CMS College Kottayam(Mahatma Gandhi University) Kerala, IndiaDepartment of Chemistry, CMS College Kottayam(Mahatma Gandhi University) Kerala, IndiaDepartment of Chemistry, CMS College Kottayam(Mahatma Gandhi University) Kerala, India Transition metal-catalyzed reactions have attracted much attention in synthetic organic chemistry due to their important role in the formation of C-heteroatom bonds. Ullmann coupling has risen in prominence in recent decades owing to its utilization in the synthesis of biaryl ethers found in a wide range of natural products together with biologically essential molecules, including antibiotics and major industrial polymers. In this article we provide the current understanding of the theoretical aspects of the underlying mechanism of the Ullmann-type O-arylation reaction. https://www.chimia.ch/chimia/article/view/6306Density Functional TheoryMechanistic studiesO-arylationTransition-metal catalysis |
| spellingShingle | Parvathi Santhoshkumar C. Rajalakshmi Lydia Elizabeth Mathews Rehin Sulay Vibin Ipe Thomas Mechanistic Views on First-row Earth-Abundant Transition Metal Catalyzed Ullmann-type O-Arylation Reactions CHIMIA Density Functional Theory Mechanistic studies O-arylation Transition-metal catalysis |
| title | Mechanistic Views on First-row Earth-Abundant Transition Metal Catalyzed Ullmann-type O-Arylation Reactions |
| title_full | Mechanistic Views on First-row Earth-Abundant Transition Metal Catalyzed Ullmann-type O-Arylation Reactions |
| title_fullStr | Mechanistic Views on First-row Earth-Abundant Transition Metal Catalyzed Ullmann-type O-Arylation Reactions |
| title_full_unstemmed | Mechanistic Views on First-row Earth-Abundant Transition Metal Catalyzed Ullmann-type O-Arylation Reactions |
| title_short | Mechanistic Views on First-row Earth-Abundant Transition Metal Catalyzed Ullmann-type O-Arylation Reactions |
| title_sort | mechanistic views on first row earth abundant transition metal catalyzed ullmann type o arylation reactions |
| topic | Density Functional Theory Mechanistic studies O-arylation Transition-metal catalysis |
| url | https://www.chimia.ch/chimia/article/view/6306 |
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