Investigation of CMAS resistance in the (NdSmEuGd)(1-x)/2Dy2xZr2O7 series
The study examines the corrosion behavior of the (NdSmEuGd)(1-x)/2Dy2xZr2O7 series in 1300 °C molten salt CMAS, demonstrating that the dense layer formed by ZrO2 and apatite could effectively inhibit the penetration of CMAS. Smaller rare-earth ion radii tend to form larger-sized ZrO2, while larger r...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2024-01-01
|
| Series: | Journal of Materials Research and Technology |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2238785423030223 |
| _version_ | 1827368335386345472 |
|---|---|
| author | Mengyao Li Fan Peng Wei Zheng Jimei Zhang Yi Zeng |
| author_facet | Mengyao Li Fan Peng Wei Zheng Jimei Zhang Yi Zeng |
| author_sort | Mengyao Li |
| collection | DOAJ |
| description | The study examines the corrosion behavior of the (NdSmEuGd)(1-x)/2Dy2xZr2O7 series in 1300 °C molten salt CMAS, demonstrating that the dense layer formed by ZrO2 and apatite could effectively inhibit the penetration of CMAS. Smaller rare-earth ion radii tend to form larger-sized ZrO2, while larger rare-earth ion radii favor apatite formation. Therefore, by carefully balancing the rare earth ion radii in the composition design of high-entropy samples, the levels of ZrO2 and apatite formation can be adjusted to prevent CMAS infiltration. This approach helps identify high-entropy zirconate samples with superior corrosion resistance to CMAS. |
| first_indexed | 2024-03-08T09:29:51Z |
| format | Article |
| id | doaj.art-4dc7b13e579c49cfb001a22747a3320a |
| institution | Directory Open Access Journal |
| issn | 2238-7854 |
| language | English |
| last_indexed | 2024-03-08T09:29:51Z |
| publishDate | 2024-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Materials Research and Technology |
| spelling | doaj.art-4dc7b13e579c49cfb001a22747a3320a2024-01-31T05:43:08ZengElsevierJournal of Materials Research and Technology2238-78542024-01-0128123130Investigation of CMAS resistance in the (NdSmEuGd)(1-x)/2Dy2xZr2O7 seriesMengyao Li0Fan Peng1Wei Zheng2Jimei Zhang3Yi Zeng4The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, ChinaThe State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, ChinaThe State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, ChinaThe State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, ChinaThe State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China; Corresponding author. 1295 Dingxi road, Shanghai, 200050, China.The study examines the corrosion behavior of the (NdSmEuGd)(1-x)/2Dy2xZr2O7 series in 1300 °C molten salt CMAS, demonstrating that the dense layer formed by ZrO2 and apatite could effectively inhibit the penetration of CMAS. Smaller rare-earth ion radii tend to form larger-sized ZrO2, while larger rare-earth ion radii favor apatite formation. Therefore, by carefully balancing the rare earth ion radii in the composition design of high-entropy samples, the levels of ZrO2 and apatite formation can be adjusted to prevent CMAS infiltration. This approach helps identify high-entropy zirconate samples with superior corrosion resistance to CMAS.http://www.sciencedirect.com/science/article/pii/S2238785423030223CMAS corrosionRare earth cationsHigh-entropy zirconateCa:Si ratioThermal barrier coatings |
| spellingShingle | Mengyao Li Fan Peng Wei Zheng Jimei Zhang Yi Zeng Investigation of CMAS resistance in the (NdSmEuGd)(1-x)/2Dy2xZr2O7 series Journal of Materials Research and Technology CMAS corrosion Rare earth cations High-entropy zirconate Ca:Si ratio Thermal barrier coatings |
| title | Investigation of CMAS resistance in the (NdSmEuGd)(1-x)/2Dy2xZr2O7 series |
| title_full | Investigation of CMAS resistance in the (NdSmEuGd)(1-x)/2Dy2xZr2O7 series |
| title_fullStr | Investigation of CMAS resistance in the (NdSmEuGd)(1-x)/2Dy2xZr2O7 series |
| title_full_unstemmed | Investigation of CMAS resistance in the (NdSmEuGd)(1-x)/2Dy2xZr2O7 series |
| title_short | Investigation of CMAS resistance in the (NdSmEuGd)(1-x)/2Dy2xZr2O7 series |
| title_sort | investigation of cmas resistance in the ndsmeugd 1 x 2dy2xzr2o7 series |
| topic | CMAS corrosion Rare earth cations High-entropy zirconate Ca:Si ratio Thermal barrier coatings |
| url | http://www.sciencedirect.com/science/article/pii/S2238785423030223 |
| work_keys_str_mv | AT mengyaoli investigationofcmasresistanceinthendsmeugd1x2dy2xzr2o7series AT fanpeng investigationofcmasresistanceinthendsmeugd1x2dy2xzr2o7series AT weizheng investigationofcmasresistanceinthendsmeugd1x2dy2xzr2o7series AT jimeizhang investigationofcmasresistanceinthendsmeugd1x2dy2xzr2o7series AT yizeng investigationofcmasresistanceinthendsmeugd1x2dy2xzr2o7series |