Red ceramic and concrete waste as replacement of portland cement: Microstructure aspect of eco-mortar in external sulfate attack

The use of red ceramic and concrete waste as a replacement for cement has great importance from an environmental point of view, and it is necessary to understand its influence on the cement matrix's performance. In this paper, mortar mixtures with partial replacement of the Portland cement by t...

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Main Authors: Fernanda Brekailo, Eduardo Pereira, Elias Pereira, Marcelo M. Farias, Ronaldo A. Medeiros-Junior
Format: Article
Language:English
Published: Elsevier 2022-03-01
Series:Cleaner Materials
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2772397621000344
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author Fernanda Brekailo
Eduardo Pereira
Elias Pereira
Marcelo M. Farias
Ronaldo A. Medeiros-Junior
author_facet Fernanda Brekailo
Eduardo Pereira
Elias Pereira
Marcelo M. Farias
Ronaldo A. Medeiros-Junior
author_sort Fernanda Brekailo
collection DOAJ
description The use of red ceramic and concrete waste as a replacement for cement has great importance from an environmental point of view, and it is necessary to understand its influence on the cement matrix's performance. In this paper, mortar mixtures with partial replacement of the Portland cement by the addition of 3, 5, 12, and 20% of limestone filler (as reference), concrete waste, and red ceramic were subjected to sulfate attack. The accelerated test was monitored until the age of 98 days and microstructure analysis techniques were applied. Mortars with ceramic and concrete waste addition had greater expansion than the reference mortar. The addition of 12% of limestone filler mitigated the expansive reactions. The mortars with any type of addition had greater porosities. In this case, the aluminum oxide content in the ceramic and the calcium carbonate and calcium oxide contents in the concrete waste acted as a source for reaction with the sulfate ions. Due to the attack, the pore size distribution changed, showing that the pores in the band between 0.01 and 1 µm were filled with ettringite. The microcracks from the attack increased the pores with diameters over 1 µm. This performance reduction against sulfate attack must be considered for the use of ceramic and concrete residues in eco-efficient mortars, especially when it is inserted in environments subjected to this type of degradation.
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spelling doaj.art-4c4ae21e980f4dce8dc2792549e3890c2022-12-22T00:05:11ZengElsevierCleaner Materials2772-39762022-03-013100034Red ceramic and concrete waste as replacement of portland cement: Microstructure aspect of eco-mortar in external sulfate attackFernanda Brekailo0Eduardo Pereira1Elias Pereira2Marcelo M. Farias3Ronaldo A. Medeiros-Junior4Department of Civil Engineering, State University of Ponta Grossa, Ponta Grossa, Paraná CEP 84030-900, Brazil; Corresponding author.Department of Civil Engineering, State University of Ponta Grossa, Ponta Grossa, Paraná CEP 84030-900, BrazilDepartment of Civil Engineering, Graduate Student, Engineering and Materials Science Graduate Department, State University of Ponta Grossa, Ponta Grossa, Paraná CEP 84030-900, BrazilGraduate Student, Engineering and Materials Science Graduate Department, State University of Ponta Grossa, Ponta Grossa, Paraná CEP 84030-900, BrazilCivil Engineering Studies Center (CESEC), Postgraduate Program in Civil Engineering (PPGEC), Federal University of Parana – UFPR, Curitiba, BrazilThe use of red ceramic and concrete waste as a replacement for cement has great importance from an environmental point of view, and it is necessary to understand its influence on the cement matrix's performance. In this paper, mortar mixtures with partial replacement of the Portland cement by the addition of 3, 5, 12, and 20% of limestone filler (as reference), concrete waste, and red ceramic were subjected to sulfate attack. The accelerated test was monitored until the age of 98 days and microstructure analysis techniques were applied. Mortars with ceramic and concrete waste addition had greater expansion than the reference mortar. The addition of 12% of limestone filler mitigated the expansive reactions. The mortars with any type of addition had greater porosities. In this case, the aluminum oxide content in the ceramic and the calcium carbonate and calcium oxide contents in the concrete waste acted as a source for reaction with the sulfate ions. Due to the attack, the pore size distribution changed, showing that the pores in the band between 0.01 and 1 µm were filled with ettringite. The microcracks from the attack increased the pores with diameters over 1 µm. This performance reduction against sulfate attack must be considered for the use of ceramic and concrete residues in eco-efficient mortars, especially when it is inserted in environments subjected to this type of degradation.http://www.sciencedirect.com/science/article/pii/S2772397621000344Red ceramic wasteConcrete wasteSustainable constructionEco-mortar productionSulfate attack
spellingShingle Fernanda Brekailo
Eduardo Pereira
Elias Pereira
Marcelo M. Farias
Ronaldo A. Medeiros-Junior
Red ceramic and concrete waste as replacement of portland cement: Microstructure aspect of eco-mortar in external sulfate attack
Cleaner Materials
Red ceramic waste
Concrete waste
Sustainable construction
Eco-mortar production
Sulfate attack
title Red ceramic and concrete waste as replacement of portland cement: Microstructure aspect of eco-mortar in external sulfate attack
title_full Red ceramic and concrete waste as replacement of portland cement: Microstructure aspect of eco-mortar in external sulfate attack
title_fullStr Red ceramic and concrete waste as replacement of portland cement: Microstructure aspect of eco-mortar in external sulfate attack
title_full_unstemmed Red ceramic and concrete waste as replacement of portland cement: Microstructure aspect of eco-mortar in external sulfate attack
title_short Red ceramic and concrete waste as replacement of portland cement: Microstructure aspect of eco-mortar in external sulfate attack
title_sort red ceramic and concrete waste as replacement of portland cement microstructure aspect of eco mortar in external sulfate attack
topic Red ceramic waste
Concrete waste
Sustainable construction
Eco-mortar production
Sulfate attack
url http://www.sciencedirect.com/science/article/pii/S2772397621000344
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