Study of physical and mechanical properties of partially biodegradable LDPE polymeric films and their application for printing and packaging

Potato starch, glycerine, itaconic acid and molasses of different physical state (dry and liquid) were used for manufacturing partially biodegradable low density polyethylene (LDPE) films. The mechanical, physical properties of new polymeric films with different physical state were investigated usin...

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Main Authors: Edmundas Kibirkštis, Volodymyr Mayik, Roksolyana Zatserkovna, Kestutis Vaitasius, Anna Stepanenko, Rasa Kandrotaitė-Janutienė, Ingrida Venytė, Paulius Pavelas Danilovas
Format: Article
Language:English
Published: Elsevier 2022-08-01
Series:Polymer Testing
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S0142941822001702
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author Edmundas Kibirkštis
Volodymyr Mayik
Roksolyana Zatserkovna
Kestutis Vaitasius
Anna Stepanenko
Rasa Kandrotaitė-Janutienė
Ingrida Venytė
Paulius Pavelas Danilovas
author_facet Edmundas Kibirkštis
Volodymyr Mayik
Roksolyana Zatserkovna
Kestutis Vaitasius
Anna Stepanenko
Rasa Kandrotaitė-Janutienė
Ingrida Venytė
Paulius Pavelas Danilovas
author_sort Edmundas Kibirkštis
collection DOAJ
description Potato starch, glycerine, itaconic acid and molasses of different physical state (dry and liquid) were used for manufacturing partially biodegradable low density polyethylene (LDPE) films. The mechanical, physical properties of new polymeric films with different physical state were investigated using these test methods: scanning electron microscopy, FTIR spectroscopy, thermogravimetric analysis, tensile testing, heat seal testing and printability testing. Investigated film properties were determined and compared with the properties of the pure LDPE film. It was determined that thermal stability did not changed significantly with the addition of biodegradable additives. The tensile strength and elongation of LDPE films containing potato starch, glycerine and itaconic acid were about 50% lower than pure LDPE film but of the film containing dry molasses and glycerine - was only 25% lower. The heat seal strength of film containing dry molasses was the closest to pure LDPE film at 115 °C. The other tested films required a higher temperature range to form a seal of sufficient strength. The SEM microphotographs have shown the particles of biodegradable additives randomly oriented on the surfaces of some LDPE films, thus, the values of optical density of only one LDPE film containing potato starch and glycerine were the closest to pure LDPE film. LDPE with molasses has been found to be the most suitable film for printing and packaging processes.
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spelling doaj.art-4db4dadee74b4c959c37389e94bc925e2022-12-22T00:38:23ZengElsevierPolymer Testing0142-94182022-08-01112107646Study of physical and mechanical properties of partially biodegradable LDPE polymeric films and their application for printing and packagingEdmundas Kibirkštis0Volodymyr Mayik1Roksolyana Zatserkovna2Kestutis Vaitasius3Anna Stepanenko4Rasa Kandrotaitė-Janutienė5Ingrida Venytė6Paulius Pavelas Danilovas7Kaunas University of Technology, Department of Production Engineering, Studentų St. 56, 51424, Kaunas, LithuaniaUkrainian Academy of Printing, Department of Media Printing Technologies and Packaging, Pidholosko St., 19, 79020, Lviv, UkraineUkrainian Academy of Printing, Department of Media Printing Technologies and Packaging, Pidholosko St., 19, 79020, Lviv, UkraineKaunas University of Technology, Department of Production Engineering, Studentų St. 56, 51424, Kaunas, Lithuania; Corresponding author.Velikomorskaja Str. 30-60, 220028, Minsk, BelarusKaunas University of Technology, Department of Production Engineering, Studentų St. 56, 51424, Kaunas, LithuaniaKaunas University of Technology, Department of Production Engineering, Studentų St. 56, 51424, Kaunas, LithuaniaPolymer Competence Center, Gradauciznos K. 7, 60430, Raseiniu R., LithuaniaPotato starch, glycerine, itaconic acid and molasses of different physical state (dry and liquid) were used for manufacturing partially biodegradable low density polyethylene (LDPE) films. The mechanical, physical properties of new polymeric films with different physical state were investigated using these test methods: scanning electron microscopy, FTIR spectroscopy, thermogravimetric analysis, tensile testing, heat seal testing and printability testing. Investigated film properties were determined and compared with the properties of the pure LDPE film. It was determined that thermal stability did not changed significantly with the addition of biodegradable additives. The tensile strength and elongation of LDPE films containing potato starch, glycerine and itaconic acid were about 50% lower than pure LDPE film but of the film containing dry molasses and glycerine - was only 25% lower. The heat seal strength of film containing dry molasses was the closest to pure LDPE film at 115 °C. The other tested films required a higher temperature range to form a seal of sufficient strength. The SEM microphotographs have shown the particles of biodegradable additives randomly oriented on the surfaces of some LDPE films, thus, the values of optical density of only one LDPE film containing potato starch and glycerine were the closest to pure LDPE film. LDPE with molasses has been found to be the most suitable film for printing and packaging processes.http://www.sciencedirect.com/science/article/pii/S0142941822001702Thermal stabilityTensile strengthHeat seal strengthOptical densityPrintabilityPackaging
spellingShingle Edmundas Kibirkštis
Volodymyr Mayik
Roksolyana Zatserkovna
Kestutis Vaitasius
Anna Stepanenko
Rasa Kandrotaitė-Janutienė
Ingrida Venytė
Paulius Pavelas Danilovas
Study of physical and mechanical properties of partially biodegradable LDPE polymeric films and their application for printing and packaging
Polymer Testing
Thermal stability
Tensile strength
Heat seal strength
Optical density
Printability
Packaging
title Study of physical and mechanical properties of partially biodegradable LDPE polymeric films and their application for printing and packaging
title_full Study of physical and mechanical properties of partially biodegradable LDPE polymeric films and their application for printing and packaging
title_fullStr Study of physical and mechanical properties of partially biodegradable LDPE polymeric films and their application for printing and packaging
title_full_unstemmed Study of physical and mechanical properties of partially biodegradable LDPE polymeric films and their application for printing and packaging
title_short Study of physical and mechanical properties of partially biodegradable LDPE polymeric films and their application for printing and packaging
title_sort study of physical and mechanical properties of partially biodegradable ldpe polymeric films and their application for printing and packaging
topic Thermal stability
Tensile strength
Heat seal strength
Optical density
Printability
Packaging
url http://www.sciencedirect.com/science/article/pii/S0142941822001702
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