Determination of Bi in complex oxide samples by atomic absorption spectrometry by using ordinary acetylene – air flame atomization

In the present work the air/acetylene flame atomic absorption spectrometry was used for bismuth determination in complex oxides. Interference studies were carried out, and interference with vanadium and molybdenum was detected. The method of standard additions and traditional calibration curve metho...

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Main Authors: Zoya A. Mikhaylovskaya, Elena S. Buyanova, Denis Yu. Smirnov
Format: Article
Language:English
Published: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2019-12-01
Series:Chimica Techno Acta
Subjects:
Online Access:https://chimicatechnoacta.ru/article/view/4291
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author Zoya A. Mikhaylovskaya
Elena S. Buyanova
Denis Yu. Smirnov
author_facet Zoya A. Mikhaylovskaya
Elena S. Buyanova
Denis Yu. Smirnov
author_sort Zoya A. Mikhaylovskaya
collection DOAJ
description In the present work the air/acetylene flame atomic absorption spectrometry was used for bismuth determination in complex oxides. Interference studies were carried out, and interference with vanadium and molybdenum was detected. The method of standard additions and traditional calibration curve method were used. Calibration and standard addition curves were fitted with linear and polynomial functions. It was shown that using polynomial function gives better results for the standard additions method for determination of bismuth by acetylene/air flame atomic absorption spectrometry. The calibration curve method was shown to be correct at low ( 10mg/L) concentration of an interferent.
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spelling doaj.art-4db6358553af496c87c2e311f9b85afb2024-12-25T09:36:53ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. ElʹcinaChimica Techno Acta2411-14142019-12-016413814610.15826/chimtech.2019.6.4.033412Determination of Bi in complex oxide samples by atomic absorption spectrometry by using ordinary acetylene – air flame atomizationZoya A. Mikhaylovskaya0Elena S. Buyanova1Denis Yu. Smirnov2Zavaritsky Institute of Geology and Geochemistry of the Ural Branch of the Russian Academy of Sciences, Ekaterinburg; Ural Federal University, EkaterinburgUral Federal University, EkaterinburgZavaritsky Institute of Geology and Geochemistry of the Ural Branch of the Russian Academy of Sciences, EkaterinburgIn the present work the air/acetylene flame atomic absorption spectrometry was used for bismuth determination in complex oxides. Interference studies were carried out, and interference with vanadium and molybdenum was detected. The method of standard additions and traditional calibration curve method were used. Calibration and standard addition curves were fitted with linear and polynomial functions. It was shown that using polynomial function gives better results for the standard additions method for determination of bismuth by acetylene/air flame atomic absorption spectrometry. The calibration curve method was shown to be correct at low ( 10mg/L) concentration of an interferent.https://chimicatechnoacta.ru/article/view/4291determination of bismuthflame atomic absorption spectrometryanalysis of solid oxides
spellingShingle Zoya A. Mikhaylovskaya
Elena S. Buyanova
Denis Yu. Smirnov
Determination of Bi in complex oxide samples by atomic absorption spectrometry by using ordinary acetylene – air flame atomization
Chimica Techno Acta
determination of bismuth
flame atomic absorption spectrometry
analysis of solid oxides
title Determination of Bi in complex oxide samples by atomic absorption spectrometry by using ordinary acetylene – air flame atomization
title_full Determination of Bi in complex oxide samples by atomic absorption spectrometry by using ordinary acetylene – air flame atomization
title_fullStr Determination of Bi in complex oxide samples by atomic absorption spectrometry by using ordinary acetylene – air flame atomization
title_full_unstemmed Determination of Bi in complex oxide samples by atomic absorption spectrometry by using ordinary acetylene – air flame atomization
title_short Determination of Bi in complex oxide samples by atomic absorption spectrometry by using ordinary acetylene – air flame atomization
title_sort determination of bi in complex oxide samples by atomic absorption spectrometry by using ordinary acetylene air flame atomization
topic determination of bismuth
flame atomic absorption spectrometry
analysis of solid oxides
url https://chimicatechnoacta.ru/article/view/4291
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AT elenasbuyanova determinationofbiincomplexoxidesamplesbyatomicabsorptionspectrometrybyusingordinaryacetyleneairflameatomization
AT denisyusmirnov determinationofbiincomplexoxidesamplesbyatomicabsorptionspectrometrybyusingordinaryacetyleneairflameatomization