Superconducting Fullerene Nanowhiskers

We synthesized superconducting fullerene nanowhiskers (C<sub>60</sub>NWs) by potassium (K) intercalation. They showed large superconducting volume fractions, as high as 80%. The superconducting transition temperature at 17 K was independent of the K content (x) in the ran...

Full description

Bibliographic Details
Main Authors: Yoshihiko Takano, Takahide Yamaguchi, Hiroyuki Okazaki, Takatsugu Wakahara, Toshinori Ozaki, Kun’ichi Miyazawa, Ryoei Kato, Hiroyuki Takeya
Format: Article
Language:English
Published: MDPI AG 2012-04-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/17/5/4851
_version_ 1818444815263596544
author Yoshihiko Takano
Takahide Yamaguchi
Hiroyuki Okazaki
Takatsugu Wakahara
Toshinori Ozaki
Kun’ichi Miyazawa
Ryoei Kato
Hiroyuki Takeya
author_facet Yoshihiko Takano
Takahide Yamaguchi
Hiroyuki Okazaki
Takatsugu Wakahara
Toshinori Ozaki
Kun’ichi Miyazawa
Ryoei Kato
Hiroyuki Takeya
author_sort Yoshihiko Takano
collection DOAJ
description We synthesized superconducting fullerene nanowhiskers (C<sub>60</sub>NWs) by potassium (K) intercalation. They showed large superconducting volume fractions, as high as 80%. The superconducting transition temperature at 17 K was independent of the K content (x) in the range between 1.6 and 6.0 in K-doped C<sub>60</sub> nanowhiskers (K<sub>x</sub>C<sub>60</sub>NWs), while the superconducting volume fractions changed with x. The highest shielding fraction of a full shielding volume was observed in the material of K<sub>3.3</sub>C<sub>60</sub>NW by heating at 200 °C. On the other hand, that of a K-doped fullerene (K-C<sub>60</sub>) crystal was less than 1%. We report the superconducting behaviors of our newly synthesized K<sub>x</sub>C<sub>60</sub>NWs in comparison to those of K<sub>x</sub>C<sub>60</sub> crystals, which show superconductivity at 19 K in K<sub>3</sub>C<sub>60</sub>. The lattice structures are also discussed, based on the x-ray diffraction (XRD) analyses.
first_indexed 2024-12-14T19:21:56Z
format Article
id doaj.art-4c1aba7d27ca4c079e4ba3b888428a42
institution Directory Open Access Journal
issn 1420-3049
language English
last_indexed 2024-12-14T19:21:56Z
publishDate 2012-04-01
publisher MDPI AG
record_format Article
series Molecules
spelling doaj.art-4c1aba7d27ca4c079e4ba3b888428a422022-12-21T22:50:19ZengMDPI AGMolecules1420-30492012-04-011754851485910.3390/molecules17054851Superconducting Fullerene NanowhiskersYoshihiko TakanoTakahide YamaguchiHiroyuki OkazakiTakatsugu WakaharaToshinori OzakiKun’ichi MiyazawaRyoei KatoHiroyuki TakeyaWe synthesized superconducting fullerene nanowhiskers (C<sub>60</sub>NWs) by potassium (K) intercalation. They showed large superconducting volume fractions, as high as 80%. The superconducting transition temperature at 17 K was independent of the K content (x) in the range between 1.6 and 6.0 in K-doped C<sub>60</sub> nanowhiskers (K<sub>x</sub>C<sub>60</sub>NWs), while the superconducting volume fractions changed with x. The highest shielding fraction of a full shielding volume was observed in the material of K<sub>3.3</sub>C<sub>60</sub>NW by heating at 200 °C. On the other hand, that of a K-doped fullerene (K-C<sub>60</sub>) crystal was less than 1%. We report the superconducting behaviors of our newly synthesized K<sub>x</sub>C<sub>60</sub>NWs in comparison to those of K<sub>x</sub>C<sub>60</sub> crystals, which show superconductivity at 19 K in K<sub>3</sub>C<sub>60</sub>. The lattice structures are also discussed, based on the x-ray diffraction (XRD) analyses.http://www.mdpi.com/1420-3049/17/5/4851fullerene nanowhiskersuperconductorpotassium intercalation
spellingShingle Yoshihiko Takano
Takahide Yamaguchi
Hiroyuki Okazaki
Takatsugu Wakahara
Toshinori Ozaki
Kun’ichi Miyazawa
Ryoei Kato
Hiroyuki Takeya
Superconducting Fullerene Nanowhiskers
Molecules
fullerene nanowhisker
superconductor
potassium intercalation
title Superconducting Fullerene Nanowhiskers
title_full Superconducting Fullerene Nanowhiskers
title_fullStr Superconducting Fullerene Nanowhiskers
title_full_unstemmed Superconducting Fullerene Nanowhiskers
title_short Superconducting Fullerene Nanowhiskers
title_sort superconducting fullerene nanowhiskers
topic fullerene nanowhisker
superconductor
potassium intercalation
url http://www.mdpi.com/1420-3049/17/5/4851
work_keys_str_mv AT yoshihikotakano superconductingfullerenenanowhiskers
AT takahideyamaguchi superconductingfullerenenanowhiskers
AT hiroyukiokazaki superconductingfullerenenanowhiskers
AT takatsuguwakahara superconductingfullerenenanowhiskers
AT toshinoriozaki superconductingfullerenenanowhiskers
AT kunichimiyazawa superconductingfullerenenanowhiskers
AT ryoeikato superconductingfullerenenanowhiskers
AT hiroyukitakeya superconductingfullerenenanowhiskers