Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterization
In the scope of this study, acesulfame ace, acs -nicotinamide na mixed ligand complexes of Mg II , Ca II , Sr II and Ba II were synthesized for the first time. Possible formulas for complexes were determined as [Mg H2O 4 na 2] acs 2, [Ca H2O 6 na 2] acs 2, [Sr H2O 7 na 2] acs 2, [Ba H2O 7 na 2]...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Hitit University
2014-12-01
|
| Series: | Hittite Journal of Science and Engineering |
| Subjects: | |
| Online Access: | https://dergipark.org.tr/tr/download/article-file/1506975 |
| _version_ | 1797662723115319296 |
|---|---|
| author | Dursun Ali Kose Omer Yurdakul |
| author_facet | Dursun Ali Kose Omer Yurdakul |
| author_sort | Dursun Ali Kose |
| collection | DOAJ |
| description | In the scope of this study, acesulfame ace, acs -nicotinamide na mixed ligand complexes of Mg II , Ca II , Sr II and Ba II were synthesized for the first time. Possible formulas for complexes were determined as [Mg H2O 4 na 2] acs 2, [Ca H2O 6 na 2] acs 2, [Sr H2O 7 na 2] acs 2, [Ba H2O 7 na 2] acs 2 . It was observed that acesulfame ligands within structure were located two moles each at outer surface of coordination sphere acting as counter-ion allowing the charge balance of structure. The solubility of compounds gaining ionic character in this way was determined as quite well as compared to complex structures. Characterizations of complexes synthesized were performed via melting point analysis, elemental analysis, mass spectroscopy and FT-IR spectroscopy methods. Thermal properties of complexes obtained were determined with tandem TG-DTG and DTA techniques. It was found that the coordination spheres of metal cations within compounds obtained in this study were filled with nicotinamide and aqua ligands |
| first_indexed | 2024-03-11T19:03:14Z |
| format | Article |
| id | doaj.art-4c23b11b0e5d4c5084e3c07fa97d9781 |
| institution | Directory Open Access Journal |
| issn | 2148-4171 |
| language | English |
| last_indexed | 2024-03-11T19:03:14Z |
| publishDate | 2014-12-01 |
| publisher | Hitit University |
| record_format | Article |
| series | Hittite Journal of Science and Engineering |
| spelling | doaj.art-4c23b11b0e5d4c5084e3c07fa97d97812023-10-10T11:17:27ZengHitit UniversityHittite Journal of Science and Engineering2148-41712014-12-0111515710.17350/HJSE19030000008150Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterizationDursun Ali Kose0Omer Yurdakul1Hitit University, Department of Chemistry, Corum, TurkeyHitit University, Department of Chemistry, Corum, TurkeyIn the scope of this study, acesulfame ace, acs -nicotinamide na mixed ligand complexes of Mg II , Ca II , Sr II and Ba II were synthesized for the first time. Possible formulas for complexes were determined as [Mg H2O 4 na 2] acs 2, [Ca H2O 6 na 2] acs 2, [Sr H2O 7 na 2] acs 2, [Ba H2O 7 na 2] acs 2 . It was observed that acesulfame ligands within structure were located two moles each at outer surface of coordination sphere acting as counter-ion allowing the charge balance of structure. The solubility of compounds gaining ionic character in this way was determined as quite well as compared to complex structures. Characterizations of complexes synthesized were performed via melting point analysis, elemental analysis, mass spectroscopy and FT-IR spectroscopy methods. Thermal properties of complexes obtained were determined with tandem TG-DTG and DTA techniques. It was found that the coordination spheres of metal cations within compounds obtained in this study were filled with nicotinamide and aqua ligandshttps://dergipark.org.tr/tr/download/article-file/1506975acesulfamenicotinamideearth alkaline metalscoordination compoundthermal properties. |
| spellingShingle | Dursun Ali Kose Omer Yurdakul Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterization Hittite Journal of Science and Engineering acesulfame nicotinamide earth alkaline metals coordination compound thermal properties. |
| title | Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterization |
| title_full | Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterization |
| title_fullStr | Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterization |
| title_full_unstemmed | Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterization |
| title_short | Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterization |
| title_sort | mixed ligand complexes of acesulfame nicotinamide with earth alkaline metal cations mgii caii baii and srii synthesis and characterization |
| topic | acesulfame nicotinamide earth alkaline metals coordination compound thermal properties. |
| url | https://dergipark.org.tr/tr/download/article-file/1506975 |
| work_keys_str_mv | AT dursunalikose mixedligandcomplexesofacesulfamenicotinamidewithearthalkalinemetalcationsmgiicaiibaiiandsriisynthesisandcharacterization AT omeryurdakul mixedligandcomplexesofacesulfamenicotinamidewithearthalkalinemetalcationsmgiicaiibaiiandsriisynthesisandcharacterization |