Directed self-assembly of a two-state block copolymer system

Abstract In this work, ladder-shaped block copolymer structures consisting of parallel bars, bends, and T-junctions are formed inside square confinement. We define binary states by the two degenerate alignment orientations, and study properties of the two-state system. We control the binary states b...

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Main Authors: Hyung Wan Do, Hong Kyoon Choi, Karim R. Gadelrab, Jae-Byum Chang, Alfredo Alexander-Katz, Caroline A. Ross, Karl K. Berggren
Format: Article
Language:English
Published: SpringerOpen 2018-09-01
Series:Nano Convergence
Subjects:
Online Access:http://link.springer.com/article/10.1186/s40580-018-0156-z
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author Hyung Wan Do
Hong Kyoon Choi
Karim R. Gadelrab
Jae-Byum Chang
Alfredo Alexander-Katz
Caroline A. Ross
Karl K. Berggren
author_facet Hyung Wan Do
Hong Kyoon Choi
Karim R. Gadelrab
Jae-Byum Chang
Alfredo Alexander-Katz
Caroline A. Ross
Karl K. Berggren
author_sort Hyung Wan Do
collection DOAJ
description Abstract In this work, ladder-shaped block copolymer structures consisting of parallel bars, bends, and T-junctions are formed inside square confinement. We define binary states by the two degenerate alignment orientations, and study properties of the two-state system. We control the binary states by creating openings around the confinement, changing the confinement geometry, or placing lithographic guiding patterns inside the confinement. Self-consistent field theory simulations show templating effect from the wall openings and reproduce the experimental results. We demonstrate scaling of a single binary state into a larger binary state array with individual binary state control.
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spelling doaj.art-4c5915c0656b4e5182bd9d170c7146d62022-12-21T23:41:41ZengSpringerOpenNano Convergence2196-54042018-09-01511910.1186/s40580-018-0156-zDirected self-assembly of a two-state block copolymer systemHyung Wan Do0Hong Kyoon Choi1Karim R. Gadelrab2Jae-Byum Chang3Alfredo Alexander-Katz4Caroline A. Ross5Karl K. Berggren6Department of Electrical Engineering and Computer Science, Massachusetts Institute of TechnologyDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyDepartment of Electrical Engineering and Computer Science, Massachusetts Institute of TechnologyAbstract In this work, ladder-shaped block copolymer structures consisting of parallel bars, bends, and T-junctions are formed inside square confinement. We define binary states by the two degenerate alignment orientations, and study properties of the two-state system. We control the binary states by creating openings around the confinement, changing the confinement geometry, or placing lithographic guiding patterns inside the confinement. Self-consistent field theory simulations show templating effect from the wall openings and reproduce the experimental results. We demonstrate scaling of a single binary state into a larger binary state array with individual binary state control.http://link.springer.com/article/10.1186/s40580-018-0156-zBlock copolymersSelf-assemblyGraphoepitaxyNanostructuresLithographic confinement
spellingShingle Hyung Wan Do
Hong Kyoon Choi
Karim R. Gadelrab
Jae-Byum Chang
Alfredo Alexander-Katz
Caroline A. Ross
Karl K. Berggren
Directed self-assembly of a two-state block copolymer system
Nano Convergence
Block copolymers
Self-assembly
Graphoepitaxy
Nanostructures
Lithographic confinement
title Directed self-assembly of a two-state block copolymer system
title_full Directed self-assembly of a two-state block copolymer system
title_fullStr Directed self-assembly of a two-state block copolymer system
title_full_unstemmed Directed self-assembly of a two-state block copolymer system
title_short Directed self-assembly of a two-state block copolymer system
title_sort directed self assembly of a two state block copolymer system
topic Block copolymers
Self-assembly
Graphoepitaxy
Nanostructures
Lithographic confinement
url http://link.springer.com/article/10.1186/s40580-018-0156-z
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