Sol–Gel-Derived Glass-Ceramic Photorefractive Films for Photonic Structures

Glass photonics are widespread, from everyday objects around us to high-tech specialized devices. Among different technologies, sol–gel synthesis allows for nanoscale materials engineering by exploiting its unique structures, such as transparent glass-ceramics, to tailor optical and electromagnetic...

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Main Authors: Anna Lukowiak, Lidia Zur, Thi Ngoc Lam Tran, Marcello Meneghetti, Simone Berneschi, Gualtiero Nunzi Conti, Stefano Pelli, Cosimo Trono, B.N. Shivakiran Bhaktha, Daniele Zonta, Stefano Taccheo, Giancarlo C. Righini, Maurizio Ferrari
Format: Article
Language:English
Published: MDPI AG 2017-02-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/7/2/61
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author Anna Lukowiak
Lidia Zur
Thi Ngoc Lam Tran
Marcello Meneghetti
Simone Berneschi
Gualtiero Nunzi Conti
Stefano Pelli
Cosimo Trono
B.N. Shivakiran Bhaktha
Daniele Zonta
Stefano Taccheo
Giancarlo C. Righini
Maurizio Ferrari
author_facet Anna Lukowiak
Lidia Zur
Thi Ngoc Lam Tran
Marcello Meneghetti
Simone Berneschi
Gualtiero Nunzi Conti
Stefano Pelli
Cosimo Trono
B.N. Shivakiran Bhaktha
Daniele Zonta
Stefano Taccheo
Giancarlo C. Righini
Maurizio Ferrari
author_sort Anna Lukowiak
collection DOAJ
description Glass photonics are widespread, from everyday objects around us to high-tech specialized devices. Among different technologies, sol–gel synthesis allows for nanoscale materials engineering by exploiting its unique structures, such as transparent glass-ceramics, to tailor optical and electromagnetic properties and to boost photon-management yield. Here, we briefly discuss the state of the technology and show that the choice of the sol–gel as a synthesis method brings the advantage of process versatility regarding materials composition and ease of implementation. In this context, we present tin-dioxide–silica (SnO2–SiO2) glass-ceramic waveguides activated by europium ions (Eu3+). The focus is on the photorefractive properties of this system because its photoluminescence properties have already been discussed in the papers presented in the bibliography. The main findings include the high photosensitivity of sol–gel 25SnO2:75SiO2 glass-ceramic waveguides; the ultraviolet (UV)-induced refractive index change (Δn ~ −1.6 × 10−3), the easy fabrication process, and the low propagation losses (0.5 ± 0.2 dB/cm), that make this glass-ceramic an interesting photonic material for smart optical applications.
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spelling doaj.art-4dadcc6b32044afc8da5202d78fd7d352022-12-22T04:27:30ZengMDPI AGCrystals2073-43522017-02-01726110.3390/cryst7020061cryst7020061Sol–Gel-Derived Glass-Ceramic Photorefractive Films for Photonic StructuresAnna Lukowiak0Lidia Zur1Thi Ngoc Lam Tran2Marcello Meneghetti3Simone Berneschi4Gualtiero Nunzi Conti5Stefano Pelli6Cosimo Trono7B.N. Shivakiran Bhaktha8Daniele Zonta9Stefano Taccheo10Giancarlo C. Righini11Maurizio Ferrari12Institute of Low Temperature and Structure Research, PAS, 2 Okolna St., 50-422 Wroclaw, PolandCentro di Studi e Ricerche “Enrico Fermi”, Piazza del Viminale 1, 00184 Roma, ItalyIFN-CNR CSMFO Lab., and FBK Photonics Unit via alla Cascata 56/C Povo, 38123 Trento, ItalyIFN-CNR CSMFO Lab., and FBK Photonics Unit via alla Cascata 56/C Povo, 38123 Trento, ItalyCNR-IFAC Via Madonna del Piano, 10, 50019 Sesto Fiorentino, FI, ItalyCNR-IFAC Via Madonna del Piano, 10, 50019 Sesto Fiorentino, FI, ItalyCNR-IFAC Via Madonna del Piano, 10, 50019 Sesto Fiorentino, FI, ItalyCNR-IFAC Via Madonna del Piano, 10, 50019 Sesto Fiorentino, FI, ItalyDepartment of Physics, Indian Institute of Technology Kharagpur, Kharagpur 721302, IndiaCentro di Studi e Ricerche “Enrico Fermi”, Piazza del Viminale 1, 00184 Roma, ItalyCollege of Engineering, Swansea University, Singleton Park, Swansea SA2 8PP, UKCentro di Studi e Ricerche “Enrico Fermi”, Piazza del Viminale 1, 00184 Roma, ItalyCentro di Studi e Ricerche “Enrico Fermi”, Piazza del Viminale 1, 00184 Roma, ItalyGlass photonics are widespread, from everyday objects around us to high-tech specialized devices. Among different technologies, sol–gel synthesis allows for nanoscale materials engineering by exploiting its unique structures, such as transparent glass-ceramics, to tailor optical and electromagnetic properties and to boost photon-management yield. Here, we briefly discuss the state of the technology and show that the choice of the sol–gel as a synthesis method brings the advantage of process versatility regarding materials composition and ease of implementation. In this context, we present tin-dioxide–silica (SnO2–SiO2) glass-ceramic waveguides activated by europium ions (Eu3+). The focus is on the photorefractive properties of this system because its photoluminescence properties have already been discussed in the papers presented in the bibliography. The main findings include the high photosensitivity of sol–gel 25SnO2:75SiO2 glass-ceramic waveguides; the ultraviolet (UV)-induced refractive index change (Δn ~ −1.6 × 10−3), the easy fabrication process, and the low propagation losses (0.5 ± 0.2 dB/cm), that make this glass-ceramic an interesting photonic material for smart optical applications.http://www.mdpi.com/2073-4352/7/2/61sol–gelSnO2–SiO2transparent glass-ceramicsphotorefractivityplanar waveguidesattenuation coefficientLorentz–Lorenz formula
spellingShingle Anna Lukowiak
Lidia Zur
Thi Ngoc Lam Tran
Marcello Meneghetti
Simone Berneschi
Gualtiero Nunzi Conti
Stefano Pelli
Cosimo Trono
B.N. Shivakiran Bhaktha
Daniele Zonta
Stefano Taccheo
Giancarlo C. Righini
Maurizio Ferrari
Sol–Gel-Derived Glass-Ceramic Photorefractive Films for Photonic Structures
Crystals
sol–gel
SnO2–SiO2
transparent glass-ceramics
photorefractivity
planar waveguides
attenuation coefficient
Lorentz–Lorenz formula
title Sol–Gel-Derived Glass-Ceramic Photorefractive Films for Photonic Structures
title_full Sol–Gel-Derived Glass-Ceramic Photorefractive Films for Photonic Structures
title_fullStr Sol–Gel-Derived Glass-Ceramic Photorefractive Films for Photonic Structures
title_full_unstemmed Sol–Gel-Derived Glass-Ceramic Photorefractive Films for Photonic Structures
title_short Sol–Gel-Derived Glass-Ceramic Photorefractive Films for Photonic Structures
title_sort sol gel derived glass ceramic photorefractive films for photonic structures
topic sol–gel
SnO2–SiO2
transparent glass-ceramics
photorefractivity
planar waveguides
attenuation coefficient
Lorentz–Lorenz formula
url http://www.mdpi.com/2073-4352/7/2/61
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