‘Unzipping’ of twin lamella in nanotwinned nickel nanowires under flexural bending

We report the fabrication of nickel nanowires with parallel growth-twin structures (‘twin lamella’ along the wire axis) by electrochemical deposition, and demonstrate an interesting twin ‘unzipping’ phenomenon in such nanotwinned nanowires under bending. Through in situ TEM, we found that ‘unzipping...

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Bibliographic Details
Main Authors: Binjun Wang, Hongti Zhang, Jun Lou, Yang Lu
Format: Article
Language:English
Published: Taylor & Francis Group 2018-01-01
Series:Materials Research Letters
Subjects:
Online Access:http://dx.doi.org/10.1080/21663831.2017.1383317
Description
Summary:We report the fabrication of nickel nanowires with parallel growth-twin structures (‘twin lamella’ along the wire axis) by electrochemical deposition, and demonstrate an interesting twin ‘unzipping’ phenomenon in such nanotwinned nanowires under bending. Through in situ TEM, we found that ‘unzipping’ of twin lamella was achieved by gradually increasing twin spacing along the wire axis via a layer-by-layer twin boundary migration process. Molecular dynamics simulations suggest that partial dislocation slip is responsible for activating the ‘unzipping’, with a multi-step-process involving dislocation loop initiation, expansion and partially annihilation. Our work could provide new insights into the deformation mechanisms of nanotwinned 1-D metallic nanostructures.
ISSN:2166-3831