1,4-Bis(pyrimidin-2-ylsulfanyl)butane
The –SCH2CH2CH2CH2S– portion of the title compound, C12H14N2S2, adopts an extended zigzag conformation. The angles at the tetrahedral carbon atoms are marginally increased [113.63 (12)° and 111.38 (17)° for S&#...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810041103 |
| _version_ | 1819349365224898560 |
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| author | Muhammad Akbar Fahim Ashraf Quereshi Waqar Nasir Ahmad Adnan Seik Weng Ng |
| author_facet | Muhammad Akbar Fahim Ashraf Quereshi Waqar Nasir Ahmad Adnan Seik Weng Ng |
| author_sort | Muhammad Akbar |
| collection | DOAJ |
| description | The –SCH2CH2CH2CH2S– portion of the title compound, C12H14N2S2, adopts an extended zigzag conformation. The angles at the tetrahedral carbon atoms are marginally increased [113.63 (12)° and 111.38 (17)° for S—C—C and C—C—C respectively] from the idealized tetrahedral angle. The molecule lies on an inversion center located at the mid-point of the butyl chain. In the crystal, there is a π–π stacking interaction between inversion-related pyrimidine rings with mean interplanar spacing of 3.494 (2) Å. |
| first_indexed | 2024-12-24T18:59:22Z |
| format | Article |
| id | doaj.art-4cc564c8353b4903a120858da9c6f7ee |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T18:59:22Z |
| publishDate | 2010-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4cc564c8353b4903a120858da9c6f7ee2022-12-21T16:43:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611o2849o284910.1107/S16005368100411031,4-Bis(pyrimidin-2-ylsulfanyl)butaneMuhammad AkbarFahim Ashraf QuereshiWaqar NasirAhmad AdnanSeik Weng NgThe –SCH2CH2CH2CH2S– portion of the title compound, C12H14N2S2, adopts an extended zigzag conformation. The angles at the tetrahedral carbon atoms are marginally increased [113.63 (12)° and 111.38 (17)° for S—C—C and C—C—C respectively] from the idealized tetrahedral angle. The molecule lies on an inversion center located at the mid-point of the butyl chain. In the crystal, there is a π–π stacking interaction between inversion-related pyrimidine rings with mean interplanar spacing of 3.494 (2) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536810041103 |
| spellingShingle | Muhammad Akbar Fahim Ashraf Quereshi Waqar Nasir Ahmad Adnan Seik Weng Ng 1,4-Bis(pyrimidin-2-ylsulfanyl)butane Acta Crystallographica Section E |
| title | 1,4-Bis(pyrimidin-2-ylsulfanyl)butane |
| title_full | 1,4-Bis(pyrimidin-2-ylsulfanyl)butane |
| title_fullStr | 1,4-Bis(pyrimidin-2-ylsulfanyl)butane |
| title_full_unstemmed | 1,4-Bis(pyrimidin-2-ylsulfanyl)butane |
| title_short | 1,4-Bis(pyrimidin-2-ylsulfanyl)butane |
| title_sort | 1 4 bis pyrimidin 2 ylsulfanyl butane |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810041103 |
| work_keys_str_mv | AT muhammadakbar 14bispyrimidin2ylsulfanylbutane AT fahimashrafquereshi 14bispyrimidin2ylsulfanylbutane AT waqarnasir 14bispyrimidin2ylsulfanylbutane AT ahmadadnan 14bispyrimidin2ylsulfanylbutane AT seikwengng 14bispyrimidin2ylsulfanylbutane |