Mechanical properties of abaca fiber reinforced polypropylene composites: Effect of chemical treatment by benzenediazonium chloride

Untreated abaca fibers and benzenediazonium chloride treated abaca strands were employed as reinforcements for fabricating polypropylene composites by injection molding method. Various composites were fabricated with different fiber loadings of 30%, 35%, 40%, 45% and 50% with and without coupling ag...

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Main Authors: Ramadevi Punyamurthy, Dhanalakshmi Sampathkumar, Raghu Patel G. Ranganagowda, Basavaraju Bennehalli, Chikkol V. Srinivasa
Format: Article
Language:English
Published: Elsevier 2017-07-01
Series:Journal of King Saud University: Engineering Sciences
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1018363915000288
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author Ramadevi Punyamurthy
Dhanalakshmi Sampathkumar
Raghu Patel G. Ranganagowda
Basavaraju Bennehalli
Chikkol V. Srinivasa
author_facet Ramadevi Punyamurthy
Dhanalakshmi Sampathkumar
Raghu Patel G. Ranganagowda
Basavaraju Bennehalli
Chikkol V. Srinivasa
author_sort Ramadevi Punyamurthy
collection DOAJ
description Untreated abaca fibers and benzenediazonium chloride treated abaca strands were employed as reinforcements for fabricating polypropylene composites by injection molding method. Various composites were fabricated with different fiber loadings of 30%, 35%, 40%, 45% and 50% with and without coupling agents. Abaca composites without coupling agents with 40% fiber loadings were found to have optimum properties when mechanical characterization was done and the investigation also revealed that untreated and treated composites with coupling agents were found to have improved tensile strength, flexural strength and impact strength when correlated to composites without coupling agents. Among various surface modifications performed, benzenediazonium chloride treated abaca strands reinforced polypropylene composites with coupling agents showed superior properties. For composites including coupling agents, surge in tensile strength and flexural strength was observed with hike in fiber content up to 50% whereas optimum impact properties were shown at 40% fiber loading. Between untreated composites with coupling agent and without coupling agent, composites with coupling agent showed 77.50% hike in tensile strength for 50% fiber loading. Benzenediazonium chloride treated composites with coupling agent showed 70.07% increase in tensile strength when compared to benzenediazonium chloride treated composites without coupling agent for 50% fiber loading. Untreated composites with coupling agent showed 64.91% increase in flexural strength when compared to untreated composites without coupling agent for 50% fiber loading. Benzenediazonium chloride treated composites with coupling agent showed 36.84% increase in flexural strength when compared to benzenediazonium chloride treated composites without coupling agent for 50% fiber loading. However, in case of impact strength, addition of coupling agent increased the impact strength up to 35% fiber loading and beyond 35% fiber loading addition of coupling agent decreased the impact strength. Untreated composites with coupling agent showed 3.53% decrease in impact strength when compared to untreated composites without coupling agent for 40% fiber loading. Benzenediazonium chloride treated composites with coupling agent showed 6.59% decrease in impact strength when compared to benzenediazonium chloride treated composites without coupling agent for 40% fiber loading.
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spelling doaj.art-4daba8c9dbab47a6bb8de22c8045b26a2022-12-22T03:51:22ZengElsevierJournal of King Saud University: Engineering Sciences1018-36392017-07-0129328929410.1016/j.jksues.2015.10.004Mechanical properties of abaca fiber reinforced polypropylene composites: Effect of chemical treatment by benzenediazonium chlorideRamadevi Punyamurthy0Dhanalakshmi Sampathkumar1Raghu Patel G. Ranganagowda2Basavaraju Bennehalli3Chikkol V. Srinivasa4Department of Chemistry, Jawaharlal Nehru Technological University, Hyderabad 500085, Telangana, IndiaDepartment of Chemistry, Jawaharlal Nehru Technological University, Hyderabad 500085, Telangana, IndiaDepartment of Chemistry, Alva’s Institute of Engineering & Technology, Mijar 574225, Karnataka, IndiaDepartment of Chemistry, Alva’s Institute of Engineering & Technology, Mijar 574225, Karnataka, IndiaDepartment of Mechanical Engineering, GM Institute of Technology, Davangere 577006, Karnataka, IndiaUntreated abaca fibers and benzenediazonium chloride treated abaca strands were employed as reinforcements for fabricating polypropylene composites by injection molding method. Various composites were fabricated with different fiber loadings of 30%, 35%, 40%, 45% and 50% with and without coupling agents. Abaca composites without coupling agents with 40% fiber loadings were found to have optimum properties when mechanical characterization was done and the investigation also revealed that untreated and treated composites with coupling agents were found to have improved tensile strength, flexural strength and impact strength when correlated to composites without coupling agents. Among various surface modifications performed, benzenediazonium chloride treated abaca strands reinforced polypropylene composites with coupling agents showed superior properties. For composites including coupling agents, surge in tensile strength and flexural strength was observed with hike in fiber content up to 50% whereas optimum impact properties were shown at 40% fiber loading. Between untreated composites with coupling agent and without coupling agent, composites with coupling agent showed 77.50% hike in tensile strength for 50% fiber loading. Benzenediazonium chloride treated composites with coupling agent showed 70.07% increase in tensile strength when compared to benzenediazonium chloride treated composites without coupling agent for 50% fiber loading. Untreated composites with coupling agent showed 64.91% increase in flexural strength when compared to untreated composites without coupling agent for 50% fiber loading. Benzenediazonium chloride treated composites with coupling agent showed 36.84% increase in flexural strength when compared to benzenediazonium chloride treated composites without coupling agent for 50% fiber loading. However, in case of impact strength, addition of coupling agent increased the impact strength up to 35% fiber loading and beyond 35% fiber loading addition of coupling agent decreased the impact strength. Untreated composites with coupling agent showed 3.53% decrease in impact strength when compared to untreated composites without coupling agent for 40% fiber loading. Benzenediazonium chloride treated composites with coupling agent showed 6.59% decrease in impact strength when compared to benzenediazonium chloride treated composites without coupling agent for 40% fiber loading.http://www.sciencedirect.com/science/article/pii/S1018363915000288Abaca fibersBenzenediazonium chloridePolypropyleneCoupling agentMechanical properties
spellingShingle Ramadevi Punyamurthy
Dhanalakshmi Sampathkumar
Raghu Patel G. Ranganagowda
Basavaraju Bennehalli
Chikkol V. Srinivasa
Mechanical properties of abaca fiber reinforced polypropylene composites: Effect of chemical treatment by benzenediazonium chloride
Journal of King Saud University: Engineering Sciences
Abaca fibers
Benzenediazonium chloride
Polypropylene
Coupling agent
Mechanical properties
title Mechanical properties of abaca fiber reinforced polypropylene composites: Effect of chemical treatment by benzenediazonium chloride
title_full Mechanical properties of abaca fiber reinforced polypropylene composites: Effect of chemical treatment by benzenediazonium chloride
title_fullStr Mechanical properties of abaca fiber reinforced polypropylene composites: Effect of chemical treatment by benzenediazonium chloride
title_full_unstemmed Mechanical properties of abaca fiber reinforced polypropylene composites: Effect of chemical treatment by benzenediazonium chloride
title_short Mechanical properties of abaca fiber reinforced polypropylene composites: Effect of chemical treatment by benzenediazonium chloride
title_sort mechanical properties of abaca fiber reinforced polypropylene composites effect of chemical treatment by benzenediazonium chloride
topic Abaca fibers
Benzenediazonium chloride
Polypropylene
Coupling agent
Mechanical properties
url http://www.sciencedirect.com/science/article/pii/S1018363915000288
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AT raghupatelgranganagowda mechanicalpropertiesofabacafiberreinforcedpolypropylenecompositeseffectofchemicaltreatmentbybenzenediazoniumchloride
AT basavarajubennehalli mechanicalpropertiesofabacafiberreinforcedpolypropylenecompositeseffectofchemicaltreatmentbybenzenediazoniumchloride
AT chikkolvsrinivasa mechanicalpropertiesofabacafiberreinforcedpolypropylenecompositeseffectofchemicaltreatmentbybenzenediazoniumchloride