Crystal structure of a salt with a protonated sugar cation and a cobalt(II) complex anion: (GlcN–H, K)[Co(NCS)4]·2H2O
The title compound, d-(+)-glucosammonium potassium tetrathiocyanatocobaltate(II) dihydrate, K(C6H14NO5)[Co(NCS)4]·2H2O or (GlcNH)(K)[Co(NCS)4]·2H2O, has been obtained as a side product of an incomplete salt metathesis reaction of d-(+)-glucosamine hydrochloride (GlcN·HCl) and K2[Co(NCS)4]. The asymm...
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| Language: | English |
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International Union of Crystallography
2019-09-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314619011428 |
| _version_ | 1818512864446513152 |
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| author | Tim Peppel Sabine M. L. Detert Christian Vogel Martin Köckerling |
| author_facet | Tim Peppel Sabine M. L. Detert Christian Vogel Martin Köckerling |
| author_sort | Tim Peppel |
| collection | DOAJ |
| description | The title compound, d-(+)-glucosammonium potassium tetrathiocyanatocobaltate(II) dihydrate, K(C6H14NO5)[Co(NCS)4]·2H2O or (GlcNH)(K)[Co(NCS)4]·2H2O, has been obtained as a side product of an incomplete salt metathesis reaction of d-(+)-glucosamine hydrochloride (GlcN·HCl) and K2[Co(NCS)4]. The asymmetric unit contains a d-(+)-glucosammonium cation, a potassium cation, a tetraisothiocyanatocobalt(II) complex anion and two water molecules. The water molecules coordinate to the potassium cation, which is further coordinated via three short K+...SCN− contacts involving three [Co(NCS)4]2− complex anions and via three O atoms of two d-(+)-glucosammonium cations, leading to an overall eightfold coordination around the potassium cation. Hydrogen-bonding interactions between the building blocks consolidate the three-dimensional arrangement. |
| first_indexed | 2024-12-10T23:52:59Z |
| format | Article |
| id | doaj.art-4c030eaeb10c48768f061f75a10d7898 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-10T23:52:59Z |
| publishDate | 2019-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-4c030eaeb10c48768f061f75a10d78982022-12-22T01:28:41ZengInternational Union of CrystallographyIUCrData2414-31462019-09-0149x19114210.1107/S2414314619011428wm4108Crystal structure of a salt with a protonated sugar cation and a cobalt(II) complex anion: (GlcN–H, K)[Co(NCS)4]·2H2OTim Peppel0Sabine M. L. Detert1Christian Vogel2Martin Köckerling3Leibniz-Institut für Katalyse e.V., Heterogene Photokatalyse, Albert-Einstein-Str. 29a, D-18059 Rostock, GermanyUniversität Rostock, Institut für Chemie, Organische Chemie, Albert-Einstein-Str. 3a, D-18059 Rostock, GermanyUniversität Rostock, Institut für Chemie, Organische Chemie, Albert-Einstein-Str. 3a, D-18059 Rostock, GermanyUniversität Rostock, Institut für Chemie, Anorganische Festkörperchemie, Albert-Einstein-Str. 3a, D-18059 Rostock, GermanyThe title compound, d-(+)-glucosammonium potassium tetrathiocyanatocobaltate(II) dihydrate, K(C6H14NO5)[Co(NCS)4]·2H2O or (GlcNH)(K)[Co(NCS)4]·2H2O, has been obtained as a side product of an incomplete salt metathesis reaction of d-(+)-glucosamine hydrochloride (GlcN·HCl) and K2[Co(NCS)4]. The asymmetric unit contains a d-(+)-glucosammonium cation, a potassium cation, a tetraisothiocyanatocobalt(II) complex anion and two water molecules. The water molecules coordinate to the potassium cation, which is further coordinated via three short K+...SCN− contacts involving three [Co(NCS)4]2− complex anions and via three O atoms of two d-(+)-glucosammonium cations, leading to an overall eightfold coordination around the potassium cation. Hydrogen-bonding interactions between the building blocks consolidate the three-dimensional arrangement.http://scripts.iucr.org/cgi-bin/paper?S2414314619011428cobaltglucosamineionic liquidcrystal structure |
| spellingShingle | Tim Peppel Sabine M. L. Detert Christian Vogel Martin Köckerling Crystal structure of a salt with a protonated sugar cation and a cobalt(II) complex anion: (GlcN–H, K)[Co(NCS)4]·2H2O IUCrData cobalt glucosamine ionic liquid crystal structure |
| title | Crystal structure of a salt with a protonated sugar cation and a cobalt(II) complex anion: (GlcN–H, K)[Co(NCS)4]·2H2O |
| title_full | Crystal structure of a salt with a protonated sugar cation and a cobalt(II) complex anion: (GlcN–H, K)[Co(NCS)4]·2H2O |
| title_fullStr | Crystal structure of a salt with a protonated sugar cation and a cobalt(II) complex anion: (GlcN–H, K)[Co(NCS)4]·2H2O |
| title_full_unstemmed | Crystal structure of a salt with a protonated sugar cation and a cobalt(II) complex anion: (GlcN–H, K)[Co(NCS)4]·2H2O |
| title_short | Crystal structure of a salt with a protonated sugar cation and a cobalt(II) complex anion: (GlcN–H, K)[Co(NCS)4]·2H2O |
| title_sort | crystal structure of a salt with a protonated sugar cation and a cobalt ii complex anion glcn h k co ncs 4 ·2h2o |
| topic | cobalt glucosamine ionic liquid crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314619011428 |
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