Investigation of significantly high barrier height in Cu/GaN Schottky diode

Current-voltage (I-V) measurements combined with analytical calculations have been used to explain mechanisms for forward-bias current flow in Copper (Cu) Schottky diodes fabricated on Gallium Nitride (GaN) epitaxial films. An ideality factor of 1.7 was found at room temperature (RT), which indicate...

Full description

Bibliographic Details
Main Authors: Manjari Garg, Ashutosh Kumar, S. Nagarajan, M. Sopanen, R. Singh
Format: Article
Language:English
Published: AIP Publishing LLC 2016-01-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.4939936
_version_ 1828180285356769280
author Manjari Garg
Ashutosh Kumar
S. Nagarajan
M. Sopanen
R. Singh
author_facet Manjari Garg
Ashutosh Kumar
S. Nagarajan
M. Sopanen
R. Singh
author_sort Manjari Garg
collection DOAJ
description Current-voltage (I-V) measurements combined with analytical calculations have been used to explain mechanisms for forward-bias current flow in Copper (Cu) Schottky diodes fabricated on Gallium Nitride (GaN) epitaxial films. An ideality factor of 1.7 was found at room temperature (RT), which indicated deviation from thermionic emission (TE) mechanism for current flow in the Schottky diode. Instead the current transport was better explained using the thermionic field-emission (TFE) mechanism. A high barrier height of 1.19 eV was obtained at room temperature. X-ray photoelectron spectroscopy (XPS) was used to investigate the plausible reason for observing Schottky barrier height (SBH) that is significantly higher than as predicted by the Schottky-Mott model for Cu/GaN diodes. XPS measurements revealed the presence of an ultrathin cuprous oxide (Cu2O) layer at the interface between Cu and GaN. With Cu2O acting as a degenerate p-type semiconductor with high work function of 5.36 eV, a high barrier height of 1.19 eV is obtained for the Cu/Cu2O/GaN Schottky diode. Moreover, the ideality factor and barrier height were found to be temperature dependent, implying spatial inhomogeneity of barrier height at the metal semiconductor interface.
first_indexed 2024-04-12T05:42:58Z
format Article
id doaj.art-4c3a8fead54e4350a22893993961b875
institution Directory Open Access Journal
issn 2158-3226
language English
last_indexed 2024-04-12T05:42:58Z
publishDate 2016-01-01
publisher AIP Publishing LLC
record_format Article
series AIP Advances
spelling doaj.art-4c3a8fead54e4350a22893993961b8752022-12-22T03:45:32ZengAIP Publishing LLCAIP Advances2158-32262016-01-0161015206015206-710.1063/1.4939936025601ADVInvestigation of significantly high barrier height in Cu/GaN Schottky diodeManjari Garg0Ashutosh Kumar1S. Nagarajan2M. Sopanen3R. Singh4Department of Physics, Indian Institute of Technology, Delhi, Hauz Khas, New Delhi-110016, IndiaDepartment of Physics, Indian Institute of Technology, Delhi, Hauz Khas, New Delhi-110016, IndiaDepartment of Micro and Nanosciences, Aalto University, P.O. Box 13500, FI-00076, Aalto, FinlandDepartment of Micro and Nanosciences, Aalto University, P.O. Box 13500, FI-00076, Aalto, FinlandDepartment of Physics, Indian Institute of Technology, Delhi, Hauz Khas, New Delhi-110016, IndiaCurrent-voltage (I-V) measurements combined with analytical calculations have been used to explain mechanisms for forward-bias current flow in Copper (Cu) Schottky diodes fabricated on Gallium Nitride (GaN) epitaxial films. An ideality factor of 1.7 was found at room temperature (RT), which indicated deviation from thermionic emission (TE) mechanism for current flow in the Schottky diode. Instead the current transport was better explained using the thermionic field-emission (TFE) mechanism. A high barrier height of 1.19 eV was obtained at room temperature. X-ray photoelectron spectroscopy (XPS) was used to investigate the plausible reason for observing Schottky barrier height (SBH) that is significantly higher than as predicted by the Schottky-Mott model for Cu/GaN diodes. XPS measurements revealed the presence of an ultrathin cuprous oxide (Cu2O) layer at the interface between Cu and GaN. With Cu2O acting as a degenerate p-type semiconductor with high work function of 5.36 eV, a high barrier height of 1.19 eV is obtained for the Cu/Cu2O/GaN Schottky diode. Moreover, the ideality factor and barrier height were found to be temperature dependent, implying spatial inhomogeneity of barrier height at the metal semiconductor interface.http://dx.doi.org/10.1063/1.4939936
spellingShingle Manjari Garg
Ashutosh Kumar
S. Nagarajan
M. Sopanen
R. Singh
Investigation of significantly high barrier height in Cu/GaN Schottky diode
AIP Advances
title Investigation of significantly high barrier height in Cu/GaN Schottky diode
title_full Investigation of significantly high barrier height in Cu/GaN Schottky diode
title_fullStr Investigation of significantly high barrier height in Cu/GaN Schottky diode
title_full_unstemmed Investigation of significantly high barrier height in Cu/GaN Schottky diode
title_short Investigation of significantly high barrier height in Cu/GaN Schottky diode
title_sort investigation of significantly high barrier height in cu gan schottky diode
url http://dx.doi.org/10.1063/1.4939936
work_keys_str_mv AT manjarigarg investigationofsignificantlyhighbarrierheightincuganschottkydiode
AT ashutoshkumar investigationofsignificantlyhighbarrierheightincuganschottkydiode
AT snagarajan investigationofsignificantlyhighbarrierheightincuganschottkydiode
AT msopanen investigationofsignificantlyhighbarrierheightincuganschottkydiode
AT rsingh investigationofsignificantlyhighbarrierheightincuganschottkydiode