New chemistry of transition metal oxyhydrides

In this review we describe recent advances in transition metal oxyhydride chemistry obtained by topochemical routes, such as low temperature reduction with metal hydrides, or high-pressure solid-state reactions. Besides the crystal chemistry, magnetic and transport properties of the bulk powder and...

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Main Authors: Yoji Kobayashi, Olivier Hernandez, Cédric Tassel, Hiroshi Kageyama
Format: Article
Language:English
Published: Taylor & Francis Group 2017-12-01
Series:Science and Technology of Advanced Materials
Subjects:
Online Access:http://dx.doi.org/10.1080/14686996.2017.1394776
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author Yoji Kobayashi
Olivier Hernandez
Cédric Tassel
Hiroshi Kageyama
author_facet Yoji Kobayashi
Olivier Hernandez
Cédric Tassel
Hiroshi Kageyama
author_sort Yoji Kobayashi
collection DOAJ
description In this review we describe recent advances in transition metal oxyhydride chemistry obtained by topochemical routes, such as low temperature reduction with metal hydrides, or high-pressure solid-state reactions. Besides the crystal chemistry, magnetic and transport properties of the bulk powder and epitaxial thin film samples, the remarkable lability of the hydride anion is particularly highlighted as a new strategy to discover unprecedented mixed anion materials.
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spelling doaj.art-4d746ec2564a419186181ec2dc96e0292022-12-21T19:03:31ZengTaylor & Francis GroupScience and Technology of Advanced Materials1468-69961878-55142017-12-0118190591810.1080/14686996.2017.13947761394776New chemistry of transition metal oxyhydridesYoji Kobayashi0Olivier Hernandez1Cédric Tassel2Hiroshi Kageyama3Kyoto UniversityUMR 6226 CNRS-University of Rennes 1Kyoto UniversityKyoto UniversityIn this review we describe recent advances in transition metal oxyhydride chemistry obtained by topochemical routes, such as low temperature reduction with metal hydrides, or high-pressure solid-state reactions. Besides the crystal chemistry, magnetic and transport properties of the bulk powder and epitaxial thin film samples, the remarkable lability of the hydride anion is particularly highlighted as a new strategy to discover unprecedented mixed anion materials.http://dx.doi.org/10.1080/14686996.2017.1394776Oxyhydridehydridemixed anionssolid-state chemistry
spellingShingle Yoji Kobayashi
Olivier Hernandez
Cédric Tassel
Hiroshi Kageyama
New chemistry of transition metal oxyhydrides
Science and Technology of Advanced Materials
Oxyhydride
hydride
mixed anions
solid-state chemistry
title New chemistry of transition metal oxyhydrides
title_full New chemistry of transition metal oxyhydrides
title_fullStr New chemistry of transition metal oxyhydrides
title_full_unstemmed New chemistry of transition metal oxyhydrides
title_short New chemistry of transition metal oxyhydrides
title_sort new chemistry of transition metal oxyhydrides
topic Oxyhydride
hydride
mixed anions
solid-state chemistry
url http://dx.doi.org/10.1080/14686996.2017.1394776
work_keys_str_mv AT yojikobayashi newchemistryoftransitionmetaloxyhydrides
AT olivierhernandez newchemistryoftransitionmetaloxyhydrides
AT cedrictassel newchemistryoftransitionmetaloxyhydrides
AT hiroshikageyama newchemistryoftransitionmetaloxyhydrides