Impact of sunlight irradiation on CvFAP photodecarboxylation

A visible-light-driven photocatalytic decarboxylation of palmitic acid and related fatty acids is described in this study. Remarkable decarboxylation rates have been observed with full conversion in less than 20 min. In this study, we have demonstrated that sunlight irradiation, even on cloudy days,...

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Main Authors: Alexandre S. França, Gabriela C. Breda, Kleber T. De Oliveira, Rodrigo V. Almeida, Frank Hollmann, Rodrigo O. M. A. De Souza
Format: Article
Language:English
Published: Frontiers Media S.A. 2023-04-01
Series:Frontiers in Catalysis
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fctls.2023.1165079/full
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author Alexandre S. França
Gabriela C. Breda
Gabriela C. Breda
Kleber T. De Oliveira
Rodrigo V. Almeida
Frank Hollmann
Rodrigo O. M. A. De Souza
author_facet Alexandre S. França
Gabriela C. Breda
Gabriela C. Breda
Kleber T. De Oliveira
Rodrigo V. Almeida
Frank Hollmann
Rodrigo O. M. A. De Souza
author_sort Alexandre S. França
collection DOAJ
description A visible-light-driven photocatalytic decarboxylation of palmitic acid and related fatty acids is described in this study. Remarkable decarboxylation rates have been observed with full conversion in less than 20 min. In this study, we have demonstrated that sunlight irradiation, even on cloudy days, can deliver similar results to traditional LED lamps while using much less energy and minimizing environmental impact. The findings indicate that the process of enzymatic decarboxylation could be useful for the production of different biofuels in the future.
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spelling doaj.art-4cbbdd985ac94471baed8354120213852023-04-13T04:50:45ZengFrontiers Media S.A.Frontiers in Catalysis2673-78412023-04-01310.3389/fctls.2023.11650791165079Impact of sunlight irradiation on CvFAP photodecarboxylationAlexandre S. França0Gabriela C. Breda1Gabriela C. Breda2Kleber T. De Oliveira3Rodrigo V. Almeida4Frank Hollmann5Rodrigo O. M. A. De Souza6Biocatalysis and Organic Synthesis Group, Chemistry Institute, Federal University of Rio de Janeiro, Rio de Janeiro, BrazilBiocatalysis and Organic Synthesis Group, Chemistry Institute, Federal University of Rio de Janeiro, Rio de Janeiro, BrazilLaboratório de Microbiologia Molecular e Proteínas, Biochemistry Department, Chemistry Institute, Federal University of Rio de Janeiro, Rio de Janeiro, BrazilDepartment of Chemistry, Federal University of São Carlos, São Carlos, São Paulo, BrazilLaboratório de Microbiologia Molecular e Proteínas, Biochemistry Department, Chemistry Institute, Federal University of Rio de Janeiro, Rio de Janeiro, BrazilDepartment of Biotechnology, Delft University of Technology, Delft, NetherlandsBiocatalysis and Organic Synthesis Group, Chemistry Institute, Federal University of Rio de Janeiro, Rio de Janeiro, BrazilA visible-light-driven photocatalytic decarboxylation of palmitic acid and related fatty acids is described in this study. Remarkable decarboxylation rates have been observed with full conversion in less than 20 min. In this study, we have demonstrated that sunlight irradiation, even on cloudy days, can deliver similar results to traditional LED lamps while using much less energy and minimizing environmental impact. The findings indicate that the process of enzymatic decarboxylation could be useful for the production of different biofuels in the future.https://www.frontiersin.org/articles/10.3389/fctls.2023.1165079/fullphotodecarboxylationbiocatalysisgreen chemistrysunlightCvFAP
spellingShingle Alexandre S. França
Gabriela C. Breda
Gabriela C. Breda
Kleber T. De Oliveira
Rodrigo V. Almeida
Frank Hollmann
Rodrigo O. M. A. De Souza
Impact of sunlight irradiation on CvFAP photodecarboxylation
Frontiers in Catalysis
photodecarboxylation
biocatalysis
green chemistry
sunlight
CvFAP
title Impact of sunlight irradiation on CvFAP photodecarboxylation
title_full Impact of sunlight irradiation on CvFAP photodecarboxylation
title_fullStr Impact of sunlight irradiation on CvFAP photodecarboxylation
title_full_unstemmed Impact of sunlight irradiation on CvFAP photodecarboxylation
title_short Impact of sunlight irradiation on CvFAP photodecarboxylation
title_sort impact of sunlight irradiation on cvfap photodecarboxylation
topic photodecarboxylation
biocatalysis
green chemistry
sunlight
CvFAP
url https://www.frontiersin.org/articles/10.3389/fctls.2023.1165079/full
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