Superconducting Fullerene Nanowhiskers
We synthesized superconducting fullerene nanowhiskers (C<sub>60</sub>NWs) by potassium (K) intercalation. They showed large superconducting volume fractions, as high as 80%. The superconducting transition temperature at 17 K was independent of the K content (x) in the ran...
Main Authors: | , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
MDPI AG
2012-04-01
|
Series: | Molecules |
Subjects: | |
Online Access: | http://www.mdpi.com/1420-3049/17/5/4851 |
_version_ | 1818444815263596544 |
---|---|
author | Yoshihiko Takano Takahide Yamaguchi Hiroyuki Okazaki Takatsugu Wakahara Toshinori Ozaki Kun’ichi Miyazawa Ryoei Kato Hiroyuki Takeya |
author_facet | Yoshihiko Takano Takahide Yamaguchi Hiroyuki Okazaki Takatsugu Wakahara Toshinori Ozaki Kun’ichi Miyazawa Ryoei Kato Hiroyuki Takeya |
author_sort | Yoshihiko Takano |
collection | DOAJ |
description | We synthesized superconducting fullerene nanowhiskers (C<sub>60</sub>NWs) by potassium (K) intercalation. They showed large superconducting volume fractions, as high as 80%. The superconducting transition temperature at 17 K was independent of the K content (x) in the range between 1.6 and 6.0 in K-doped C<sub>60</sub> nanowhiskers (K<sub>x</sub>C<sub>60</sub>NWs), while the superconducting volume fractions changed with x. The highest shielding fraction of a full shielding volume was observed in the material of K<sub>3.3</sub>C<sub>60</sub>NW by heating at 200 °C. On the other hand, that of a K-doped fullerene (K-C<sub>60</sub>) crystal was less than 1%. We report the superconducting behaviors of our newly synthesized K<sub>x</sub>C<sub>60</sub>NWs in comparison to those of K<sub>x</sub>C<sub>60</sub> crystals, which show superconductivity at 19 K in K<sub>3</sub>C<sub>60</sub>. The lattice structures are also discussed, based on the x-ray diffraction (XRD) analyses. |
first_indexed | 2024-12-14T19:21:56Z |
format | Article |
id | doaj.art-4c1aba7d27ca4c079e4ba3b888428a42 |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-12-14T19:21:56Z |
publishDate | 2012-04-01 |
publisher | MDPI AG |
record_format | Article |
series | Molecules |
spelling | doaj.art-4c1aba7d27ca4c079e4ba3b888428a422022-12-21T22:50:19ZengMDPI AGMolecules1420-30492012-04-011754851485910.3390/molecules17054851Superconducting Fullerene NanowhiskersYoshihiko TakanoTakahide YamaguchiHiroyuki OkazakiTakatsugu WakaharaToshinori OzakiKun’ichi MiyazawaRyoei KatoHiroyuki TakeyaWe synthesized superconducting fullerene nanowhiskers (C<sub>60</sub>NWs) by potassium (K) intercalation. They showed large superconducting volume fractions, as high as 80%. The superconducting transition temperature at 17 K was independent of the K content (x) in the range between 1.6 and 6.0 in K-doped C<sub>60</sub> nanowhiskers (K<sub>x</sub>C<sub>60</sub>NWs), while the superconducting volume fractions changed with x. The highest shielding fraction of a full shielding volume was observed in the material of K<sub>3.3</sub>C<sub>60</sub>NW by heating at 200 °C. On the other hand, that of a K-doped fullerene (K-C<sub>60</sub>) crystal was less than 1%. We report the superconducting behaviors of our newly synthesized K<sub>x</sub>C<sub>60</sub>NWs in comparison to those of K<sub>x</sub>C<sub>60</sub> crystals, which show superconductivity at 19 K in K<sub>3</sub>C<sub>60</sub>. The lattice structures are also discussed, based on the x-ray diffraction (XRD) analyses.http://www.mdpi.com/1420-3049/17/5/4851fullerene nanowhiskersuperconductorpotassium intercalation |
spellingShingle | Yoshihiko Takano Takahide Yamaguchi Hiroyuki Okazaki Takatsugu Wakahara Toshinori Ozaki Kun’ichi Miyazawa Ryoei Kato Hiroyuki Takeya Superconducting Fullerene Nanowhiskers Molecules fullerene nanowhisker superconductor potassium intercalation |
title | Superconducting Fullerene Nanowhiskers |
title_full | Superconducting Fullerene Nanowhiskers |
title_fullStr | Superconducting Fullerene Nanowhiskers |
title_full_unstemmed | Superconducting Fullerene Nanowhiskers |
title_short | Superconducting Fullerene Nanowhiskers |
title_sort | superconducting fullerene nanowhiskers |
topic | fullerene nanowhisker superconductor potassium intercalation |
url | http://www.mdpi.com/1420-3049/17/5/4851 |
work_keys_str_mv | AT yoshihikotakano superconductingfullerenenanowhiskers AT takahideyamaguchi superconductingfullerenenanowhiskers AT hiroyukiokazaki superconductingfullerenenanowhiskers AT takatsuguwakahara superconductingfullerenenanowhiskers AT toshinoriozaki superconductingfullerenenanowhiskers AT kunichimiyazawa superconductingfullerenenanowhiskers AT ryoeikato superconductingfullerenenanowhiskers AT hiroyukitakeya superconductingfullerenenanowhiskers |