9-(Pyrrolidinium-1-yl)-9-boranuidabicyclo[3.3.1]nonane
The title compound, C12H24BN, is an adduct formed from 9-borabicyclo[3.3.1]nonane (9-BBN) and pyrrolidine. It crystallizes in the triclinic space group P\overline{1} with three molecules in the asymmetric unit, one of which has disorder of the pyrrolidine ring. The B—N bond lengths are between 1.631...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2023-04-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314623003322 |
| _version_ | 1797832830412128256 |
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| author | Marcus Herbig Uwe Böhme |
| author_facet | Marcus Herbig Uwe Böhme |
| author_sort | Marcus Herbig |
| collection | DOAJ |
| description | The title compound, C12H24BN, is an adduct formed from 9-borabicyclo[3.3.1]nonane (9-BBN) and pyrrolidine. It crystallizes in the triclinic space group P\overline{1} with three molecules in the asymmetric unit, one of which has disorder of the pyrrolidine ring. The B—N bond lengths are between 1.631 (2) and 1.641 (2) Å. The boron and nitrogen atoms are bound to one hydrogen atom each. These hydrogen atoms are in antiperiplanar orientation. Both six-membered rings of the 9-BBN unit are in a chair conformation in all three molecules. Differences between the three crystallographic independent molecules are found in the five-membered rings of the pyrrolidine unit. These adopt different twisted and envelope conformations. |
| first_indexed | 2024-04-09T14:15:06Z |
| format | Article |
| id | doaj.art-4d497d3fee50482d84e632b89584e70a |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-04-09T14:15:06Z |
| publishDate | 2023-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-4d497d3fee50482d84e632b89584e70a2023-05-05T14:05:03ZengInternational Union of CrystallographyIUCrData2414-31462023-04-0184x23033210.1107/S2414314623003322im40189-(Pyrrolidinium-1-yl)-9-boranuidabicyclo[3.3.1]nonaneMarcus Herbig0Uwe Böhme1Institut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, GermanyInstitut für Anorganische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, 09599 Freiberg, GermanyThe title compound, C12H24BN, is an adduct formed from 9-borabicyclo[3.3.1]nonane (9-BBN) and pyrrolidine. It crystallizes in the triclinic space group P\overline{1} with three molecules in the asymmetric unit, one of which has disorder of the pyrrolidine ring. The B—N bond lengths are between 1.631 (2) and 1.641 (2) Å. The boron and nitrogen atoms are bound to one hydrogen atom each. These hydrogen atoms are in antiperiplanar orientation. Both six-membered rings of the 9-BBN unit are in a chair conformation in all three molecules. Differences between the three crystallographic independent molecules are found in the five-membered rings of the pyrrolidine unit. These adopt different twisted and envelope conformations.http://scripts.iucr.org/cgi-bin/paper?S2414314623003322crystal structure |
| spellingShingle | Marcus Herbig Uwe Böhme 9-(Pyrrolidinium-1-yl)-9-boranuidabicyclo[3.3.1]nonane IUCrData crystal structure |
| title | 9-(Pyrrolidinium-1-yl)-9-boranuidabicyclo[3.3.1]nonane |
| title_full | 9-(Pyrrolidinium-1-yl)-9-boranuidabicyclo[3.3.1]nonane |
| title_fullStr | 9-(Pyrrolidinium-1-yl)-9-boranuidabicyclo[3.3.1]nonane |
| title_full_unstemmed | 9-(Pyrrolidinium-1-yl)-9-boranuidabicyclo[3.3.1]nonane |
| title_short | 9-(Pyrrolidinium-1-yl)-9-boranuidabicyclo[3.3.1]nonane |
| title_sort | 9 pyrrolidinium 1 yl 9 boranuidabicyclo 3 3 1 nonane |
| topic | crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314623003322 |
| work_keys_str_mv | AT marcusherbig 9pyrrolidinium1yl9boranuidabicyclo331nonane AT uwebohme 9pyrrolidinium1yl9boranuidabicyclo331nonane |