Crystal structure of N-(3-benzoyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)benzamide
In the title compound, C22H19NO2S, the cyclohexene ring adopts a half-chair conformation. The dihedral angles between the plane of the thiophene ring and those of its amide- and carbonyl-bonded benzene rings are 7.1 (1) and 59.0 (2)°, respectively. An intramolecular N—H...O hydrogen bond generates a...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-09-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814016948 |
| _version_ | 1818971543607181312 |
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| author | Manpreet Kaur Jerry P. Jasinski H. S. Yathirajan Thammarse S. Yamuna K. Byrappa |
| author_facet | Manpreet Kaur Jerry P. Jasinski H. S. Yathirajan Thammarse S. Yamuna K. Byrappa |
| author_sort | Manpreet Kaur |
| collection | DOAJ |
| description | In the title compound, C22H19NO2S, the cyclohexene ring adopts a half-chair conformation. The dihedral angles between the plane of the thiophene ring and those of its amide- and carbonyl-bonded benzene rings are 7.1 (1) and 59.0 (2)°, respectively. An intramolecular N—H...O hydrogen bond generates an S(6) ring. In the crystal, very weak aromatic π–π stacking interactions [centroid–centroid separation = 3.9009 (10) Å] are observed. |
| first_indexed | 2024-12-20T14:54:03Z |
| format | Article |
| id | doaj.art-4cf7ca2924bb4719ade39cea5f905b37 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T14:54:03Z |
| publishDate | 2014-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4cf7ca2924bb4719ade39cea5f905b372022-12-21T19:36:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-09-01709o951o95210.1107/S1600536814016948hb7258Crystal structure of N-(3-benzoyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)benzamideManpreet Kaur0Jerry P. Jasinski1H. S. Yathirajan2Thammarse S. Yamuna3K. Byrappa4Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, IndiaDepartment of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USADepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, IndiaDepartment of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, IndiaMaterials Science Center, University of Mysore, Vijyana Bhavan Building, Manasagangothri, Mysore-570 006, IndiaIn the title compound, C22H19NO2S, the cyclohexene ring adopts a half-chair conformation. The dihedral angles between the plane of the thiophene ring and those of its amide- and carbonyl-bonded benzene rings are 7.1 (1) and 59.0 (2)°, respectively. An intramolecular N—H...O hydrogen bond generates an S(6) ring. In the crystal, very weak aromatic π–π stacking interactions [centroid–centroid separation = 3.9009 (10) Å] are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536814016948crystal structurehydrogen bondingπ–π stacking interactionsbenzamide1-benzothiophene2-aminothiophene derivatives |
| spellingShingle | Manpreet Kaur Jerry P. Jasinski H. S. Yathirajan Thammarse S. Yamuna K. Byrappa Crystal structure of N-(3-benzoyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)benzamide Acta Crystallographica Section E crystal structure hydrogen bonding π–π stacking interactions benzamide 1-benzothiophene 2-aminothiophene derivatives |
| title | Crystal structure of N-(3-benzoyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)benzamide |
| title_full | Crystal structure of N-(3-benzoyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)benzamide |
| title_fullStr | Crystal structure of N-(3-benzoyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)benzamide |
| title_full_unstemmed | Crystal structure of N-(3-benzoyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)benzamide |
| title_short | Crystal structure of N-(3-benzoyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)benzamide |
| title_sort | crystal structure of n 3 benzoyl 4 5 6 7 tetrahydro 1 benzothiophen 2 yl benzamide |
| topic | crystal structure hydrogen bonding π–π stacking interactions benzamide 1-benzothiophene 2-aminothiophene derivatives |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814016948 |
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