Kinetics and Thermodynamics of Mg-Al Disorder in MgAl<sub>2</sub>O<sub>4</sub>-Spinel: A Review

Kinetics and Thermodynamics of Mg-Al Disorder in MgAl<sub>2</sub>O<sub>4</sub>-Spinel: A Review

The MgAl<sub>2</sub>O<sub>4</sub>-spinel has wide applications in various industries and in geosciences. It shows a significant inter-site Mg-Al cation exchange (denoted by the inversion parameter <i>x</i>), which modifies structural features, such as the unit-cel...

Full description

Bibliographic Details
Main Authors:	Yunlu Ma, Xi Liu
Format:	Article
Language:	English
Published:	MDPI AG 2019-05-01
Series:	Molecules
Subjects:	MgAl<sub>2</sub>O<sub>4</sub>-spinel cation exchange reaction kinetics temperature thermodynamic model non-configurational entropy
Online Access:	https://www.mdpi.com/1420-3049/24/9/1704

Similar Items

Thermodynamics of Mg–Al Order-Disorder Reaction in MgAl<sub>2</sub>O<sub>4</sub>-Spinel: Constrained by Prolonged Annealing Experiments at 773–1123 K
by: Yunlu Ma, et al.
Published: (2021-02-01)

Structural and Luminescent Peculiarities of Spark Plasma Sintered Transparent MgAl<sub>2</sub>O<sub>4</sub> Spinel Ceramics Doped with Cerium Ions
by: Damir Valiev, et al.
Published: (2022-09-01)

Enhancing Laser Damage Resistance of Co<sup>2+</sup>:MgAl<sub>2</sub>O<sub>4</sub> Crystal by Plasma Etching
by: Giedrius Abromavičius, et al.
Published: (2023-01-01)

Combustion Synthesis of NbB<sub>2</sub>–Spinel MgAl<sub>2</sub>O<sub>4</sub> Composites from MgO-Added Thermite-Based Reactants with Excess Boron
by: Chun-Liang Yeh, et al.
Published: (2020-03-01)

Improving the Transparency of a MgAl<sub>2</sub>O<sub>4</sub> Spinel Damaged by Sandblasting through a SiO<sub>2</sub>-ZrO<sub>2</sub> Coating
by: Akram Zegadi, et al.
Published: (2024-05-01)

Wasteless Synthesis and Properties of Highly Dispersed MgAl<sub>2</sub>O<sub>4</sub> Based on Product of Thermal Activation of Gibbsite
by: Aleksey V. Zhuzhgov, et al.
Published: (2022-04-01)

Directionally Solidified Cobalt-Doped MgO-MgAl<sub>2</sub>O<sub>4</sub> Eutectic Composites for Selective Emitters
by: Rosa I. Merino, et al.
Published: (2022-10-01)

Tensile Adhesion Strength of Atmospheric Plasma Sprayed MgAl<sub>2</sub>O<sub>4</sub>, Al<sub>2</sub>O<sub>3</sub> Coatings
by: Andrey Zayatzev, et al.
Published: (2022-12-01)

MgAl-NO<sub>3</sub> LDH: Adsorption Isotherms and Multivariate Optimization for Cr(VI) Removal
by: Anna Maria Cardinale, et al.
Published: (2023-03-01)

Yield Strength of Transparent MgAl<sub>2</sub>O<sub>4</sub> Nano-Ceramic at High Pressure and Temperature
by: Zhang Jie, et al.
Published: (2010-01-01)

Performance Analysis of TiO<sub>2</sub>-Modified Co/MgAl<sub>2</sub>O<sub>4</sub> Catalyst for Dry Reforming of Methane in a Fixed Bed Reactor for Syngas (H<sub>2</sub>, CO) Production
by: Arslan Mazhar, et al.
Published: (2021-06-01)

MgAl Oxide Coatings Modified with CeO<sub>2</sub> Particles Formed by Plasma Electrolytic Oxidation of AZ31 Magnesium Alloy: Photoluminescent and Photocatalytic Properties
by: Stevan Stojadinović, et al.
Published: (2024-03-01)

Síntese do espinélio MgAl2O4 via "sol-gel" Synthesis of MgAl2O4 spinel via "sol-gel"
by: A. L. Heck, et al.
Published: (2005-06-01)

Characterization of Synthetic Non-Metallic Inclusions Consisting of TiN, Ti<sub>2</sub>O<sub>3</sub>, and Oxides of Al<sub>2</sub>O<sub>3</sub> and MgO·Al<sub>2</sub>O<sub>3</sub> Spinel Using Raman Spectroscopy
by: Francis Gyakwaa, et al.
Published: (2021-09-01)

Synthesis, Electronic Structure, and Electrochemical Properties of the Cubic Mg<sub>2</sub>MnO<sub>4</sub> Spinel with Porous-Spongy Structure
by: Zhenyan Wang, et al.
Published: (2021-04-01)

Cu<sup>2+</sup>-Ion-Substitution-Driven Microstructure and Microwave Dielectric Properties of Mg<sub>1−<i>x</i></sub>Cu<i><sub>x</sub></i>Al<sub>2</sub>O<sub>4</sub> Ceramics
by: Yuanming Lai, et al.
Published: (2022-09-01)

Kinetic and Thermodynamic Studies on Synthesis of Mg-Doped LiMn<sub>2</sub>O<sub>4</sub> Nanoparticles
by: Aleksei Llusco, et al.
Published: (2020-07-01)

Phase-Pure Epitaxial b-Axis-Oriented Bronze TiO<sub>2</sub> Films
by: Andreas Herklotz, et al.
Published: (2022-12-01)

Molecular Dynamics-Based Cohesive Zone Model for Mg/Mg<sub>17</sub>Al<sub>12</sub> Interface
by: Xiao Ru Zhuo, et al.
Published: (2020-06-01)

First-Principles Investigations on Structural Stability, Elastic Properties and Electronic Structure of Mg<sub>32</sub>(Al,Zn)<sub>49</sub> Phase and MgZn<sub>2</sub> Phase
by: Yu Song, et al.
Published: (2022-05-01)

Pressure-Induced YbFe<sub>2</sub>O<sub>4</sub>-Type to Spinel Structural Change of InGaMgO<sub>4</sub>
by: Takehiro Koike, et al.
Published: (2024-08-01)

Proper MgO/Al<sub>2</sub>O<sub>3</sub> Ratio in Blast-Furnace Slag: Analysis of Proper MgO/Al<sub>2</sub>O<sub>3</sub> Ratio Based on Observed Data
by: Fengman Shen, et al.
Published: (2020-06-01)

Design and Performance of a New Zn<sub>0.5</sub>Mg<sub>0.5</sub>FeMnO<sub>4</sub> Porous Spinel as Anode Material for Li-Ion Batteries
by: Zakaria Chchiyai, et al.
Published: (2023-10-01)

Mg<sub>6</sub>MnO<sub>8</sub> as a Magnesium-Ion Battery Material: Defects, Dopants and Mg-Ion Transport
by: Navaratnarajah Kuganathan, et al.
Published: (2019-08-01)

Preparation of Hydrated TiO<sub>2</sub> Particles by Hydrothermal Hydrolysis of Mg/Al-Bearing TiOSO<sub>4</sub> Solution
by: Shuyu Lin, et al.
Published: (2023-03-01)

The study on the interface reaction characteristics of different binary slag, CaO – MgO, Al<sub>2</sub>O<sub>3</sub> – CaO, Al<sub>2</sub>O<sub>3</sub> – MgO, SiO<sub>2</sub> – CaO, SiO<sub>2</sub> - MgO
by: R. R. Yin, et al.
Published: (2019-01-01)

Influences of Multilayer Graphene and Boron Decoration on the Structure and Combustion Heat of Al<sub>3</sub>Mg<sub>2</sub> Alloy
by: Jun Dong, et al.
Published: (2020-10-01)

Corrosion Resistance of Mg(OH)<sub>2</sub>/Mn(OH)<sub>2</sub> Hydroxide Film on ZK60 Mg Alloy
by: Yongmin Wang, et al.
Published: (2022-10-01)

Thermodynamic Properties of MgAl<sub>2</sub>O<sub>4</sub> Spinel at High Temperatures and High Pressures
by: Wuxueying Qiu, et al.
Published: (2023-01-01)

Spinel Magnesium Ferrite (MgFe<sub>2</sub>O<sub>4</sub>): A Glycine-Assisted Colloidal Combustion and Its Potentiality in Gas-Sensing Application
by: Digambar Nadargi, et al.
Published: (2022-09-01)

A Mini-Review on CO<sub>2</sub> Photoreduction by MgAl-LDH Based Materials
by: Changqing Wang, et al.
Published: (2022-10-01)

Fe<sub>2</sub>O<sub>3</sub>/MgFe<sub>2</sub>O<sub>4</sub> Nanosheet on Nickel Foam for High-Performance Asymmetric Supercapacitors
by: Jiao Li, et al.
Published: (2023-11-01)

First-Principle Investigation into Mechanical Properties of Al<sub>6</sub>Mg<sub>1</sub>Zr<sub>1</sub> under Uniaxial Tension Strain on the Basis of Density Functional Theory
by: Lihua Zhang, et al.
Published: (2023-09-01)

Phase Transitions in the “Spinel-Layered” Li<sub>1+x</sub>Ni<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4</sub> (x = 0, 0.5, 1) Cathodes upon (De)lithiation Studied with Operando Synchrotron X-ray Powder Diffraction
by: Oleg A. Drozhzhin, et al.
Published: (2021-05-01)

Effect of Substitutional Elements on the Thermodynamic and Electrochemical Properties of Mechanically Alloyed La<sub>1.5</sub>Mg<sub>0.5</sub>Ni<sub>7−<i>x</i></sub>M<i><sub>x</sub></i> alloys (M = Al, Mn)
by: Marek Nowak, et al.
Published: (2020-04-01)

Effects of Coloration of Spinel CoAl<sub>2</sub>O<sub>4</sub> Cobalt Blue Pigments: Composition, Structure, and Cation Distribution
by: Weiran Zhang, et al.
Published: (2023-09-01)

Microstructures and Dehydrogenation Properties of Ball-milled MgH<sub>2</sub>-K<sub>2</sub>Ti<sub>6</sub>O<sub>13</sub>-Ni Composite Systems
by: ZHANG Jian, et al.
Published: (2016-11-01)

Improved Discharge Performance of AZ72-0.05La Alloy Anode via Refining Mg<sub>17</sub>Al<sub>12</sub> Phase
by: Junqing Guo, et al.
Published: (2024-03-01)

Reinforcement of the Ceramic Matrix of CaO-ZrO<sub>2</sub>-MgO with Al<sub>2</sub>O<sub>3</sub> Coarse Particles
by: João Mamede, et al.
Published: (2022-03-01)

Investigation of Structural and Luminescent Properties of Sol-Gel-Derived Cr‑Substituted Mg<sub>3</sub>Al<sub>1−x</sub>Cr<sub>x</sub> Layered Double Hydroxides
by: Ligita Valeikiene, et al.
Published: (2021-03-01)