Novel Trends in the Development of Surfactant-Based Hydraulic Fracturing Fluids: A Review

Viscoelastic surfactants (VES) are amphiphilic molecules which self-assemble into long polymer-like aggregates—wormlike micelles. Such micellar chains form an entangled network, imparting high viscosity and viscoelasticity to aqueous solutions. VES are currently attracting great attention as the mai...

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Main Authors: Andrey V. Shibaev, Andrei A. Osiptsov, Olga E. Philippova
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Gels
Subjects:
Online Access:https://www.mdpi.com/2310-2861/7/4/258
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author Andrey V. Shibaev
Andrei A. Osiptsov
Olga E. Philippova
author_facet Andrey V. Shibaev
Andrei A. Osiptsov
Olga E. Philippova
author_sort Andrey V. Shibaev
collection DOAJ
description Viscoelastic surfactants (VES) are amphiphilic molecules which self-assemble into long polymer-like aggregates—wormlike micelles. Such micellar chains form an entangled network, imparting high viscosity and viscoelasticity to aqueous solutions. VES are currently attracting great attention as the main components of clean hydraulic fracturing fluids used for enhanced oil recovery (EOR). Fracturing fluids consist of proppant particles suspended in a viscoelastic medium. They are pumped into a wellbore under high pressure to create fractures, through which the oil can flow into the well. Polymer gels have been used most often for fracturing operations; however, VES solutions are advantageous as they usually require no breakers other than reservoir hydrocarbons to be cleaned from the well. Many attempts have recently been made to improve the viscoelastic properties, temperature, and salt resistance of VES fluids to make them a cost-effective alternative to polymer gels. This review aims at describing the novel concepts and advancements in the fundamental science of VES-based fracturing fluids reported in the last few years, which have not yet been widely industrially implemented, but are significant for prospective future applications. Recent achievements, reviewed in this paper, include the use of oligomeric surfactants, surfactant mixtures, hybrid nanoparticle/VES, or polymer/VES fluids. The advantages and limitations of the different VES fluids are discussed. The fundamental reasons for the different ways of improvement of VES performance for fracturing are described.
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spelling doaj.art-4ca44db2d54a4764b21e640c77f9983a2023-11-23T08:28:41ZengMDPI AGGels2310-28612021-12-017425810.3390/gels7040258Novel Trends in the Development of Surfactant-Based Hydraulic Fracturing Fluids: A ReviewAndrey V. Shibaev0Andrei A. Osiptsov1Olga E. Philippova2Physics Department, Moscow State University, 119991 Moscow, RussiaSkolkovo Institute of Science and Technology (Skoltech), 121205 Moscow, RussiaPhysics Department, Moscow State University, 119991 Moscow, RussiaViscoelastic surfactants (VES) are amphiphilic molecules which self-assemble into long polymer-like aggregates—wormlike micelles. Such micellar chains form an entangled network, imparting high viscosity and viscoelasticity to aqueous solutions. VES are currently attracting great attention as the main components of clean hydraulic fracturing fluids used for enhanced oil recovery (EOR). Fracturing fluids consist of proppant particles suspended in a viscoelastic medium. They are pumped into a wellbore under high pressure to create fractures, through which the oil can flow into the well. Polymer gels have been used most often for fracturing operations; however, VES solutions are advantageous as they usually require no breakers other than reservoir hydrocarbons to be cleaned from the well. Many attempts have recently been made to improve the viscoelastic properties, temperature, and salt resistance of VES fluids to make them a cost-effective alternative to polymer gels. This review aims at describing the novel concepts and advancements in the fundamental science of VES-based fracturing fluids reported in the last few years, which have not yet been widely industrially implemented, but are significant for prospective future applications. Recent achievements, reviewed in this paper, include the use of oligomeric surfactants, surfactant mixtures, hybrid nanoparticle/VES, or polymer/VES fluids. The advantages and limitations of the different VES fluids are discussed. The fundamental reasons for the different ways of improvement of VES performance for fracturing are described.https://www.mdpi.com/2310-2861/7/4/258viscoelastic surfactantswormlike micellesgelsviscoelasticityoil recoveryhydraulic fracturing
spellingShingle Andrey V. Shibaev
Andrei A. Osiptsov
Olga E. Philippova
Novel Trends in the Development of Surfactant-Based Hydraulic Fracturing Fluids: A Review
Gels
viscoelastic surfactants
wormlike micelles
gels
viscoelasticity
oil recovery
hydraulic fracturing
title Novel Trends in the Development of Surfactant-Based Hydraulic Fracturing Fluids: A Review
title_full Novel Trends in the Development of Surfactant-Based Hydraulic Fracturing Fluids: A Review
title_fullStr Novel Trends in the Development of Surfactant-Based Hydraulic Fracturing Fluids: A Review
title_full_unstemmed Novel Trends in the Development of Surfactant-Based Hydraulic Fracturing Fluids: A Review
title_short Novel Trends in the Development of Surfactant-Based Hydraulic Fracturing Fluids: A Review
title_sort novel trends in the development of surfactant based hydraulic fracturing fluids a review
topic viscoelastic surfactants
wormlike micelles
gels
viscoelasticity
oil recovery
hydraulic fracturing
url https://www.mdpi.com/2310-2861/7/4/258
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