Directed self-assembly of a two-state block copolymer system
Abstract In this work, ladder-shaped block copolymer structures consisting of parallel bars, bends, and T-junctions are formed inside square confinement. We define binary states by the two degenerate alignment orientations, and study properties of the two-state system. We control the binary states b...
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Format: | Article |
Language: | English |
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SpringerOpen
2018-09-01
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Series: | Nano Convergence |
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Online Access: | http://link.springer.com/article/10.1186/s40580-018-0156-z |
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author | Hyung Wan Do Hong Kyoon Choi Karim R. Gadelrab Jae-Byum Chang Alfredo Alexander-Katz Caroline A. Ross Karl K. Berggren |
author_facet | Hyung Wan Do Hong Kyoon Choi Karim R. Gadelrab Jae-Byum Chang Alfredo Alexander-Katz Caroline A. Ross Karl K. Berggren |
author_sort | Hyung Wan Do |
collection | DOAJ |
description | Abstract In this work, ladder-shaped block copolymer structures consisting of parallel bars, bends, and T-junctions are formed inside square confinement. We define binary states by the two degenerate alignment orientations, and study properties of the two-state system. We control the binary states by creating openings around the confinement, changing the confinement geometry, or placing lithographic guiding patterns inside the confinement. Self-consistent field theory simulations show templating effect from the wall openings and reproduce the experimental results. We demonstrate scaling of a single binary state into a larger binary state array with individual binary state control. |
first_indexed | 2024-12-13T14:37:36Z |
format | Article |
id | doaj.art-4c5915c0656b4e5182bd9d170c7146d6 |
institution | Directory Open Access Journal |
issn | 2196-5404 |
language | English |
last_indexed | 2024-12-13T14:37:36Z |
publishDate | 2018-09-01 |
publisher | SpringerOpen |
record_format | Article |
series | Nano Convergence |
spelling | doaj.art-4c5915c0656b4e5182bd9d170c7146d62022-12-21T23:41:41ZengSpringerOpenNano Convergence2196-54042018-09-01511910.1186/s40580-018-0156-zDirected self-assembly of a two-state block copolymer systemHyung Wan Do0Hong Kyoon Choi1Karim R. Gadelrab2Jae-Byum Chang3Alfredo Alexander-Katz4Caroline A. Ross5Karl K. Berggren6Department of Electrical Engineering and Computer Science, Massachusetts Institute of TechnologyDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyDepartment of Electrical Engineering and Computer Science, Massachusetts Institute of TechnologyAbstract In this work, ladder-shaped block copolymer structures consisting of parallel bars, bends, and T-junctions are formed inside square confinement. We define binary states by the two degenerate alignment orientations, and study properties of the two-state system. We control the binary states by creating openings around the confinement, changing the confinement geometry, or placing lithographic guiding patterns inside the confinement. Self-consistent field theory simulations show templating effect from the wall openings and reproduce the experimental results. We demonstrate scaling of a single binary state into a larger binary state array with individual binary state control.http://link.springer.com/article/10.1186/s40580-018-0156-zBlock copolymersSelf-assemblyGraphoepitaxyNanostructuresLithographic confinement |
spellingShingle | Hyung Wan Do Hong Kyoon Choi Karim R. Gadelrab Jae-Byum Chang Alfredo Alexander-Katz Caroline A. Ross Karl K. Berggren Directed self-assembly of a two-state block copolymer system Nano Convergence Block copolymers Self-assembly Graphoepitaxy Nanostructures Lithographic confinement |
title | Directed self-assembly of a two-state block copolymer system |
title_full | Directed self-assembly of a two-state block copolymer system |
title_fullStr | Directed self-assembly of a two-state block copolymer system |
title_full_unstemmed | Directed self-assembly of a two-state block copolymer system |
title_short | Directed self-assembly of a two-state block copolymer system |
title_sort | directed self assembly of a two state block copolymer system |
topic | Block copolymers Self-assembly Graphoepitaxy Nanostructures Lithographic confinement |
url | http://link.springer.com/article/10.1186/s40580-018-0156-z |
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