Dichloridobis(1,3-phenylpropane-1,3-dionato-κ2O,O′)tin(IV) toluene hemisolvate
The two Sn—O—C—C—C—O chelate rings in the title compound, [Sn(C15H11O2)2Cl2]·0.5C7H8, adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626&am...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810028084 |
| _version_ | 1818286351091499008 |
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| author | Chun Keng Thy Kong Mun Lo Seik Weng Ng |
| author_facet | Chun Keng Thy Kong Mun Lo Seik Weng Ng |
| author_sort | Chun Keng Thy |
| collection | DOAJ |
| description | The two Sn—O—C—C—C—O chelate rings in the title compound, [Sn(C15H11O2)2Cl2]·0.5C7H8, adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) Å in one ring and by 0.690 (1) Å for the other. The two planes are aligned at an angle of 59.6 (1)°. The Cl atoms occupy cis positions in the octahedral SnCl2O4 coordination environment. The solvent molecule is disordered about a center of inversion. |
| first_indexed | 2024-12-13T01:23:12Z |
| format | Article |
| id | doaj.art-4d819098550447f286861dc55692ebec |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:23:12Z |
| publishDate | 2010-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-4d819098550447f286861dc55692ebec2022-12-22T00:04:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m992m99210.1107/S1600536810028084Dichloridobis(1,3-phenylpropane-1,3-dionato-κ2O,O′)tin(IV) toluene hemisolvateChun Keng ThyKong Mun LoSeik Weng NgThe two Sn—O—C—C—C—O chelate rings in the title compound, [Sn(C15H11O2)2Cl2]·0.5C7H8, adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) Å in one ring and by 0.690 (1) Å for the other. The two planes are aligned at an angle of 59.6 (1)°. The Cl atoms occupy cis positions in the octahedral SnCl2O4 coordination environment. The solvent molecule is disordered about a center of inversion.http://scripts.iucr.org/cgi-bin/paper?S1600536810028084 |
| spellingShingle | Chun Keng Thy Kong Mun Lo Seik Weng Ng Dichloridobis(1,3-phenylpropane-1,3-dionato-κ2O,O′)tin(IV) toluene hemisolvate Acta Crystallographica Section E |
| title | Dichloridobis(1,3-phenylpropane-1,3-dionato-κ2O,O′)tin(IV) toluene hemisolvate |
| title_full | Dichloridobis(1,3-phenylpropane-1,3-dionato-κ2O,O′)tin(IV) toluene hemisolvate |
| title_fullStr | Dichloridobis(1,3-phenylpropane-1,3-dionato-κ2O,O′)tin(IV) toluene hemisolvate |
| title_full_unstemmed | Dichloridobis(1,3-phenylpropane-1,3-dionato-κ2O,O′)tin(IV) toluene hemisolvate |
| title_short | Dichloridobis(1,3-phenylpropane-1,3-dionato-κ2O,O′)tin(IV) toluene hemisolvate |
| title_sort | dichloridobis 1 3 phenylpropane 1 3 dionato amp 954 2o o amp 8242 tin iv toluene hemisolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810028084 |
| work_keys_str_mv | AT chunkengthy dichloridobis13phenylpropane13dionatoamp9542ooamp8242tinivtoluenehemisolvate AT kongmunlo dichloridobis13phenylpropane13dionatoamp9542ooamp8242tinivtoluenehemisolvate AT seikwengng dichloridobis13phenylpropane13dionatoamp9542ooamp8242tinivtoluenehemisolvate |