Impact of sunlight irradiation on CvFAP photodecarboxylation
A visible-light-driven photocatalytic decarboxylation of palmitic acid and related fatty acids is described in this study. Remarkable decarboxylation rates have been observed with full conversion in less than 20 min. In this study, we have demonstrated that sunlight irradiation, even on cloudy days,...
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Frontiers Media S.A.
2023-04-01
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Series: | Frontiers in Catalysis |
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Online Access: | https://www.frontiersin.org/articles/10.3389/fctls.2023.1165079/full |
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author | Alexandre S. França Gabriela C. Breda Gabriela C. Breda Kleber T. De Oliveira Rodrigo V. Almeida Frank Hollmann Rodrigo O. M. A. De Souza |
author_facet | Alexandre S. França Gabriela C. Breda Gabriela C. Breda Kleber T. De Oliveira Rodrigo V. Almeida Frank Hollmann Rodrigo O. M. A. De Souza |
author_sort | Alexandre S. França |
collection | DOAJ |
description | A visible-light-driven photocatalytic decarboxylation of palmitic acid and related fatty acids is described in this study. Remarkable decarboxylation rates have been observed with full conversion in less than 20 min. In this study, we have demonstrated that sunlight irradiation, even on cloudy days, can deliver similar results to traditional LED lamps while using much less energy and minimizing environmental impact. The findings indicate that the process of enzymatic decarboxylation could be useful for the production of different biofuels in the future. |
first_indexed | 2024-04-09T18:15:32Z |
format | Article |
id | doaj.art-4cbbdd985ac94471baed835412021385 |
institution | Directory Open Access Journal |
issn | 2673-7841 |
language | English |
last_indexed | 2024-04-09T18:15:32Z |
publishDate | 2023-04-01 |
publisher | Frontiers Media S.A. |
record_format | Article |
series | Frontiers in Catalysis |
spelling | doaj.art-4cbbdd985ac94471baed8354120213852023-04-13T04:50:45ZengFrontiers Media S.A.Frontiers in Catalysis2673-78412023-04-01310.3389/fctls.2023.11650791165079Impact of sunlight irradiation on CvFAP photodecarboxylationAlexandre S. França0Gabriela C. Breda1Gabriela C. Breda2Kleber T. De Oliveira3Rodrigo V. Almeida4Frank Hollmann5Rodrigo O. M. A. De Souza6Biocatalysis and Organic Synthesis Group, Chemistry Institute, Federal University of Rio de Janeiro, Rio de Janeiro, BrazilBiocatalysis and Organic Synthesis Group, Chemistry Institute, Federal University of Rio de Janeiro, Rio de Janeiro, BrazilLaboratório de Microbiologia Molecular e Proteínas, Biochemistry Department, Chemistry Institute, Federal University of Rio de Janeiro, Rio de Janeiro, BrazilDepartment of Chemistry, Federal University of São Carlos, São Carlos, São Paulo, BrazilLaboratório de Microbiologia Molecular e Proteínas, Biochemistry Department, Chemistry Institute, Federal University of Rio de Janeiro, Rio de Janeiro, BrazilDepartment of Biotechnology, Delft University of Technology, Delft, NetherlandsBiocatalysis and Organic Synthesis Group, Chemistry Institute, Federal University of Rio de Janeiro, Rio de Janeiro, BrazilA visible-light-driven photocatalytic decarboxylation of palmitic acid and related fatty acids is described in this study. Remarkable decarboxylation rates have been observed with full conversion in less than 20 min. In this study, we have demonstrated that sunlight irradiation, even on cloudy days, can deliver similar results to traditional LED lamps while using much less energy and minimizing environmental impact. The findings indicate that the process of enzymatic decarboxylation could be useful for the production of different biofuels in the future.https://www.frontiersin.org/articles/10.3389/fctls.2023.1165079/fullphotodecarboxylationbiocatalysisgreen chemistrysunlightCvFAP |
spellingShingle | Alexandre S. França Gabriela C. Breda Gabriela C. Breda Kleber T. De Oliveira Rodrigo V. Almeida Frank Hollmann Rodrigo O. M. A. De Souza Impact of sunlight irradiation on CvFAP photodecarboxylation Frontiers in Catalysis photodecarboxylation biocatalysis green chemistry sunlight CvFAP |
title | Impact of sunlight irradiation on CvFAP photodecarboxylation |
title_full | Impact of sunlight irradiation on CvFAP photodecarboxylation |
title_fullStr | Impact of sunlight irradiation on CvFAP photodecarboxylation |
title_full_unstemmed | Impact of sunlight irradiation on CvFAP photodecarboxylation |
title_short | Impact of sunlight irradiation on CvFAP photodecarboxylation |
title_sort | impact of sunlight irradiation on cvfap photodecarboxylation |
topic | photodecarboxylation biocatalysis green chemistry sunlight CvFAP |
url | https://www.frontiersin.org/articles/10.3389/fctls.2023.1165079/full |
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