A Review on the Modeling of the Elastic Modulus and Yield Stress of Polymers and Polymer Nanocomposites: Effect of Temperature, Loading Rate and Porosity

Porous polymer-based nanocomposites have been used for various applications due to their advantages, including multi-functionalities, easy and known manufacturability, and low cost. Understanding of their mechanical properties has become essential to expand the nanocomposites’ applications and effic...

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Main Authors: Reema H. Alasfar, Said Ahzi, Nicolas Barth, Viktor Kochkodan, Marwan Khraisheh, Muammer Koç
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/3/360
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author Reema H. Alasfar
Said Ahzi
Nicolas Barth
Viktor Kochkodan
Marwan Khraisheh
Muammer Koç
author_facet Reema H. Alasfar
Said Ahzi
Nicolas Barth
Viktor Kochkodan
Marwan Khraisheh
Muammer Koç
author_sort Reema H. Alasfar
collection DOAJ
description Porous polymer-based nanocomposites have been used for various applications due to their advantages, including multi-functionalities, easy and known manufacturability, and low cost. Understanding of their mechanical properties has become essential to expand the nanocomposites’ applications and efficiency, including service-life, resistance to different loads, and reliability. In this review paper, the focus is on the modeling of the mechanical properties of porous polymer-based nanocomposites, including the effects of loading rates, operational temperatures, and the material’s porosity. First, modeling of the elastic modulus and yield stress for glassy polymers and polymer reinforced by nanofillers are addressed. Then, modeling of porosity effects on these properties for polymers are reviewed, especially via the use of the well-known power-law approach linking porosity to elastic modulus and/or stress. Studies related to extending the mechanical modeling to account for porosity effects on the elastic modulus and yield stress of polymers and polymer-nanocomposites are discussed. Finally, a brief review of the implementation of this modeling into 3D computational methods to predict the large elastic-viscoplastic deformation response of glassy polymers is presented. In addition to the modeling part, the experimental techniques to measure the elastic modulus and the yield stress are discussed, and applications of polymers and polymer composites as membranes for water treatment and scaffolds for bone tissue engineering are addressed. Some modeling results and validation from different studies are presented as well.
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spelling doaj.art-4d32b1705a3040d3a75deb182c1856b32023-11-23T17:32:31ZengMDPI AGPolymers2073-43602022-01-0114336010.3390/polym14030360A Review on the Modeling of the Elastic Modulus and Yield Stress of Polymers and Polymer Nanocomposites: Effect of Temperature, Loading Rate and PorosityReema H. Alasfar0Said Ahzi1Nicolas Barth2Viktor Kochkodan3Marwan Khraisheh4Muammer Koç5Division of Sustainable Development, College of Science and Engineering, Hamad bin Khalifa University, Doha P.O. Box 34110, QatarMechanical Engineering Program, Texas A&M University at Qatar, Doha P.O. Box 34110, QatarQatar Environment and Energy Research Institute, Hamad bin Khalifa University, Doha P.O. Box 34110, QatarQatar Environment and Energy Research Institute, Hamad bin Khalifa University, Doha P.O. Box 34110, QatarMechanical Engineering Program, Texas A&M University at Qatar, Doha P.O. Box 34110, QatarDivision of Sustainable Development, College of Science and Engineering, Hamad bin Khalifa University, Doha P.O. Box 34110, QatarPorous polymer-based nanocomposites have been used for various applications due to their advantages, including multi-functionalities, easy and known manufacturability, and low cost. Understanding of their mechanical properties has become essential to expand the nanocomposites’ applications and efficiency, including service-life, resistance to different loads, and reliability. In this review paper, the focus is on the modeling of the mechanical properties of porous polymer-based nanocomposites, including the effects of loading rates, operational temperatures, and the material’s porosity. First, modeling of the elastic modulus and yield stress for glassy polymers and polymer reinforced by nanofillers are addressed. Then, modeling of porosity effects on these properties for polymers are reviewed, especially via the use of the well-known power-law approach linking porosity to elastic modulus and/or stress. Studies related to extending the mechanical modeling to account for porosity effects on the elastic modulus and yield stress of polymers and polymer-nanocomposites are discussed. Finally, a brief review of the implementation of this modeling into 3D computational methods to predict the large elastic-viscoplastic deformation response of glassy polymers is presented. In addition to the modeling part, the experimental techniques to measure the elastic modulus and the yield stress are discussed, and applications of polymers and polymer composites as membranes for water treatment and scaffolds for bone tissue engineering are addressed. Some modeling results and validation from different studies are presented as well.https://www.mdpi.com/2073-4360/14/3/360modelingpolymerspolymer nanocompositeselastic modulusyield stressporosity effect
spellingShingle Reema H. Alasfar
Said Ahzi
Nicolas Barth
Viktor Kochkodan
Marwan Khraisheh
Muammer Koç
A Review on the Modeling of the Elastic Modulus and Yield Stress of Polymers and Polymer Nanocomposites: Effect of Temperature, Loading Rate and Porosity
Polymers
modeling
polymers
polymer nanocomposites
elastic modulus
yield stress
porosity effect
title A Review on the Modeling of the Elastic Modulus and Yield Stress of Polymers and Polymer Nanocomposites: Effect of Temperature, Loading Rate and Porosity
title_full A Review on the Modeling of the Elastic Modulus and Yield Stress of Polymers and Polymer Nanocomposites: Effect of Temperature, Loading Rate and Porosity
title_fullStr A Review on the Modeling of the Elastic Modulus and Yield Stress of Polymers and Polymer Nanocomposites: Effect of Temperature, Loading Rate and Porosity
title_full_unstemmed A Review on the Modeling of the Elastic Modulus and Yield Stress of Polymers and Polymer Nanocomposites: Effect of Temperature, Loading Rate and Porosity
title_short A Review on the Modeling of the Elastic Modulus and Yield Stress of Polymers and Polymer Nanocomposites: Effect of Temperature, Loading Rate and Porosity
title_sort review on the modeling of the elastic modulus and yield stress of polymers and polymer nanocomposites effect of temperature loading rate and porosity
topic modeling
polymers
polymer nanocomposites
elastic modulus
yield stress
porosity effect
url https://www.mdpi.com/2073-4360/14/3/360
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