Doubting radiocarbon dating from in-slag charcoal

A Roman-Period bloomery smelting site had been excavated in the Lahn valley at Wetzlar-Dalheim in central Germany during 2006–2012. The production unit consisted of a big rectangular workshop pit with 13 slag pit-furnaces, two waste dumps and a small sunken hut. The stratigraphical sequence, along...

Full description

Bibliographic Details
Main Authors: Guntram Gassmann, Andreas Schäfer
Format: Article
Language:ces
Published: Institute of Archaeology of the Czech Academy of Sciences, Prague 2018-10-01
Series:Archeologické Rozhledy
Subjects:
Online Access:https://archeologickerozhledy.cz/index.php/ar/article/view/81
_version_ 1797954226499878912
author Guntram Gassmann
Andreas Schäfer
author_facet Guntram Gassmann
Andreas Schäfer
author_sort Guntram Gassmann
collection DOAJ
description A Roman-Period bloomery smelting site had been excavated in the Lahn valley at Wetzlar-Dalheim in central Germany during 2006–2012. The production unit consisted of a big rectangular workshop pit with 13 slag pit-furnaces, two waste dumps and a small sunken hut. The stratigraphical sequence, along with abundant pottery and small finds, allows the dating of short-lived smelting activity to a time slot around the third quarter of the first century AD. As a first series of radiocarbon measurements from in-slag charcoal samples resulted in a bewildering date range from the Iron Age right back into the Neolithic, a second dating series has been undertaken. This time exclusively charcoal samples taken from the bottom of the furnace pits have been analysed. The resulting dates fit to the archaeologically derived dating. It is clear that the 14C content of the in-slag charcoal samples must have been altered already during the process in antiquity. With none of the analysed dates younger than the archaeologically fixed date of the bloomery production unit, it is obvious that a contamination with fossil carbon must have taken place. The wide and inconsistent date range suggests that fossil carbon has entered the metallurgical system within the furnace in an uncontrollable manner. The observed phenomenon has wide implications for other metallurgical sites with high temperature processes under strongly reducing conditions. Charcoal samples from such sites, especially from inside slags, might be contaminated to an unpredictable degree and produce seemingly older dates. A first review of previously published data series calls for a reconsideration of the reliability of radiocarbon dates from metallurgical slags.
first_indexed 2024-04-10T23:14:19Z
format Article
id doaj.art-4dcba1d42a0c42a89ce6643fac2905d6
institution Directory Open Access Journal
issn 0323-1267
2570-9151
language ces
last_indexed 2024-04-10T23:14:19Z
publishDate 2018-10-01
publisher Institute of Archaeology of the Czech Academy of Sciences, Prague
record_format Article
series Archeologické Rozhledy
spelling doaj.art-4dcba1d42a0c42a89ce6643fac2905d62023-01-12T21:02:52ZcesInstitute of Archaeology of the Czech Academy of Sciences, PragueArcheologické Rozhledy0323-12672570-91512018-10-0170310.35686/AR.2018.14Doubting radiocarbon dating from in-slag charcoalGuntram Gassmann0Andreas Schäfer1ARGUS Company, Kastellweg 10, DE-72072 TübingenInstitute of Archaeological Sciences, Heritage Sciences and Art History, University of Bamberg, DE-96045 Bamberg A Roman-Period bloomery smelting site had been excavated in the Lahn valley at Wetzlar-Dalheim in central Germany during 2006–2012. The production unit consisted of a big rectangular workshop pit with 13 slag pit-furnaces, two waste dumps and a small sunken hut. The stratigraphical sequence, along with abundant pottery and small finds, allows the dating of short-lived smelting activity to a time slot around the third quarter of the first century AD. As a first series of radiocarbon measurements from in-slag charcoal samples resulted in a bewildering date range from the Iron Age right back into the Neolithic, a second dating series has been undertaken. This time exclusively charcoal samples taken from the bottom of the furnace pits have been analysed. The resulting dates fit to the archaeologically derived dating. It is clear that the 14C content of the in-slag charcoal samples must have been altered already during the process in antiquity. With none of the analysed dates younger than the archaeologically fixed date of the bloomery production unit, it is obvious that a contamination with fossil carbon must have taken place. The wide and inconsistent date range suggests that fossil carbon has entered the metallurgical system within the furnace in an uncontrollable manner. The observed phenomenon has wide implications for other metallurgical sites with high temperature processes under strongly reducing conditions. Charcoal samples from such sites, especially from inside slags, might be contaminated to an unpredictable degree and produce seemingly older dates. A first review of previously published data series calls for a reconsideration of the reliability of radiocarbon dates from metallurgical slags. https://archeologickerozhledy.cz/index.php/ar/article/view/81radiocarbon datingmethodologycharcoal samplesslagfossil carbon
spellingShingle Guntram Gassmann
Andreas Schäfer
Doubting radiocarbon dating from in-slag charcoal
Archeologické Rozhledy
radiocarbon dating
methodology
charcoal samples
slag
fossil carbon
title Doubting radiocarbon dating from in-slag charcoal
title_full Doubting radiocarbon dating from in-slag charcoal
title_fullStr Doubting radiocarbon dating from in-slag charcoal
title_full_unstemmed Doubting radiocarbon dating from in-slag charcoal
title_short Doubting radiocarbon dating from in-slag charcoal
title_sort doubting radiocarbon dating from in slag charcoal
topic radiocarbon dating
methodology
charcoal samples
slag
fossil carbon
url https://archeologickerozhledy.cz/index.php/ar/article/view/81
work_keys_str_mv AT guntramgassmann doubtingradiocarbondatingfrominslagcharcoal
AT andreasschafer doubtingradiocarbondatingfrominslagcharcoal