Alginate Ag for Composite Hollow Fiber Membrane: Formation and Ethylene/Ethane Gas Mixture Separation

Membranes based on natural polymers, in particular alginate, are of great interest for various separation tasks. In particular, the possibility of introducing silver ions during the crosslinking of sodium alginate makes it possible to obtain a membrane with an active olefin transporter. In this work...

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Main Authors: Evgenia Dmitrieva, Evgenia Grushevenko, Daria Razlataya, George Golubev, Tatiana Rokhmanka, Tatyana Anokhina, Stepan Bazhenov
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/12/11/1090
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author Evgenia Dmitrieva
Evgenia Grushevenko
Daria Razlataya
George Golubev
Tatiana Rokhmanka
Tatyana Anokhina
Stepan Bazhenov
author_facet Evgenia Dmitrieva
Evgenia Grushevenko
Daria Razlataya
George Golubev
Tatiana Rokhmanka
Tatyana Anokhina
Stepan Bazhenov
author_sort Evgenia Dmitrieva
collection DOAJ
description Membranes based on natural polymers, in particular alginate, are of great interest for various separation tasks. In particular, the possibility of introducing silver ions during the crosslinking of sodium alginate makes it possible to obtain a membrane with an active olefin transporter. In this work, the creation of a hollow fiber composite membrane with a selective layer of silver alginate is proposed for the first time. The approach to obtaining silver alginate is presented in detail, and its sorption and transport properties are also studied. It is worth noting the increased selectivity of the material for the ethylene/ethane mixture (more than 100). A technique for obtaining a hollow fiber membrane from silver alginate has been developed, and its separating characteristics have been determined. It is shown that in thin layers, silver alginate retains high values of selectivity for the ethylene/ethane gas pair. The obtained gas transport properties demonstrate the high potential of using membranes based on silver alginate for the separation of an olefin/paraffin mixture.
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spelling doaj.art-4cf0fba408c84bfab6a776bab93915612023-11-24T05:48:56ZengMDPI AGMembranes2077-03752022-11-011211109010.3390/membranes12111090Alginate Ag for Composite Hollow Fiber Membrane: Formation and Ethylene/Ethane Gas Mixture SeparationEvgenia Dmitrieva0Evgenia Grushevenko1Daria Razlataya2George Golubev3Tatiana Rokhmanka4Tatyana Anokhina5Stepan Bazhenov6A.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninsky Pr. 29, 119991 Moscow, RussiaA.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninsky Pr. 29, 119991 Moscow, RussiaA.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninsky Pr. 29, 119991 Moscow, RussiaA.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninsky Pr. 29, 119991 Moscow, RussiaA.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninsky Pr. 29, 119991 Moscow, RussiaA.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninsky Pr. 29, 119991 Moscow, RussiaA.V. Topchiev Institute of Petrochemical Synthesis RAS, Leninsky Pr. 29, 119991 Moscow, RussiaMembranes based on natural polymers, in particular alginate, are of great interest for various separation tasks. In particular, the possibility of introducing silver ions during the crosslinking of sodium alginate makes it possible to obtain a membrane with an active olefin transporter. In this work, the creation of a hollow fiber composite membrane with a selective layer of silver alginate is proposed for the first time. The approach to obtaining silver alginate is presented in detail, and its sorption and transport properties are also studied. It is worth noting the increased selectivity of the material for the ethylene/ethane mixture (more than 100). A technique for obtaining a hollow fiber membrane from silver alginate has been developed, and its separating characteristics have been determined. It is shown that in thin layers, silver alginate retains high values of selectivity for the ethylene/ethane gas pair. The obtained gas transport properties demonstrate the high potential of using membranes based on silver alginate for the separation of an olefin/paraffin mixture.https://www.mdpi.com/2077-0375/12/11/1090silver alginatecomposite membranegas separation propertiesethylene–ethane separation
spellingShingle Evgenia Dmitrieva
Evgenia Grushevenko
Daria Razlataya
George Golubev
Tatiana Rokhmanka
Tatyana Anokhina
Stepan Bazhenov
Alginate Ag for Composite Hollow Fiber Membrane: Formation and Ethylene/Ethane Gas Mixture Separation
Membranes
silver alginate
composite membrane
gas separation properties
ethylene–ethane separation
title Alginate Ag for Composite Hollow Fiber Membrane: Formation and Ethylene/Ethane Gas Mixture Separation
title_full Alginate Ag for Composite Hollow Fiber Membrane: Formation and Ethylene/Ethane Gas Mixture Separation
title_fullStr Alginate Ag for Composite Hollow Fiber Membrane: Formation and Ethylene/Ethane Gas Mixture Separation
title_full_unstemmed Alginate Ag for Composite Hollow Fiber Membrane: Formation and Ethylene/Ethane Gas Mixture Separation
title_short Alginate Ag for Composite Hollow Fiber Membrane: Formation and Ethylene/Ethane Gas Mixture Separation
title_sort alginate ag for composite hollow fiber membrane formation and ethylene ethane gas mixture separation
topic silver alginate
composite membrane
gas separation properties
ethylene–ethane separation
url https://www.mdpi.com/2077-0375/12/11/1090
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AT dariarazlataya alginateagforcompositehollowfibermembraneformationandethyleneethanegasmixtureseparation
AT georgegolubev alginateagforcompositehollowfibermembraneformationandethyleneethanegasmixtureseparation
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