Separation of 1,3-Propanediol from Aqueous Solutions by Ion Exchange Chromatography
1,3-propanediol is a promising monomer with many applications and can be produced by bioconversion of renewable resources. The separation of this product from fermentation broth is a difficult task. In this work, the application of cation exchange resin for the separation of 1,3-propanediol from mod...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Sciendo
2014-06-01
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| Series: | Polish Journal of Chemical Technology |
| Subjects: | |
| Online Access: | https://doi.org/10.2478/pjct-2014-0035 |
| _version_ | 1818584087541055488 |
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| author | Rukowicz Beata Miesiąc Ireneusz Alejski Krzysztof |
| author_facet | Rukowicz Beata Miesiąc Ireneusz Alejski Krzysztof |
| author_sort | Rukowicz Beata |
| collection | DOAJ |
| description | 1,3-propanediol is a promising monomer with many applications and can be produced by bioconversion of renewable resources. The separation of this product from fermentation broth is a difficult task. In this work, the application of cation exchange resin for the separation of 1,3-propanediol from model aqueous solution was examined. The best effect of separation of 1,3-propanediol from glycerol using sorption method was obtained for H+ resin form, although the observed partition coefficient of 1,3-propanediol was low. On the basis of the results of the sorption of 1,3-propanediol, the ionic forms of the resin were selected and used in the next experiments (H+, Ca2+, Ag+, Na+, Pb2+, Zn2+). The best results in ion exchange chromatography were obtained for cation exchange resin in H+ and Ca2+ form. The use of smaller particle size of resin and a longer length of the column allows to obtain better separation of mixtures. |
| first_indexed | 2024-12-16T08:15:36Z |
| format | Article |
| id | doaj.art-4cac32971c4e44e2b7938a4703454ff6 |
| institution | Directory Open Access Journal |
| issn | 1899-4741 |
| language | English |
| last_indexed | 2024-12-16T08:15:36Z |
| publishDate | 2014-06-01 |
| publisher | Sciendo |
| record_format | Article |
| series | Polish Journal of Chemical Technology |
| spelling | doaj.art-4cac32971c4e44e2b7938a4703454ff62022-12-21T22:38:15ZengSciendoPolish Journal of Chemical Technology1899-47412014-06-01162828610.2478/pjct-2014-0035pjct-2014-0035Separation of 1,3-Propanediol from Aqueous Solutions by Ion Exchange ChromatographyRukowicz Beata0Miesiąc Ireneusz1Alejski Krzysztof2Poznan University of Technology, Institute of Technology and Chemical Engineering, pl. M. Skłodowskiej-Curie 2, 60-965 Poznan, PolandPoznan University of Technology, Institute of Technology and Chemical Engineering, pl. M. Skłodowskiej-Curie 2, 60-965 Poznan, PolandPoznan University of Technology, Institute of Technology and Chemical Engineering, pl. M. Skłodowskiej-Curie 2, 60-965 Poznan, Poland1,3-propanediol is a promising monomer with many applications and can be produced by bioconversion of renewable resources. The separation of this product from fermentation broth is a difficult task. In this work, the application of cation exchange resin for the separation of 1,3-propanediol from model aqueous solution was examined. The best effect of separation of 1,3-propanediol from glycerol using sorption method was obtained for H+ resin form, although the observed partition coefficient of 1,3-propanediol was low. On the basis of the results of the sorption of 1,3-propanediol, the ionic forms of the resin were selected and used in the next experiments (H+, Ca2+, Ag+, Na+, Pb2+, Zn2+). The best results in ion exchange chromatography were obtained for cation exchange resin in H+ and Ca2+ form. The use of smaller particle size of resin and a longer length of the column allows to obtain better separation of mixtures.https://doi.org/10.2478/pjct-2014-00351,3-propanediolglycerolfermentationsorptionion exchange chromatography |
| spellingShingle | Rukowicz Beata Miesiąc Ireneusz Alejski Krzysztof Separation of 1,3-Propanediol from Aqueous Solutions by Ion Exchange Chromatography Polish Journal of Chemical Technology 1,3-propanediol glycerol fermentation sorption ion exchange chromatography |
| title | Separation of 1,3-Propanediol from Aqueous Solutions by Ion Exchange Chromatography |
| title_full | Separation of 1,3-Propanediol from Aqueous Solutions by Ion Exchange Chromatography |
| title_fullStr | Separation of 1,3-Propanediol from Aqueous Solutions by Ion Exchange Chromatography |
| title_full_unstemmed | Separation of 1,3-Propanediol from Aqueous Solutions by Ion Exchange Chromatography |
| title_short | Separation of 1,3-Propanediol from Aqueous Solutions by Ion Exchange Chromatography |
| title_sort | separation of 1 3 propanediol from aqueous solutions by ion exchange chromatography |
| topic | 1,3-propanediol glycerol fermentation sorption ion exchange chromatography |
| url | https://doi.org/10.2478/pjct-2014-0035 |
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