Treatment of Oily Wastewater by the Optimization of Fe2O3 Calcination Temperatures in Innovative Bio-Electron-Fenton Microbial Fuel Cells

Due to the fact that Iron oxide (Fe2O3) is known to have a good effect on the photochemical reaction of catalysts, an investigation in this study into the enhancement of the degradation performance of bio-electro-Fenton microbial fuel cells (Bio-E-Fenton MFCs) was carried out using three photocataly...

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Main Authors: Jung-Chen Wu, Wei-Mon Yan, Chin-Tsan Wang, Chen-Hao Wang, Yi-Hao Pai, Kai-Chin Wang, Yan-Ming Chen, Tzu-Hsuan Lan, Sangeetha Thangavel
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/11/3/565
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author Jung-Chen Wu
Wei-Mon Yan
Chin-Tsan Wang
Chen-Hao Wang
Yi-Hao Pai
Kai-Chin Wang
Yan-Ming Chen
Tzu-Hsuan Lan
Sangeetha Thangavel
author_facet Jung-Chen Wu
Wei-Mon Yan
Chin-Tsan Wang
Chen-Hao Wang
Yi-Hao Pai
Kai-Chin Wang
Yan-Ming Chen
Tzu-Hsuan Lan
Sangeetha Thangavel
author_sort Jung-Chen Wu
collection DOAJ
description Due to the fact that Iron oxide (Fe2O3) is known to have a good effect on the photochemical reaction of catalysts, an investigation in this study into the enhancement of the degradation performance of bio-electro-Fenton microbial fuel cells (Bio-E-Fenton MFCs) was carried out using three photocatalytic cathodes. These cathodes were produced at different calcination temperatures of Fe2O3 ranging from 500 °C to 900 °C for realizing their performance as photo catalysts within the cathodic chamber of an MFC, and they were compared for their ability to degrade oily wastewater. Results show that a suitable temperature for the calcination of iron oxide would have a significantly positive effect on the performance of Bio-E-Fenton MFCs. An optimal calcination temperature of 500 °C for Fe2O3 in the electrode material of the cathode was observed to produce a maximum power density of 52.5 mW/m2 and a chemical oxygen demand (COD) degradation rate of oily wastewater (catholyte) of 99.3% within one hour of operation. These novel findings will be useful for the improvement of the performance and applications of Bio-E-Fenton MFCs and their future applications in the field of wastewater treatment.
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spelling doaj.art-4cfb9511fcac4e87846e2238f10f39ee2022-12-22T02:18:54ZengMDPI AGEnergies1996-10732018-03-0111356510.3390/en11030565en11030565Treatment of Oily Wastewater by the Optimization of Fe2O3 Calcination Temperatures in Innovative Bio-Electron-Fenton Microbial Fuel CellsJung-Chen Wu0Wei-Mon Yan1Chin-Tsan Wang2Chen-Hao Wang3Yi-Hao Pai4Kai-Chin Wang5Yan-Ming Chen6Tzu-Hsuan Lan7Sangeetha Thangavel8Department of Materials Science and Engineering, National Taiwan University of Science and Technology, No. 43, Keelung Rd., Sec. 4, Da’an Dist., Taipei 10607, TaiwanDepartment of Energy and Refrigerating Air-Conditioning Engineering, National Taipei University of Technology, 1, Sec. 3, Zhongxiao E. Rd., Taipei 10608, TaiwanDepartment of Mechanical and Electro-Mechanical Engineering, National Ilan University, No. 1, Sec. 1, Shennong Rd., Yilan 26047, TaiwanDepartment of Materials Science and Engineering, National Taiwan University of Science and Technology, No. 43, Keelung Rd., Sec. 4, Da’an Dist., Taipei 10607, TaiwanDepartment of Opto-Electronic Engineering, National Dong Hwa University, No. 1, Sec. 2, Da Hsueh Rd., Shoufeng, Hualien 97401, TaiwanDepartment of Materials Science and Engineering, National Taiwan University of Science and Technology, No. 43, Keelung Rd., Sec. 4, Da’an Dist., Taipei 10607, TaiwanDepartment of Materials and Mineral Resources Engineering & Institute of Materials Science and Engineering National Taipei University of Technology, No. 1, Sec. 3, Zhong-Xiao E. Rd., Taipei 10608, TaiwanDepartment of Materials and Mineral Resources Engineering & Institute of Materials Science and Engineering National Taipei University of Technology, No. 1, Sec. 3, Zhong-Xiao E. Rd., Taipei 10608, TaiwanDepartment of Energy and Refrigerating Air-Conditioning Engineering, National Taipei University of Technology, 1, Sec. 3, Zhongxiao E. Rd., Taipei 10608, TaiwanDue to the fact that Iron oxide (Fe2O3) is known to have a good effect on the photochemical reaction of catalysts, an investigation in this study into the enhancement of the degradation performance of bio-electro-Fenton microbial fuel cells (Bio-E-Fenton MFCs) was carried out using three photocatalytic cathodes. These cathodes were produced at different calcination temperatures of Fe2O3 ranging from 500 °C to 900 °C for realizing their performance as photo catalysts within the cathodic chamber of an MFC, and they were compared for their ability to degrade oily wastewater. Results show that a suitable temperature for the calcination of iron oxide would have a significantly positive effect on the performance of Bio-E-Fenton MFCs. An optimal calcination temperature of 500 °C for Fe2O3 in the electrode material of the cathode was observed to produce a maximum power density of 52.5 mW/m2 and a chemical oxygen demand (COD) degradation rate of oily wastewater (catholyte) of 99.3% within one hour of operation. These novel findings will be useful for the improvement of the performance and applications of Bio-E-Fenton MFCs and their future applications in the field of wastewater treatment.http://www.mdpi.com/1996-1073/11/3/565bio-electro-Fenton microbial fuel cells (Bio-E-Fenton MFCs)wastewaterphoto catalystdegradationcalcinationchemical oxygen demand (COD)
spellingShingle Jung-Chen Wu
Wei-Mon Yan
Chin-Tsan Wang
Chen-Hao Wang
Yi-Hao Pai
Kai-Chin Wang
Yan-Ming Chen
Tzu-Hsuan Lan
Sangeetha Thangavel
Treatment of Oily Wastewater by the Optimization of Fe2O3 Calcination Temperatures in Innovative Bio-Electron-Fenton Microbial Fuel Cells
Energies
bio-electro-Fenton microbial fuel cells (Bio-E-Fenton MFCs)
wastewater
photo catalyst
degradation
calcination
chemical oxygen demand (COD)
title Treatment of Oily Wastewater by the Optimization of Fe2O3 Calcination Temperatures in Innovative Bio-Electron-Fenton Microbial Fuel Cells
title_full Treatment of Oily Wastewater by the Optimization of Fe2O3 Calcination Temperatures in Innovative Bio-Electron-Fenton Microbial Fuel Cells
title_fullStr Treatment of Oily Wastewater by the Optimization of Fe2O3 Calcination Temperatures in Innovative Bio-Electron-Fenton Microbial Fuel Cells
title_full_unstemmed Treatment of Oily Wastewater by the Optimization of Fe2O3 Calcination Temperatures in Innovative Bio-Electron-Fenton Microbial Fuel Cells
title_short Treatment of Oily Wastewater by the Optimization of Fe2O3 Calcination Temperatures in Innovative Bio-Electron-Fenton Microbial Fuel Cells
title_sort treatment of oily wastewater by the optimization of fe2o3 calcination temperatures in innovative bio electron fenton microbial fuel cells
topic bio-electro-Fenton microbial fuel cells (Bio-E-Fenton MFCs)
wastewater
photo catalyst
degradation
calcination
chemical oxygen demand (COD)
url http://www.mdpi.com/1996-1073/11/3/565
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