Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate
The tridentate ligand N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane (L) has been prepared in one step by condensation of two equivalents of 1-hydroxymethyl-3,5-dimethylpyrazole with one equivalent of 2-aminoethanol. This reaction is carried out under microwave irradiation (60 W) in...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2003-11-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/8/11/780/ |
| _version_ | 1819241270911959040 |
|---|---|
| author | Driss Eddike Sghir El Kadiri Abdelkrim Ramdani Rachid Touzani Fouad Malek Mohamed El Kodadi |
| author_facet | Driss Eddike Sghir El Kadiri Abdelkrim Ramdani Rachid Touzani Fouad Malek Mohamed El Kodadi |
| author_sort | Driss Eddike |
| collection | DOAJ |
| description | The tridentate ligand N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane (L) has been prepared in one step by condensation of two equivalents of 1-hydroxymethyl-3,5-dimethylpyrazole with one equivalent of 2-aminoethanol. This reaction is carried out under microwave irradiation (60 W) in the absence of solvent for 20 min [1]. Using this ligand L a new Cu(II) dinitrate complex has been prepared. The singlecrystal X-ray structure of the title compound, [N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane] (3,5-dimethylpyrazole)copper(II) dinitrate, revels that the copper (II) ion is coordinated to two pyrazole nitrogens, one tertiary amine nitrogen of the ligand L and 3,5-dimethylpyrazole, and in the apical position by an alcohol O atom. |
| first_indexed | 2024-12-23T14:21:15Z |
| format | Article |
| id | doaj.art-4d66c8c99dca4f40a2e19d8ca0851663 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-23T14:21:15Z |
| publishDate | 2003-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-4d66c8c99dca4f40a2e19d8ca08516632022-12-21T17:43:47ZengMDPI AGMolecules1420-30492003-11-0181178078710.3390/81100780Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrateDriss EddikeSghir El KadiriAbdelkrim RamdaniRachid TouzaniFouad MalekMohamed El KodadiThe tridentate ligand N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane (L) has been prepared in one step by condensation of two equivalents of 1-hydroxymethyl-3,5-dimethylpyrazole with one equivalent of 2-aminoethanol. This reaction is carried out under microwave irradiation (60 W) in the absence of solvent for 20 min [1]. Using this ligand L a new Cu(II) dinitrate complex has been prepared. The singlecrystal X-ray structure of the title compound, [N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane] (3,5-dimethylpyrazole)copper(II) dinitrate, revels that the copper (II) ion is coordinated to two pyrazole nitrogens, one tertiary amine nitrogen of the ligand L and 3,5-dimethylpyrazole, and in the apical position by an alcohol O atom.http://www.mdpi.com/1420-3049/8/11/780/Structurecopper complextripodpyrazoletridentate ligand |
| spellingShingle | Driss Eddike Sghir El Kadiri Abdelkrim Ramdani Rachid Touzani Fouad Malek Mohamed El Kodadi Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate Molecules Structure copper complex tripod pyrazole tridentate ligand |
| title | Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate |
| title_full | Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate |
| title_fullStr | Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate |
| title_full_unstemmed | Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate |
| title_short | Synthesis and X-Ray Structure of [N,N-Bis(3,5-dimethylpyrazol-1-ylmethyl)-1-hydroxy-2-aminoethane](3,5-dimethylpyrazole) copper(II) dinitrate |
| title_sort | synthesis and x ray structure of n n bis 3 5 dimethylpyrazol 1 ylmethyl 1 hydroxy 2 aminoethane 3 5 dimethylpyrazole copper ii dinitrate |
| topic | Structure copper complex tripod pyrazole tridentate ligand |
| url | http://www.mdpi.com/1420-3049/8/11/780/ |
| work_keys_str_mv | AT drisseddike synthesisandxraystructureofnnbis35dimethylpyrazol1ylmethyl1hydroxy2aminoethane35dimethylpyrazolecopperiidinitrate AT sghirelkadiri synthesisandxraystructureofnnbis35dimethylpyrazol1ylmethyl1hydroxy2aminoethane35dimethylpyrazolecopperiidinitrate AT abdelkrimramdani synthesisandxraystructureofnnbis35dimethylpyrazol1ylmethyl1hydroxy2aminoethane35dimethylpyrazolecopperiidinitrate AT rachidtouzani synthesisandxraystructureofnnbis35dimethylpyrazol1ylmethyl1hydroxy2aminoethane35dimethylpyrazolecopperiidinitrate AT fouadmalek synthesisandxraystructureofnnbis35dimethylpyrazol1ylmethyl1hydroxy2aminoethane35dimethylpyrazolecopperiidinitrate AT mohamedelkodadi synthesisandxraystructureofnnbis35dimethylpyrazol1ylmethyl1hydroxy2aminoethane35dimethylpyrazolecopperiidinitrate |