Radical Mediated Decarboxylation of Amino Acids via Photochemical Carbonyl Sulfide (COS) Elimination

Radical Mediated Decarboxylation of Amino Acids via Photochemical Carbonyl Sulfide (COS) Elimination

Herein, we present the first examples of amino acid decarboxylation via photochemically activated carbonyl sulfide (COS) elimination of the corresponding thioacids. This method offers a mild approach for the decarboxylation of amino acids, furnishing <i>N</i>-alkyl amino derivatives. The...

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Bibliographic Details
Main Authors: Alby Benny, Lorenzo Di Simo, Lorenzo Guazzelli, Eoin M. Scanlan
Format: Article
Language:English
Published: MDPI AG 2024-03-01
Series:Molecules
Subjects:
thioacid
decarboxylation
amino acid
radical
photochemistry
blue LED
Online Access:https://www.mdpi.com/1420-3049/29/7/1465

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